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US4261331A Expired / Lapsed US ⏱️ 0.0 years remaining

Temperature responsive optical switch

Assignee: ExxonMobil Technology and Engineering Co
•
Filing: 1979-06-04
•
Granted: 1981-04-14
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Expires: 1999-06-04
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Abstract

Abstract An optical switching device for reflecting incident light at or above a predetermined temperature comprises a layer of a metal sulfate salt solution in thermal contact with a source of heat. The solution is characterized as having decreasing salt solubility with increasing temperature. When the heat source exceeds a predetermined temperature, the solution precipitates a light scattering layer, substantially reflecting incident light. Embodied in a solar panel, the present invention provides automatic over-temperature control, reflecting light from the energy converter whenever panel temperature exceeds a predetermined limit.

Inventors

  • 👤 Richard B. Stephens

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 16:24
CPC Classifications
F; F24; F24S; F24S40/00; F24S40/50; F24S40/52; Y; Y02; Y02E; Y02E10/00; Y02E10/40

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 186 words
Means for providing automatic over-temperature protection for solar thermal energy conversion devices by controllably reflecting incident light energy whenever said device exceeds a predetermined temperature limit, said means comprising: solar radiation absorbing means for converting light energy into heat energy; a layer of optically transparent fluid, contiguous to said solar radiation absorber and interposed between said absorber and a source of said light energy; a predetermined amount of a solute comprising a metal sulfate salt in solution with said fluid, said solute being characterized as having decreasing solubility with increasing solution temperature, and said amount of solute being predetermined as the amount necessary to saturate said solution at said predetermined temperature limit; container means having at least one optically transparent window, said container means retaining said fluid contiguous to said absorber and maintaining an interpositioning of said fluid between the radiation absorber and said transparent window whereupon said absorber attaining a predetermined temperature, said sulfate salt precipitates from said solution to form a light scattering layer between said absorber and said source of light energy, reflecting said light and reducing the temperature of the solar absorber.
Claim 2
Dependent Claim 186 words
Means for providing automatic over-temperature protection for solar thermal energy conversion devices by controllably reflecting incident light energy whenever said device exceeds a predetermined temperature limit, said means comprising: solar radiation absorbing means for converting light energy into heat energy; a layer of optically transparent fluid, contiguous to said solar radiation absorber and interposed between said absorber and a source of said light energy; a predetermined amount of a solute comprising a metal sulfate salt in solution with said fluid, said solute being characterized as having decreasing solubility with increasing solution temperature, and said amount of solute being predetermined as the amount necessary to saturate said solution at said predetermined temperature limit; container means having at least one optically transparent window, said container means retaining said fluid contiguous to said absorber and maintaining an interpositioning of said fluid between the radiation absorber and said transparent window whereupon said absorber attaining a predetermined temperature, said sulfate salt precipitates from said solution to form a light scattering layer between said absorber and said source of light energy, reflecting said light and reducing the temperature of the solar absorber.
Claim 3
Dependent Claim 44 words
The over-temperature protection means set forth in claim 1 wherein said metal sulfate salt comprises one or more of the group consisting of Mn(SO 4 ), Th(SO 4 ), Th 2 (SO 4 ), Zn(SO 4 ), Fe(SO 4 ) and Ce(SO 4 ).
Claim 4
Dependent Claim 17 words
The over-temperature protection means set forth in claim 1 wherein said metal sulfate salt comprises manganese sulfate.
Claim 5
Dependent Claim 16 words
The over-temperature protection means set forth in claim 3 wherein said optically transparent fluid comprises water.
Claim 6
Dependent Claim 34 words
The over-temperature protection means set forth in claim 3 wherein said amount of solute comprising magnesium sulfate is about 30% by weight of said solution and said temperature limit is above about 100° C.
Claim 7
Dependent Claim 21 words
The over-temperature protection means set forth in claim 1 wherein said optically transparent fluid comprises a mixture of alcohol and water.
Claim 8
Dependent Claim 15 words
The over-temperature protection means set forth in claim 6 wherein said alcohol comprises ethylene glycol.
Claim 9
Dependent Claim 23 words
The over-temperature protection means of claim 1 wherein said solution is transparent to light of wavelengths between about 0.3 microns and 1.3 microns.
Claim 10
Dependent Claim 35 words
The over-temperature protection means of claim 1 wherein said precipitate is further characterized as comprising a plurality of relatively small essentially transparent crystallites having an index of refraction differing from the liquid surrounding said crystallites.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-04-13 1984-10-13 1985-04-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-04-13 1988-10-13 1989-04-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-04-13 1992-10-13 1993-04-14 $7700.00 Window Closed / Lapsed

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