US4260716A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Polymeric quaternary ammonium hydroxides and their use in coating applications
Assignee: PPG Industries Inc
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Filing: 1979-05-07
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Granted: 1981-04-07
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Expires: 1999-05-07
Abstract
Abstract Quaternary ammonium hydroxide-containing polymers and their use in coating applications are disclosed. The quaternary ammonium hydroxide-containing polymers are prepared from reacting a polyglycidyl ether of a cyclic polyol with a tertiary amine in the presence of a sufficient amount of water for the formation of quaternary hydroxide groups. The quaternary ammonium hydroxide-containing polymers are particularly good as electrocoating resins in that they electrodeposit without generating acid counterion. They are also good in other conventional coating applications such as dip, flow, spray and roll coating in that the resulting coating can be baked without the generation of corrosive acid.
Inventors
- 👤 Roger M. Christenson
- 👤 Joseph F. Bosso
- 👤 Marvis E. Hartman
- 👤 Wen-Hsuan Chang
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 03:35
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/58; C08G18/584; C08G18/08; C08G18/0804; C08G18/0809; C08G18/0814; C08G18/64; C08G18/6415; C08G18/643; Y; Y10; Y10S; Y10S524/00; Y10S524/901
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
105 words
A water-dispersible, curable, resinous coating composition in which the resinous commponent comprises an active hydrogen-containing quaternary ammonium hydroxide-containing polymer in combination with a blocked isocyanate curing agent, said quaternary ammonium hydroxide-containing polymer comprising the reaction product of: (A) a polyglycidyl ether of a cyclic polyol; (B) a tertiary amine; sufficient water being present during the reaction of (A) and (B) for the formation of quaternary ammonium hydroxide groups without substantial advancement in molecular weight of the polymer, said quaternary ammonium hydroxide-containing polymer having a molecular weight of 1000 to 5000 and containing 0.05 to 6.0 milliequivalents of quaternary nitrogen base group per gram of polymer.
Claim 2
Dependent Claim
105 words
A water-dispersible, curable, resinous coating composition in which the resinous commponent comprises an active hydrogen-containing quaternary ammonium hydroxide-containing polymer in combination with a blocked isocyanate curing agent, said quaternary ammonium hydroxide-containing polymer comprising the reaction product of: (A) a polyglycidyl ether of a cyclic polyol; (B) a tertiary amine; sufficient water being present during the reaction of (A) and (B) for the formation of quaternary ammonium hydroxide groups without substantial advancement in molecular weight of the polymer, said quaternary ammonium hydroxide-containing polymer having a molecular weight of 1000 to 5000 and containing 0.05 to 6.0 milliequivalents of quaternary nitrogen base group per gram of polymer.
Claim 3
Dependent Claim
21 words
The polymer of claim 1 in which the cyclic polyol is selected from the class consisting of polyphenols and alicyclic polyols.
Claim 4
Dependent Claim
21 words
The polymer of claim 2 in which the cyclic polyol is an oxyalkylated derivative of the polyphenol and the alicyclic polyol.
Claim 5
Dependent Claim
23 words
The polymer of claim 1 in which the polyglycidyl ether of a cyclic polyol is a chain extended product with a polymeric polyol.
Claim 6
Dependent Claim
14 words
The polymer of claim 4 in which the polymeric polyol is a polyester polyol.
Claim 7
Dependent Claim
14 words
The polymer of claim 5 in which the polyester polyol is a polylactone polyol.
Claim 8
Dependent Claim
33 words
The polymer of claim 1 in which the polyglycidyl ether of a cyclic polyol is a chain extended product with an N-heterocyclic ring-containing material having one or more ##STR4## moieties in the ring.
Claim 9
Dependent Claim
67 words
The polymer of claim 1 in which the N-heterocyclic ring-containing material has the following structural formula: ##STR5## where X is a bivalent radical which is necessary to complete a 5 or 6-membered unsubstituted or substituted heterocyclic ring; where R is H or ##STR6## where Y is hydrogen or lower alkyl having 1 to 4 carbon atoms, m is 1 to 4, and n is 1 to 50.
Claim 10
Dependent Claim
50 words
A coated article comprising a solid substrate having deposited thereon a cured resinous coating composition, said resinous composition being deposited on said substrate from an aqueous resinous dispersion in which the resinous phase comprises the resinous coating composition of any of claims 1,2, 3, 4, 5, 6, 7 or 8.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-04-06 | 1984-10-06 | 1985-04-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-04-06 | 1988-10-06 | 1989-04-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-04-06 | 1992-10-06 | 1993-04-07 | $7700.00 | Window Closed / Lapsed |