US4263425A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for production of polyester polymer for food packing
Assignee: LL Plant Engineering AG
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Filing: 1978-11-08
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Granted: 1981-04-21
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Expires: 1998-11-08
Abstract
Abstract Polyethylene terephthalate having an acetaldehyde content of less than 2.5 ppm and suitable for packing of food and beverages intended for human consumption is produced by heating polyethylene terephthalate having an intrinsic viscosity of about 0.5--0.85 at a temperature of 180°-230° C., preferably 200°-220° C., for about 4 to 12 hours. The polyethylene terephthalate must not include more than 25 ppm of ester interchange catalyst or 20 ppm of phosphorous during this heating.
Inventors
- 👤 Hans-Jochen Rothe
- 👤 Peter Freund
- 👤 Werner Gey
- 👤 Helmut Heinze
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 03:03
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/88; C08G63/90
Claims Analysis
Total Claims: 4
Claim 1
Independent Claim
148 words
In a process for the production of polyethylene terephthalate plastic for the packing or bottling of food products for human consumption wherein there is direct contact between the food and the plastic and as a result, the presence of acetaldehyde in the product is undesirable, the improvement which comprises heating polyethylene terephthalate chips containing acetaldehyde and in a solid state having an initial intrinsic viscosity in the range of 0.5-0.85 when measured at 25° C. with 0.5 g polyethylene terephthalate per 100 ml of solvent of 60% phenol and 40% tetrachloroethane, a density in the range of 1.378-1.400, a concentration of ester interchange catalyst in the chip of less than 25 ppm and a phosphorous concentration of less than 20 ppm at a temperature of about 180°-230° C. in an inert atmosphere for about 4-12 hours to reduce the acetaldehyde content to below 2.5 ppm in the chips.
Claim 2
Dependent Claim
148 words
In a process for the production of polyethylene terephthalate plastic for the packing or bottling of food products for human consumption wherein there is direct contact between the food and the plastic and as a result, the presence of acetaldehyde in the product is undesirable, the improvement which comprises heating polyethylene terephthalate chips containing acetaldehyde and in a solid state having an initial intrinsic viscosity in the range of 0.5-0.85 when measured at 25° C. with 0.5 g polyethylene terephthalate per 100 ml of solvent of 60% phenol and 40% tetrachloroethane, a density in the range of 1.378-1.400, a concentration of ester interchange catalyst in the chip of less than 25 ppm and a phosphorous concentration of less than 20 ppm at a temperature of about 180°-230° C. in an inert atmosphere for about 4-12 hours to reduce the acetaldehyde content to below 2.5 ppm in the chips.
Claim 3
Dependent Claim
19 words
A process according to claim 1 wherein said polyethylene terephthalate is heated at a temperature of about 200°-220° C.
Claim 4
Dependent Claim
12 words
A process according to claim 1 wherein said inert gas is nitrogen.
References Cited (Backward Citations)
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-04-20 | 1984-10-20 | 1985-04-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-04-20 | 1988-10-20 | 1989-04-21 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-04-20 | 1992-10-20 | 1993-04-21 | $7700.00 | Window Closed / Lapsed |