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US4268352A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of reducing soluble starch in broke repulping using a dual polymer combination

Assignee: ChampionX LLC
•
Filing: 1979-05-30
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Granted: 1981-05-19
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Expires: 1999-05-30
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Abstract

Abstract This invention is a method of increasing the amount of retention of deposited starch and pigment on fibers in broke liquid which consists of adding to said liquid a combination dosage of a DMA-epichlorohydrin polymer together with a second polymer consisting of acrylamide/acrylate. Such a polymer may be anionic, such as an acrylamide/sodium acrylate 5% or 30% acrylic acid, or it may be cationic, such as acrylamide/dimethylamino ethyl methacrylate dimethyl sulfate quaternary. The polymers may be applied to the broke directly and preferably in the form of an inverted water-in-oil emulsion. The dosage based on dry weight of starch (T) ranges from 2-35 lbs/T of the DMA-epichlorohydrin polymer product (48% polymer, 0.96-16.8 lbs/T polymer) and 0.5-8 lbs/T based on the second polymer product (28% polymer, 0.14-2.24 lbs/T polymer) selected from the group consisting of copolymers of acrylamide/acrylic acid; copolymers of acrylamide/alkali metal acrylate (e.g., sodium acrylate); copolymers of acrylamide/dimethylamino ethyl methacrylate dimethyl sulfate quaternary (DMAEM.DMS quat).

Inventors

  • 👤 David R. Cosper
  • 👤 Patricia R. Soll

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 11:41
CPC Classifications
D; D21; D21H; D21H17/00; D21H17/20; D21H17/33; D21H17/34; D21H17/37; D21H17/375; D21C; D21C5/00; D21C5/02; D21C5/022; D21H17/41; D21H17/42; D21H17/43; D21H17/44; D21H17/45; D21H17/455; D21H17/46; D21H17/54; D21H17/55; Y; Y02; Y02W; Y02W30/00; Y02W30/50; Y02W30/64

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 89 words
A method of increasing the amount of retention of deposited starch and pigment on fibers in broke liquid which consists of adding to said liquid a combination dosage of a dimethylamine-epichlorohydrin polymer together with a second polymer selected from a group consisting of copolymers of acrylamide with (1) acrylic acid, (2) sodium acrylate, (3) dimethylamino ethyl methacrylate quaternary salt wherein the dosage to broke liquid is 0.96-16.8 lbs/ton of the dimethylamine epichlorohydrin polymer together with 0.14-2.24 lbs/ton of acrylamide copolymer, both dosages being based on dry weight of starch.
Claim 2
Independent Claim 89 words
A method of increasing the amount of retention of deposited starch and pigment on fibers in broke liquid which consists of adding to said liquid a combination dosage of a dimethylamine-epichlorohydrin polymer together with a second polymer selected from a group consisting of copolymers of acrylamide with (1) acrylic acid, (2) sodium acrylate, (3) dimethylamino ethyl methacrylate quaternary salt wherein the dosage to broke liquid is 0.96-16.8 lbs/ton of the dimethylamine epichlorohydrin polymer together with 0.14-2.24 lbs/ton of acrylamide copolymer, both dosages being based on dry weight of starch.
Claim 3
Dependent Claim 12 words
The method of claim 1 wherein the quaternary salt is dimethyl sulfate.
Claim 4
Dependent Claim 11 words
The method of claim 1 wherein the starch is oxidized starch.
Claim 5
Dependent Claim 32 words
The method of claim 1 wherein said second polymer is a copolymer of acrylamide/sodium acrylate which is a water-in-oil emulsion containing about 28% copolymer and contains from 5% to 30% acrylic acid.
Claim 6
Dependent Claim 27 words
The method of claim 1 wherein said polymer is a copolymer of 50% acrylamide and 50% acrylic acid which is a water-in-oil emulsion containing about 28% copolymer.
Claim 7
Dependent Claim 26 words
The method of claim 1 wherein said second polymer is a copolymer of polyacrylamide/dimethylamino ethyl methacrylate quaternary which is a water-in-oil emulsion containing about 28% copolymer.

References Cited (Backward Citations)

US3201304A Cited
US3323979A Cited
US3790476A Cited
US3790476B1 Cited
US3907758A Cited
US4029885A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-05-18 1984-11-17 1985-05-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-05-18 1988-11-17 1989-05-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-05-18 1992-11-17 1993-05-19 $7700.00 Window Closed / Lapsed

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