US4267145A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for preparing cold water-soluble films from PVA by melt extrusion
Assignee: EIDP Inc
•
Filing: 1978-08-25
•
Granted: 1981-05-12
•
Expires: 1998-08-25
Abstract
Abstract Films, 0.5-10 mils thick, which are rapidly and completely soluble in cold water, and which are suitable for use as packaging film in automatic packaging equipment, can be prepared by conventional melt extrusion processes when prepared from a novel composition consisting essentially of 5-20 parts by weight of a polyethylene glycol (having an average molecular weight in the range between 325 and 550) in 100 parts by weight of a partially hydrolyzed low molecular weight polyvinyl alcohol.
Inventors
- 👤 Robert D. Wysong
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 16:09
CPC Classifications
B; B65; B65D; B65D85/00; B65D85/70; B65D85/82; B29; B29C; B29C33/00; B29C33/56; B29C33/60; C; C08; C08L; C08L29/00; C08L29/02; C08L29/04; C08L71/00; C08L71/02
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
116 words
A process for making a cold water-soluble film 0.5-10 mils thick comprising melt-extruding a composition consisting essentially of 5 to 20 parts by weight of a polyethylene glycol, having an average molecular weight in the range between 325 and 550 (based upon measurement of the hydroxyl content thereof obtained by esterification of said glycol with phthalic anhydride/pyridine), in 100 parts by weight of a low molecular weight polyvinyl alcohol which is about 85 to about 90 mol% hydrolyzed (determined by saponification) and has a viscosity in the range between about 3 and about 10 cps as measured on a 4% aqueous solution at 20° C. (determined by the Hoeppler Falling Ball Method ASTM-D 1343-56, Part 8).
Claim 2
Dependent Claim
116 words
A process for making a cold water-soluble film 0.5-10 mils thick comprising melt-extruding a composition consisting essentially of 5 to 20 parts by weight of a polyethylene glycol, having an average molecular weight in the range between 325 and 550 (based upon measurement of the hydroxyl content thereof obtained by esterification of said glycol with phthalic anhydride/pyridine), in 100 parts by weight of a low molecular weight polyvinyl alcohol which is about 85 to about 90 mol% hydrolyzed (determined by saponification) and has a viscosity in the range between about 3 and about 10 cps as measured on a 4% aqueous solution at 20° C. (determined by the Hoeppler Falling Ball Method ASTM-D 1343-56, Part 8).
Claim 3
Dependent Claim
33 words
A process of claim 1 wherein said polyethylene glycol is present in an amount in the range between about 12 and about 17 parts per 100 parts by weight of said polyvinyl alcohol.
Claim 4
Dependent Claim
24 words
A process of claim 2 wherein about 15 parts of said polyethylene glycol per 100 parts by weight of said polyvinyl alcohol are present.
Claim 5
Dependent Claim
19 words
A process of claim 1 wherein said polyvinyl alcohol has a viscosity between about 4 and about 6 cps.
Claim 6
Dependent Claim
20 words
A process of claim 1 wherein said polyethylene glycol has an average molecular weight between about 380 and about 420.
Claim 7
Dependent Claim
26 words
A process of claim 5 wherein said polyethylene glycol is present in an amount of 12--17 parts by weight per 100 parts of said polyvinyl alcohol.
Claim 8
Dependent Claim
34 words
A process of claim 6 wherein said film is 1-5 mil thick and said polyethylene glycol is present in an amount of about 15 parts by weight per 100 parts of said polyvinyl alcohol.
Claim 9
Dependent Claim
20 words
A process of claim 7 wherein the viscosity of said polyvinyl alcohol is between about 4 and about 6 cps.
Claim 10
Dependent Claim
97 words
A process for making a cold water-soluble film 1-5 mils thick according to claim 1 wherein said composition contains 2 parts or less by weight per 100 parts of polyvinyl alcohol of a water-soluble polymer, said polymer being selected from polyethers of the formula --[CH 2 CH 2 O] n -- with a molecular weight of at least 600 which are sometimes referred to as polyethylene glycols and sometimes as polyethylene oxides, polypropylene glycol having an average molecular weight of at least 400, and ethylene oxide/propylene oxide copolymers having an average molecular weight of at least 400.
Claim 11
Dependent Claim
48 words
A process of claim 1 wherein said film is 1-5 mils thick and said composition contains 5 parts or less by weight of an adjuvant per 100 parts by weight of said polyvinyl alcohol, said adjuvant being selected from antioxidants, release agents, anti-block agents, slip agents and fillers.
Claim 12
Dependent Claim
12 words
A process of claim 10 wherein said adjuvant is a slip agent.
Claim 13
Dependent Claim
22 words
A process of claim 11 wherein said slip agent is selected from calcium stearate, magnesium stearate, hydrated sodium silico-aluminate, and mixtures thereof.
Claim 14
Dependent Claim
19 words
A process of claim 12 wherein said slip agent is a mixture of magnesium stearate and hydrated sodium silico-aluminate.
References Cited (Backward Citations)
CA678521A
Cited
GB557218A
Cited
US2948697A
Cited
US3157611A
Cited
US3374195A
Cited
US3413229A
Cited
US3607812A
Cited
GB1330745A
Cited
US3882196A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-05-11 | 1984-11-10 | 1985-05-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-05-11 | 1988-11-10 | 1989-05-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-05-11 | 1992-11-10 | 1993-05-12 | $7700.00 | Window Closed / Lapsed |