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US4263165A Expired / Lapsed US ⏱️ 0.0 years remaining

Blowing agent combination comprising azodicarbonamide, zinc oxide and a benzenethiol sulphonic acid derivative

Assignee: Bayer AG
•
Filing: 1980-05-07
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Granted: 1981-04-21
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Expires: 2000-05-07
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Abstract

Abstract A blowing agent combination comprising azodicarbonamide, zinc oxide and a benzenethiol sulphonic acid derivative having the general formula (I) ##STR1## wherein R is a hydrogen atom, a C 1 -C 4 alkyl radical and/or a chlorine atom, X is a number from 1 to 5, and R' is a C 1 -C 4 alkyl radical, a C 5 -C 6 cycloalkyl radical or a C 7 -C 8 arylalkyl radical each of these radicals being optionally substituted by from 1 to 3 C 1 -C 4 alkyl radicals, from 1 to 5 chlorine atoms and/or a carboxylic acid C 1 -C 4 alkyl ester radical, or a radical having one of the general formulae (11a), (11b), (11c) or (11d). ##STR2## in which y is a number from 0 to 3, R" is a C 1 -C 6 alkylene radical or a xylylene radical which is optionally substituted by from 1 to 4 methyl radicals and/or from 1-4 chlorine atoms and R and X are as defined above; may be used as blowing agents.

Inventors

  • 👤 Ernst Roos
  • 👤 Werner Jeblick
  • 👤 Helmut Hurnik

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 17:48
CPC Classifications
C; C08; C08J; C08J9/00; C08J9/04; C08J9/06; C08J9/10; C08J9/102; C08J9/103; Y; Y10; Y10S; Y10S264/00; Y10S264/05

Claims Analysis

Total Claims: 3
Claim 1
Independent Claim 203 words
A blowing agent combination comprising azodicarbonamide, zinc oxide and a benzenethiol sulphonic acid derivative of the formula ##STR8## wherein R is at least one member selected from the group consisting of hydrogen, C 1 -C 4 alkyl and chlorine; X is a number from 1 to 5 and R' is (a) C 1 -C 4 alkyl, (b) C 5 -C 6 cycloalkyl, (c) C 7 -C 8 aralkyl, (d) one of (a), (b) or (c) substituted by from 1 to 3 C 1 -C 4 alkyl moieties, (e) one of (a), (b) or (c) substituted with from 1 to 5 chlorine atoms, (f) one of (a), (b) or (c) substituted by a carboxylic acid--C 1 -C 4 alkyl ester radical, ##STR9## wherein y is a number from 0 to 3 and R" is C 1 -C 6 alkylene, xylylene or xylylene substituted by 1 to 4 members selected from the group consisting of methyl and chlorine, said blowing agent combination containing from 95 to 5 parts by weight of azodicarbonamide and from 5 to 95 parts by weight of a mixture containing 90 to 10% by weight of zinc oxide and from 10 to 90% by weight of said benzenethiol sulfonic acid derivative.
Claim 2
Dependent Claim 203 words
A blowing agent combination comprising azodicarbonamide, zinc oxide and a benzenethiol sulphonic acid derivative of the formula ##STR8## wherein R is at least one member selected from the group consisting of hydrogen, C 1 -C 4 alkyl and chlorine; X is a number from 1 to 5 and R' is (a) C 1 -C 4 alkyl, (b) C 5 -C 6 cycloalkyl, (c) C 7 -C 8 aralkyl, (d) one of (a), (b) or (c) substituted by from 1 to 3 C 1 -C 4 alkyl moieties, (e) one of (a), (b) or (c) substituted with from 1 to 5 chlorine atoms, (f) one of (a), (b) or (c) substituted by a carboxylic acid--C 1 -C 4 alkyl ester radical, ##STR9## wherein y is a number from 0 to 3 and R" is C 1 -C 6 alkylene, xylylene or xylylene substituted by 1 to 4 members selected from the group consisting of methyl and chlorine, said blowing agent combination containing from 95 to 5 parts by weight of azodicarbonamide and from 5 to 95 parts by weight of a mixture containing 90 to 10% by weight of zinc oxide and from 10 to 90% by weight of said benzenethiol sulfonic acid derivative.
Claim 3
Dependent Claim 15 words
The blowing agent combination of claim 1 wherein said benzenethiol sulphonic acid derivative is dibenzenesulphonyl-disulphide.

References Cited (Backward Citations)

US3803060A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-04-20 1984-10-20 1985-04-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-04-20 1988-10-20 1989-04-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-04-20 1992-10-20 1993-04-21 $7700.00 Window Closed / Lapsed

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