US4265946A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for forming a subbing layer on a plastic support
Assignee: Zeon Corp
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Filing: 1979-11-13
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Granted: 1981-05-05
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Expires: 1999-11-13
Abstract
Abstract A process for forming a subbing layer in photographic sensitive materials which comprises applying an aqueous dispersion of a copolymer consisting of at least one diolefin monomer and one or more vinyl monomers to a plastic film base in which the gel fraction of the copolymer in said aqueous dispersion is about 80% by weight or less.
Inventors
- 👤 Masao Yabe
- 👤 Sumitaka Tatsuta
- 👤 Takeji Ochiai
- 👤 Tamotsu Suzuki
- 👤 Masayoshi Sekiya
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 23:59
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/76; G03C1/91; G03C1/93
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
156 words
In a process for forming a subbing layer by applying an aqueous dispersion of a copolymer consisting of at least one diolefin monomer and one or more vinyl monomers to a plastic film base for photographic sensitive materials, the improvement which comprises the gel fraction of the copolymer in said aqueous dispersion is about 80% by weight or less and wherein said diolefin is selected from the group consisting of butadiene, isoprene, chloroprene, 1,4-pentadiene, 1,4-hexadiene, 3-vinyl-1,5-hexadiene, 1,5-hexadiene, 3-methyl-1,5-hexadiene, 3,4-dimethyl-1,5-hexadiene, 1,2-divinylcyclobutane, 1,6-heptadiene, 3,5-diethyl-1,5-heptadiene, 4-cyclohexyl-1,6-heptadiene, 3-(4-pentenyl)-1-cyclopentene, 1,7-octadiene, 1,8-nonadiene, 1,9-decadiene, 1,9-octadecadiene, 1-cis-9-cis 12-octadecatriene, 1,10-undecadiene, 1,11-dodecadiene, 1,12-tridecadiene, 1,13-tetradecadiene, 1,14-pentadecadiene, 1,15-hexadecadiene, 1,17-octadecadiene and 1,21-docosadiene and wherein said vinyl monomer is selected from the group consisting of styrene and derivatives thereof, acrylonitrile, methyl methacrylate, vinyl chloride, vinyl acetate, acrylic acid, methacrylic acid, itaconic acid, alkyl acrylates, acrylamide, methacrylamide, acrolein, methacrolein, glycidyl acrylate, glycidyl methacrylate, 2-hydroxyethyl acrylate, 3-hydroxyethyl methacrylate, allyl acrylate, allyl methacrylate, N-methylolated acrylamide, N-methylolated methacrylamide, divinylbenzene, vinyl isocyanate and allyl isocyanate.
Claim 2
Dependent Claim
156 words
In a process for forming a subbing layer by applying an aqueous dispersion of a copolymer consisting of at least one diolefin monomer and one or more vinyl monomers to a plastic film base for photographic sensitive materials, the improvement which comprises the gel fraction of the copolymer in said aqueous dispersion is about 80% by weight or less and wherein said diolefin is selected from the group consisting of butadiene, isoprene, chloroprene, 1,4-pentadiene, 1,4-hexadiene, 3-vinyl-1,5-hexadiene, 1,5-hexadiene, 3-methyl-1,5-hexadiene, 3,4-dimethyl-1,5-hexadiene, 1,2-divinylcyclobutane, 1,6-heptadiene, 3,5-diethyl-1,5-heptadiene, 4-cyclohexyl-1,6-heptadiene, 3-(4-pentenyl)-1-cyclopentene, 1,7-octadiene, 1,8-nonadiene, 1,9-decadiene, 1,9-octadecadiene, 1-cis-9-cis 12-octadecatriene, 1,10-undecadiene, 1,11-dodecadiene, 1,12-tridecadiene, 1,13-tetradecadiene, 1,14-pentadecadiene, 1,15-hexadecadiene, 1,17-octadecadiene and 1,21-docosadiene and wherein said vinyl monomer is selected from the group consisting of styrene and derivatives thereof, acrylonitrile, methyl methacrylate, vinyl chloride, vinyl acetate, acrylic acid, methacrylic acid, itaconic acid, alkyl acrylates, acrylamide, methacrylamide, acrolein, methacrolein, glycidyl acrylate, glycidyl methacrylate, 2-hydroxyethyl acrylate, 3-hydroxyethyl methacrylate, allyl acrylate, allyl methacrylate, N-methylolated acrylamide, N-methylolated methacrylamide, divinylbenzene, vinyl isocyanate and allyl isocyanate.
Claim 3
Dependent Claim
16 words
The process of claim 1, wherein said gel fraction is about 40% by weight or less.
Claim 4
Dependent Claim
19 words
The process of claim 1, wherein said diolefin is selected from the group consisting of butadiene, isoprene and chloroprene.
Claim 5
Dependent Claim
10 words
The process of claim 1, wherein said diolefin is butadiene.
Claim 6
Dependent Claim
36 words
The process of claim 3, wherein said copolymer is a copolymer of said diolefin and at least one monomer selected from the group consisting of styrene and derivatives thereof, acrylonitrile, methylmethacrylate, vinyl chloride and vinyl acetate.
Claim 7
Dependent Claim
84 words
The process of claim 1, wherein said copolymer is a copolymer of a diolefin and (i) at least one monomer selected from the group consisting of styrene and derivatives thereof, acrylonitrile, methyl methacrylate, vinyl chloride and vinyl acetate and (ii) at least one monomer selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid, alkyl acrylates, acrylamide, methacrylamide, acrolein, methacrolein, glycidyl acrylate, glycidyl methacrylate, 2-hydroxyethyl acrylate, 2-hydroxyethyl methacrylate, allyl acrylate, allyl methacrylate, N-methylolated acrylamide, N-methylolated methacrylamide, divinylbenzane, vinyl isocyanate and allyl isocyanate.
Claim 8
Dependent Claim
26 words
The process of claim 1, wherein said copolymer is a styrene-butadiene copolymer, a styrene-isoprene copolymer, a styrene-chloroprene copolymer, a methyl methacrylate-butadiene copolymer or an acrylonitrilebutadiene copolymer.
Claim 9
Dependent Claim
23 words
The process of claim 1, wherein said diolefin is present in said copolymer in an amount of about 10 to 60% by weight.
Claim 10
Dependent Claim
24 words
The process of claim 1, wherein said vinyl monomer is present in said copolymer in an amount of about 90 to 40% by weight.
Claim 11
Dependent Claim
36 words
The process of claim 9, wherein at least about 70 to 40% by weight of said copolymer is selected from the group consisting of styrene and derivatives thereof, acrylonitrile, methyl methacrylate, vinyl chloride and vinyl acetate.
Claim 12
Dependent Claim
12 words
The process of claim 1, wherein said copolymer is a butadiene-styrene copolymer.
Claim 13
Dependent Claim
13 words
The process of claim 1, wherein said copolymer is a butadiene-styrene-2-ethylhexyl acrylate copolymer.
Claim 14
Dependent Claim
19 words
The process of claim 1, wherein said copolymer has a gel fraction of at least about 10% by weight.
Claim 15
Dependent Claim
17 words
The process of claim 1, wherein said aqueous dispersion of a copolymer further comprises a cross-linking agent.
References Cited (Backward Citations)
US3615556A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-05-04 | 1984-11-03 | 1985-05-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-05-04 | 1988-11-03 | 1989-05-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-05-04 | 1992-11-03 | 1993-05-05 | $7700.00 | Window Closed / Lapsed |