US4268488A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for the catalytic reduction of nitrogen oxides in gaseous mixtures
Assignee: Honeywell UOP LLC
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Filing: 1979-05-10
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Granted: 1981-05-19
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Expires: 1999-05-10
Abstract
Abstract A process for the reductive removal of a nitrogen oxide from a gaseous stream, particularly a stream containing oxygen, water, sulfur dioxide, nitrogen oxide and nitrogen, by contacting the stream with ammonia in the presence of a mixture of two catalysts. The first catalyst comprises copper or a copper compound, preferably copper sulfate supported on a porous carrier material. The second catalyst is a combination of metals or compounds thereof, preferably sulfates of vanadium and iron or tungsten and iron, also dispersed on a porous carrier material.
Inventors
- 👤 Edward A. Ginger
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 13:32
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/74; B01D53/86; B01D53/8621; B01D53/8625; B01D53/8628; B01J; B01J35/00; B01J35/19
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
148 words
A process for the reductive removal of a nitrogen oxide from a gaseous stream containing said oxide which comprises contacting, at a reductive reaction temperature and pressure, said stream and ammonia with a physical mixture of a first catalyst and a second catalyst, said first catalyst comprising on an elemental basis from about 1 to about 15 wt % copper or a copper compound supported on a first porous carrier material, and said second catalyst comprising on an elemental basis from about 4 to about 10 wt % of a first component selected from the group consisting of vanadium, chromium, molybdenum and tungsten, and compounds thereof, in combination with on an elemental basis from about 4 to about 10 wt % of a second component selected from the group consisting of iron, cobalt and nickel, and compounds thereof, said combination being supported on a second porous carrier material.
Claim 2
Dependent Claim
148 words
A process for the reductive removal of a nitrogen oxide from a gaseous stream containing said oxide which comprises contacting, at a reductive reaction temperature and pressure, said stream and ammonia with a physical mixture of a first catalyst and a second catalyst, said first catalyst comprising on an elemental basis from about 1 to about 15 wt % copper or a copper compound supported on a first porous carrier material, and said second catalyst comprising on an elemental basis from about 4 to about 10 wt % of a first component selected from the group consisting of vanadium, chromium, molybdenum and tungsten, and compounds thereof, in combination with on an elemental basis from about 4 to about 10 wt % of a second component selected from the group consisting of iron, cobalt and nickel, and compounds thereof, said combination being supported on a second porous carrier material.
Claim 3
Dependent Claim
25 words
The process of claim 1 further characterized in that said gaseous stream comprises a mixture of oxygen, water, sulfur dioxide, a nitrogen oxide and nitrogen.
Claim 4
Dependent Claim
34 words
The process of claim 1 further characterized in that said first catalyst comprises on an elemental basis from about 1 to about 15 wt % copper sulfate supported on said first porous carrier material.
Claim 5
Dependent Claim
49 words
The process of claim 1 further characterized in that said first component comprises on an elemental basis from about 4 to about 10 wt % vanadium sulfate or tungsten sulfate and said second component comprises on an elemental basis from about 4 to about 10 wt % iron sulfate.
Claim 6
Dependent Claim
36 words
The process of claim 1 further characterized in that the ratio of the apparent bulk density of said first catalyst to the apparent bulk density of said second catalyst is from about 0.6 to about 1.2.
Claim 7
Dependent Claim
21 words
The process of claim 5 further characterized in that equal volumes of said first catalyst and said second catalyst are utilized.
Claim 8
Dependent Claim
17 words
The process of claim 1 further characterized in that said porous carrier material comprises an inorganic oxide.
Claim 9
Dependent Claim
15 words
The process of claim 7 further characterized in that said inorganic oxide comprises aluminum oxide.
Claim 10
Dependent Claim
38 words
The process of claim 1 further characterized in that said reductive reaction temperature is within a range from about 250° C. to about 400° C. and a pressure within a range from about atmospheric to about 2 psig.
Claim 11
Dependent Claim
29 words
The process of claim 1 further characterized in that said reductive reaction pressure is within a range from about atmospheric pressure to about 10 pounds per square inch gauge.
Claim 12
Dependent Claim
36 words
The process of claim 1 further characterized in that said ammonia is present in an amount sufficient to result in a mole ratio of said ammonia to said nitrogen oxide from about 0.75 to about 1.50.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-05-18 | 1984-11-17 | 1985-05-19 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-05-18 | 1988-11-17 | 1989-05-19 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-05-18 | 1992-11-17 | 1993-05-19 | $7700.00 | Window Closed / Lapsed |