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US4265946A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for forming a subbing layer on a plastic support

Assignee: Zeon Corp
•
Filing: 1979-11-13
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Granted: 1981-05-05
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Expires: 1999-11-13
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Abstract

Abstract A process for forming a subbing layer in photographic sensitive materials which comprises applying an aqueous dispersion of a copolymer consisting of at least one diolefin monomer and one or more vinyl monomers to a plastic film base in which the gel fraction of the copolymer in said aqueous dispersion is about 80% by weight or less.

Inventors

  • 👤 Masao Yabe
  • 👤 Sumitaka Tatsuta
  • 👤 Takeji Ochiai
  • 👤 Tamotsu Suzuki
  • 👤 Masayoshi Sekiya

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 23:59
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/76; G03C1/91; G03C1/93

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 156 words
In a process for forming a subbing layer by applying an aqueous dispersion of a copolymer consisting of at least one diolefin monomer and one or more vinyl monomers to a plastic film base for photographic sensitive materials, the improvement which comprises the gel fraction of the copolymer in said aqueous dispersion is about 80% by weight or less and wherein said diolefin is selected from the group consisting of butadiene, isoprene, chloroprene, 1,4-pentadiene, 1,4-hexadiene, 3-vinyl-1,5-hexadiene, 1,5-hexadiene, 3-methyl-1,5-hexadiene, 3,4-dimethyl-1,5-hexadiene, 1,2-divinylcyclobutane, 1,6-heptadiene, 3,5-diethyl-1,5-heptadiene, 4-cyclohexyl-1,6-heptadiene, 3-(4-pentenyl)-1-cyclopentene, 1,7-octadiene, 1,8-nonadiene, 1,9-decadiene, 1,9-octadecadiene, 1-cis-9-cis 12-octadecatriene, 1,10-undecadiene, 1,11-dodecadiene, 1,12-tridecadiene, 1,13-tetradecadiene, 1,14-pentadecadiene, 1,15-hexadecadiene, 1,17-octadecadiene and 1,21-docosadiene and wherein said vinyl monomer is selected from the group consisting of styrene and derivatives thereof, acrylonitrile, methyl methacrylate, vinyl chloride, vinyl acetate, acrylic acid, methacrylic acid, itaconic acid, alkyl acrylates, acrylamide, methacrylamide, acrolein, methacrolein, glycidyl acrylate, glycidyl methacrylate, 2-hydroxyethyl acrylate, 3-hydroxyethyl methacrylate, allyl acrylate, allyl methacrylate, N-methylolated acrylamide, N-methylolated methacrylamide, divinylbenzene, vinyl isocyanate and allyl isocyanate.
Claim 2
Dependent Claim 156 words
In a process for forming a subbing layer by applying an aqueous dispersion of a copolymer consisting of at least one diolefin monomer and one or more vinyl monomers to a plastic film base for photographic sensitive materials, the improvement which comprises the gel fraction of the copolymer in said aqueous dispersion is about 80% by weight or less and wherein said diolefin is selected from the group consisting of butadiene, isoprene, chloroprene, 1,4-pentadiene, 1,4-hexadiene, 3-vinyl-1,5-hexadiene, 1,5-hexadiene, 3-methyl-1,5-hexadiene, 3,4-dimethyl-1,5-hexadiene, 1,2-divinylcyclobutane, 1,6-heptadiene, 3,5-diethyl-1,5-heptadiene, 4-cyclohexyl-1,6-heptadiene, 3-(4-pentenyl)-1-cyclopentene, 1,7-octadiene, 1,8-nonadiene, 1,9-decadiene, 1,9-octadecadiene, 1-cis-9-cis 12-octadecatriene, 1,10-undecadiene, 1,11-dodecadiene, 1,12-tridecadiene, 1,13-tetradecadiene, 1,14-pentadecadiene, 1,15-hexadecadiene, 1,17-octadecadiene and 1,21-docosadiene and wherein said vinyl monomer is selected from the group consisting of styrene and derivatives thereof, acrylonitrile, methyl methacrylate, vinyl chloride, vinyl acetate, acrylic acid, methacrylic acid, itaconic acid, alkyl acrylates, acrylamide, methacrylamide, acrolein, methacrolein, glycidyl acrylate, glycidyl methacrylate, 2-hydroxyethyl acrylate, 3-hydroxyethyl methacrylate, allyl acrylate, allyl methacrylate, N-methylolated acrylamide, N-methylolated methacrylamide, divinylbenzene, vinyl isocyanate and allyl isocyanate.
Claim 3
Dependent Claim 16 words
The process of claim 1, wherein said gel fraction is about 40% by weight or less.
Claim 4
Dependent Claim 19 words
The process of claim 1, wherein said diolefin is selected from the group consisting of butadiene, isoprene and chloroprene.
Claim 5
Dependent Claim 10 words
The process of claim 1, wherein said diolefin is butadiene.
Claim 6
Dependent Claim 36 words
The process of claim 3, wherein said copolymer is a copolymer of said diolefin and at least one monomer selected from the group consisting of styrene and derivatives thereof, acrylonitrile, methylmethacrylate, vinyl chloride and vinyl acetate.
Claim 7
Dependent Claim 84 words
The process of claim 1, wherein said copolymer is a copolymer of a diolefin and (i) at least one monomer selected from the group consisting of styrene and derivatives thereof, acrylonitrile, methyl methacrylate, vinyl chloride and vinyl acetate and (ii) at least one monomer selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid, alkyl acrylates, acrylamide, methacrylamide, acrolein, methacrolein, glycidyl acrylate, glycidyl methacrylate, 2-hydroxyethyl acrylate, 2-hydroxyethyl methacrylate, allyl acrylate, allyl methacrylate, N-methylolated acrylamide, N-methylolated methacrylamide, divinylbenzane, vinyl isocyanate and allyl isocyanate.
Claim 8
Dependent Claim 26 words
The process of claim 1, wherein said copolymer is a styrene-butadiene copolymer, a styrene-isoprene copolymer, a styrene-chloroprene copolymer, a methyl methacrylate-butadiene copolymer or an acrylonitrilebutadiene copolymer.
Claim 9
Dependent Claim 23 words
The process of claim 1, wherein said diolefin is present in said copolymer in an amount of about 10 to 60% by weight.
Claim 10
Dependent Claim 24 words
The process of claim 1, wherein said vinyl monomer is present in said copolymer in an amount of about 90 to 40% by weight.
Claim 11
Dependent Claim 36 words
The process of claim 9, wherein at least about 70 to 40% by weight of said copolymer is selected from the group consisting of styrene and derivatives thereof, acrylonitrile, methyl methacrylate, vinyl chloride and vinyl acetate.
Claim 12
Dependent Claim 12 words
The process of claim 1, wherein said copolymer is a butadiene-styrene copolymer.
Claim 13
Dependent Claim 13 words
The process of claim 1, wherein said copolymer is a butadiene-styrene-2-ethylhexyl acrylate copolymer.
Claim 14
Dependent Claim 19 words
The process of claim 1, wherein said copolymer has a gel fraction of at least about 10% by weight.
Claim 15
Dependent Claim 17 words
The process of claim 1, wherein said aqueous dispersion of a copolymer further comprises a cross-linking agent.

References Cited (Backward Citations)

US3615556A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-05-04 1984-11-03 1985-05-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-05-04 1988-11-03 1989-05-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-05-04 1992-11-03 1993-05-05 $7700.00 Window Closed / Lapsed

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