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US4260394A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for reducing the sulfur content of coal

Assignee: INTERNATIONAL SEPARATIONS SYSTEMS Inc
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Filing: 1979-08-08
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Granted: 1981-04-07
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Expires: 1999-08-08
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Abstract

Abstract After pulverizing to minus 200 mesh, a mixture of coal and pyrite particles is passed through an A.C. silent corona discharge in the presence of a reactant gas. Simultaneously, the particles are de-agglomerated and an electrical or magnetic difference between them is enhanced. Thereafter, the pyrite is separated from the coal. The effectiveness of the pulverizing step in separating pyrite particles from the coal matrix, especially small-size particles approximately 50 micrometers and less, is enhanced by pretreating the coal with a chemical comminutant. One example is a solution of ammonia, used to presoak the coal for a short time, at, for example, atmospheric pressure and ambient temperature.

Inventors

  • 👤 Stanley R. Rich

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 18:00
CPC Classifications
B; B03; B03C; B03C7/00; C; C10; C10L; C10L9/00; Y; Y10; Y10S; Y10S44/00; Y10S44/904

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 81 words
A process for reducing the sulfur content of coal comprising the steps of pulverizing the coal to at least minus 200 mesh particles so as to free a substantial percentage of the pyrite component physically from the coal component, passing a mixture of said particles of the coal and the pyrite through an A.C. silent corona discharge so as to reduce adhesion by electrostatic forces and thereby de-agglomerate substantially all the particles, and thereafter separating said components one from the other.
Claim 2
Dependent Claim 81 words
A process for reducing the sulfur content of coal comprising the steps of pulverizing the coal to at least minus 200 mesh particles so as to free a substantial percentage of the pyrite component physically from the coal component, passing a mixture of said particles of the coal and the pyrite through an A.C. silent corona discharge so as to reduce adhesion by electrostatic forces and thereby de-agglomerate substantially all the particles, and thereafter separating said components one from the other.
Claim 3
Dependent Claim 42 words
A process according to claim 1 including, simultaneously with said de-agglomerating, altering the chemistry of the pyrite to enhance the difference in electrical conductivity between the pyrite component and the coal component, and thereafter electrostatically separating said components one from the other.
Claim 4
Dependent Claim 35 words
A process according to claim 1 including, simultaneously with said de-agglomerating, increasing selectively the magnetic susceptibility of the pyrite component relative to the coal component, and thereafter magnetically separating said components one from the other.
Claim 5
Dependent Claim 111 words
A process for reducing the sulfur content of coal comprising the steps of pulverizing the coal so as to free a substantial percentage of the pyrite component physically from the coal component in a mixture of said components, passing said pulverized mixture through an A.C. silent corona discharge to de-agglomerate substantially all of the particles of the mixture and simultaneously to alter the surfaces of substantially all the pyrite particles to a depth of at least one molecule to a new chemical form having at least one of its magnetic susceptibility and its electrical conductivity substantially enhanced relative to the coal component, and thereafter separating said components one from the other.
Claim 6
Dependent Claim 111 words
A process for reducing the sulfur content of coal comprising the steps of pulverizing the coal so as to free a substantial percentage of the pyrite component physically from the coal component in a mixture of said components, passing said pulverized mixture through an A.C. silent corona discharge to de-agglomerate substantially all of the particles of the mixture and simultaneously to alter the surfaces of substantially all the pyrite particles to a depth of at least one molecule to a new chemical form having at least one of its magnetic susceptibility and its electrical conductivity substantially enhanced relative to the coal component, and thereafter separating said components one from the other.
Claim 7
Dependent Claim 24 words
A process according to claim 4 wherein the electrical conductivity of the pyrite particles is enhanced, including the step of electrostatically separating said components.
Claim 8
Dependent Claim 24 words
A process according to claim 4 wherein the magnetic susceptibility of the pyrite particles is enhanced, including the step of magnetically separating said components.
Claim 9
Dependent Claim 45 words
A process according to claim 1 including the preliminary step of treating the coal with a suitable chemical so as to weaken bonds between the coal matrix and pyrite particles, and thereafter pulverizing the coal to physically separate the pyrite component from the coal component.
Claim 10
Dependent Claim 28 words
A process according to claim 7 wherein the chemical is 29% ammonia in water, and the coal is wetted in that solution, and thereafter the coal is pulverized.

References Cited (Backward Citations)

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US614927A Cited
US1366457A Cited
US1731473A Cited
GB819588A Cited
GB851502A Cited
GB854729A Cited
US4081251A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-04-06 1984-10-06 1985-04-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-04-06 1988-10-06 1989-04-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-04-06 1992-10-06 1993-04-07 $7700.00 Window Closed / Lapsed

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