US4267285A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Composites of polymeric material and thermosetting resinous fibers and particles and method
Assignee: Individual
•
Filing: 1979-08-20
•
Granted: 1981-05-12
•
Expires: 1999-08-20
Abstract
Abstract Composites formed of an organic polymeric matrix and cured thermosetting resinous fibers and/or particles dispersed therein and a method for preparing the same.
Inventors
- 👤 Lawrence J. Broutman
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 18:36
CPC Classifications
C; C08; C08J; C08J5/00; C08J5/04; C08L; C08L23/00; C08L23/02; C08L23/10; C08L23/12; C08L2205/00; C08L2205/14; C08L2205/16; C08L51/00; C08L51/06; C08L61/00; C08L61/04; C08L61/06; Y; Y10; Y10T; Y10T428/00; Y10T428/249921; Y10T428/249924; Y10T428/24994; Y10T428/249942; Y10T428/249947; Y10T428/25; Y10T428/254; Y10T428/29; Y10T428/2913; Y10T428/2933; Y10T428/2962; Y10T428/2964; Y10T428/2967; Y10T428/2973; Y10T428/298
Claims Analysis
Total Claims: 26
Claim 1
Independent Claim
50 words
A composite formed of a matrix of organic polymeric material and fibers of a cured thermosetting resinous material in an infusible insoluble stage dispersed within the matrix of organic polymeric material in which the fibers are surface treated to enhance the interbonding relationship with the polymeric material of the matrix.
Claim 2
Dependent Claim
50 words
A composite formed of a matrix of organic polymeric material and fibers of a cured thermosetting resinous material in an infusible insoluble stage dispersed within the matrix of organic polymeric material in which the fibers are surface treated to enhance the interbonding relationship with the polymeric material of the matrix.
Claim 3
Dependent Claim
20 words
A composite as claimed in claim 1 in which the cured thermosetting resinous material comprises a "C" stage phenolic resin.
Claim 4
Dependent Claim
20 words
A composite as claimed in claim 1 in which the fibers have a cross section within the range of 9-25μ.
Claim 5
Dependent Claim
28 words
A composite as claimed in claim 1 in which the thermosetting resinous fibers are present in an amount within the range of 2-80% by weight of the composite.
Claim 6
Dependent Claim
35 words
A composite as claimed in claim 1 in which the surface treatment of the fibers comprises a surface reaction with a carboxylated propylene, chlorinated polyolefin, titanate coupling agent or an organo silane containing functional groups.
Claim 7
Dependent Claim
65 words
A composite formed of a matrix of organic polymeric material and fibers of a cured thermosetting resinous material in an infusible insoluble stage dispersed within the matrix of organic polymeric material and in which the cured thermosetting resinous material comprises a "C" stage phenolic resin in which the phenolic hydroxyl groups are blocked to enhance the bonding relationship between the fibers and the polymeric matrix.
Claim 8
Dependent Claim
65 words
A composite formed of a matrix of organic polymeric material and fibers of a cured thermosetting resinous material in an infusible insoluble stage dispersed within the matrix of organic polymeric material and in which the cured thermosetting resinous material comprises a "C" stage phenolic resin in which the phenolic hydroxyl groups are blocked to enhance the bonding relationship between the fibers and the polymeric matrix.
Claim 9
Dependent Claim
43 words
A composite as claimed in claim 6 in which the phenolic hydroxyl groups are blocked by replacement of the hydrogen atom with a R-- or ##STR2## group in which R is a lower alkyl, a halogenated lower alkyl, phenyl or a halogenated phenyl.
Claim 10
Dependent Claim
46 words
A composite formed of a matrix of organic polymeric material and fibers of a cured thermosetting resinous material in an infusible insoluble stage dispersed within the matrix of organic polymeric material which includes an organic resinous powder admixed with the fibers in the organic polymeric matrix.
Claim 11
Dependent Claim
46 words
A composite formed of a matrix of organic polymeric material and fibers of a cured thermosetting resinous material in an infusible insoluble stage dispersed within the matrix of organic polymeric material which includes an organic resinous powder admixed with the fibers in the organic polymeric matrix.
Claim 12
Dependent Claim
34 words
A composite as claimed in claim 8 in which the powder is selected from the group consisting of phenol formaldehyde resin, a urea formaldehyde resin, and a melamine formaldehyde resin in the cured stage.
Claim 13
Dependent Claim
24 words
A composite as claimed in claim 9 in which the powder is of a particle size within the range of 5μ to 0.005 inches.
Claim 14
Dependent Claim
21 words
A composite as claimed in claim 9 in which the powder is present in an amount up to 25% by weight.
Claim 15
Dependent Claim
21 words
A composite as claimed in claim 9 in which the powder is present in an amount up to 2-20% by weight.
Claim 16
Dependent Claim
34 words
The method of producing a composite claimed in claim 1 in which the thermosetting resinous fibers are admixed with the polymeric matrix material while the latter is in a plastic stage at elevated temperature.
Claim 17
Dependent Claim
20 words
The method as claimed in claim 13 in which the fibers are admixed with the matrix material in a Banbury.
Claim 18
Dependent Claim
27 words
The method as claimed in claim 13 in which the fibers are admixed with the matrix material by introducing the fibers with the matrix material for extrusion.
Claim 19
Dependent Claim
33 words
The method as claimed in claim 13 in which the fibers are admixed with the matrix material by introducing the fibers with the polymeric matrix material between the rollers of a rolling mill.
Claim 20
Dependent Claim
30 words
The method as claimed in claim 13 which includes the step of treating the fibers for modification of their surface to enhance the bonding relationship with the polymeric matrix material.
Claim 21
Dependent Claim
51 words
The method as claimed in claim 17 in which the fibers are treated prior to their admixture with the matrix material by reaction in a solution of a compound selected from the group consisting of a carboxylated propylene, chlorinated polyolefin, titanate coupling agent and an organo silane compound containing functional groups.
Claim 22
Dependent Claim
51 words
The method as claimed in claim 17 in which the fibers are phenolic resinous fibers in which the hydroxyl groups are blocked by reaction to replace the hydrogen atom with a R-- or ##STR3## group in which R is a lower alkyl, a halogenated lower alkyl, phenyl or a halogenated phenyl.
Claim 23
Dependent Claim
27 words
The method as claimed in claim 13 in which the fibers are incorporated into the polymeric matrix in an amount within the range of 2-50% by weight.
Claim 24
Dependent Claim
33 words
The method as claimed in claim 20 which includes the step of adding a thermosetting resinous powder in an amount within the range of 2-20% by weight of the composite that is formed.
Claim 25
Dependent Claim
65 words
A composite formed of a matrix of an organic polymeric material and fibers of a cured thermosetting resinous material in an infusible insoluble stage dispersed within the matrix of organic polymeric material in which the thermosetting resinous fibers are admixed with the polymeric matrix material in a Banbury extruder or roller mill while the polymeric matrix material is in a plastic stage at elevated temperature.
Claim 26
Dependent Claim
65 words
A composite formed of a matrix of an organic polymeric material and fibers of a cured thermosetting resinous material in an infusible insoluble stage dispersed within the matrix of organic polymeric material in which the thermosetting resinous fibers are admixed with the polymeric matrix material in a Banbury extruder or roller mill while the polymeric matrix material is in a plastic stage at elevated temperature.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-05-11 | 1984-11-10 | 1985-05-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-05-11 | 1988-11-10 | 1989-05-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-05-11 | 1992-11-10 | 1993-05-12 | $7700.00 | Window Closed / Lapsed |