US4268380A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Froth flotation process
Assignee: Arkema Inc
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Filing: 1979-07-30
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Granted: 1981-05-19
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Expires: 1999-07-30
Abstract
Abstract An improvement in the froth flotation separation of metallic sulfide mineral ores, particularly those ores bearing copper and molybdenum, in which a mercaptan collector is used in an earlier primary flotation stage, the improvement comprising the addition of activated carbon to achieve deactivation of the mercaptan collector prior to the component mineral separation stage, thereby providing enhanced separation of the minerals.
Inventors
- 👤 Douglas R. Shaw
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 03:50
CPC Classifications
B; B03; B03D; B03D1/00; B03D1/001; B03D1/004; B03D1/012; B03D2201/00; B03D2201/02; B03D2203/00; B03D2203/02
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
212 words
In the method for recovery of metal values by froth flotation from metallic sulfide mineral ores comprising copper and molybdenum, including the steps of: (A) forming an aqueous mineral pulp from the ore; (B) subjecting the pulp to rougher flotation to provide a scavenger feed and a rougher concentrate; (C) adding an effective amount of an alkyl mercaptan of the formula C n H 2n+1 SH in which n is at least 12 to the rougher flotation stage (B) or to the scavenger feed resulting therefrom, as a collector, and subjecting the scavenger feed to flotation to provide a scavenger tailing and a scavenger concentrate; (D) combining, regrinding, and cleaning the concentrates from the rougher and scavenger flotation states (B) and (C) to provide a copper-molybdenum cleaner concentrate; and then (E) subjecting the cleaner concentrate of step (D) to component mineral stage flotation separation; the improvement which comprises deactivating a substantial amount of the mercaptan collector on the mineral of the ore in the cleaner concentrate of step (D) prior to the component mineral stage flotation separation in step (E), said deactivating comprising adding a deactivating effective amount of activated carbon to the cleaner concentrate prior to flotation in step (E); to provide more effective mineral separation of said copper and molybdenum.
Claim 2
Dependent Claim
212 words
In the method for recovery of metal values by froth flotation from metallic sulfide mineral ores comprising copper and molybdenum, including the steps of: (A) forming an aqueous mineral pulp from the ore; (B) subjecting the pulp to rougher flotation to provide a scavenger feed and a rougher concentrate; (C) adding an effective amount of an alkyl mercaptan of the formula C n H 2n+1 SH in which n is at least 12 to the rougher flotation stage (B) or to the scavenger feed resulting therefrom, as a collector, and subjecting the scavenger feed to flotation to provide a scavenger tailing and a scavenger concentrate; (D) combining, regrinding, and cleaning the concentrates from the rougher and scavenger flotation states (B) and (C) to provide a copper-molybdenum cleaner concentrate; and then (E) subjecting the cleaner concentrate of step (D) to component mineral stage flotation separation; the improvement which comprises deactivating a substantial amount of the mercaptan collector on the mineral of the ore in the cleaner concentrate of step (D) prior to the component mineral stage flotation separation in step (E), said deactivating comprising adding a deactivating effective amount of activated carbon to the cleaner concentrate prior to flotation in step (E); to provide more effective mineral separation of said copper and molybdenum.
Claim 3
Dependent Claim
33 words
The method as defined in claim 1, wherein the amount of activated carbon is within the range of about 0.25 to about 1.0 pound of activated carbon per ton of initial ore feed.
Claim 4
Dependent Claim
40 words
The method as defined in claim 1, wherein the activated carbon is added to the cleaner concentrate a sufficient time prior to step (E) to provide substantial deactivation of the mercaptan prior to commencement of the step (E) separation stage.
Claim 5
Dependent Claim
28 words
The method as defined in claim 3, wherein the time prior to step (E) separation stage is within the range of about 5 minutes to about 30 minutes.
Claim 6
Dependent Claim
14 words
The method as defined in claim 1, wherein the mercaptan is normal dodecyl mercaptan.
Claim 7
Dependent Claim
29 words
The method as defined in claim 5, wherein said mercaptan is added in an amount within the range of about 0.005 to about 0.02 pounds per ton of ore.
Claim 8
Dependent Claim
31 words
The method as defined in claim 6, wherein the amount of activated carbon added is within the range of about 0.25 to about 1.0 pound per ton of initial ore feed.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-05-18 | 1984-11-17 | 1985-05-19 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-05-18 | 1988-11-17 | 1989-05-19 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-05-18 | 1992-11-17 | 1993-05-19 | $7700.00 | Window Closed / Lapsed |