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US4258176A Expired / Lapsed US ⏱️ 0.0 years remaining

Transparent copolyamide from 1,10-disubstituted C11 diamine

Assignee: BASF Corp
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Filing: 1979-10-09
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Granted: 1981-03-24
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Expires: 1999-10-09
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Abstract

Abstract There are described transparent copolyamides which are obtained by reaction of a mixture (A) consisting of essentially stoichiometric amounts of a diamine ##STR1## and isophthalic acid or terephthalic acid, or a mixture of isophthalic acid and terephthalic acid, with a mixture (B) consisting of essentially stoichiometric amounts of a diamine ##STR2## and terephthalic acid or a mixture of terephthalic acid and isophthalic acid, or with a mixture (C) consisting of essentially stoichiometric amounts of a diamine ##STR3## and terephthalic acid or isophthalic acid or mixtures thereof, wherein R', R" and R 1 to R 11 have the meanings given in claim 1. The novel copolyamides are distinguished by good thermoplastic processing characteristics, by low water absorption and by good stability to hydrolysis, and are suitable for producing transparent moulded articles.

Inventors

  • 👤 Josef Pfeifer
  • 👤 Dieter Reinehr

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 23:07
CPC Classifications
C; C08; C08G; C08G69/00; C08G69/02; C08G69/26; C08G69/265

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 395 words
A transparent copolyamide having a reduced specific viscosity of at least 0.5 dl/g, measured on a 0.5% solution of m-cresol at 25° C., which copolyamide is obtained by reaction of a mixture (A) consisting of essentially stoichiometric amounts of a diamine of the formula I ##STR16## and isophthalic acid or terephthalic acid, or amide-forming derivatives thereof, or a mixture of isophthalic acid and terephthalic acid, or amide-forming derivatives thereof, either with a mixture (B) consisting of essentially stoichiometric amounts of a diamine of the formula II ##STR17## and terephthalic acid or an amide-forming derivative thereof, or a mixture of terephthalic acid and isophthalic acid, or amide-forming derivatives thereof, in a molar ratio of terephthalic acid, or amide-forming derivative: isophthalic acid, or amide-forming derivative, of 8:2 to 10:0, or with a mixture (C) consisting of essentially stoichiometric amounts of a diamine of the formula III ##STR18## and terephthalic acid or isophthalic acid, or mixtures or amide-forming derivatives thereof, wherein R' and R" independently of one another are each hydrogen or methyl, R 1 to R 4 independently of one another are each hydrogen or alkyl having 1-4 C atoms, R 5 is alkyl having 1-12 C atoms, aryl having 6-10 C atoms, or said aryl substituted by alkyl having 1-4 C atoms, R 6 is hydrogen or alkyl having 1-6 C atoms, or R 5 and R 6 together are alkylene having 4-7 C atoms, R 7 is alkyl having 1-8 C atoms, R 8 is hydrogen or alkyl having 1-5 C atoms, R 9 is cycloalkyl which has 5-12 ring C atoms and which is unsubstituted or substituted by alkyl of 1-4 C atoms, R 10 is hydrogen or methyl, and R 11 is methyl, or R 10 and R 11 together are alkylene having 4-11 C atoms, the proportion of mixture (C) being 60-80 percent by weight, based on the total copolyamide, or the proportion of mixture (B) being 50-80 percent by weight, based on the total copolyamide, with the proviso that with a proportion of mixture (B) of up to 65 percent by weight, at most 70 mol.% of isophthalic acid, or of an amide-forming derivative thereof, in mixture (A) can be replaced by terephthalic acid or by an amide-forming derivative thereof, these weight percentages in the case of amide-forming derivatives of isophthalic acid or of terephthalic acid relating to identical functional groups.
Claim 2
Dependent Claim 395 words
A transparent copolyamide having a reduced specific viscosity of at least 0.5 dl/g, measured on a 0.5% solution of m-cresol at 25° C., which copolyamide is obtained by reaction of a mixture (A) consisting of essentially stoichiometric amounts of a diamine of the formula I ##STR16## and isophthalic acid or terephthalic acid, or amide-forming derivatives thereof, or a mixture of isophthalic acid and terephthalic acid, or amide-forming derivatives thereof, either with a mixture (B) consisting of essentially stoichiometric amounts of a diamine of the formula II ##STR17## and terephthalic acid or an amide-forming derivative thereof, or a mixture of terephthalic acid and isophthalic acid, or amide-forming derivatives thereof, in a molar ratio of terephthalic acid, or amide-forming derivative: isophthalic acid, or amide-forming derivative, of 8:2 to 10:0, or with a mixture (C) consisting of essentially stoichiometric amounts of a diamine of the formula III ##STR18## and terephthalic acid or isophthalic acid, or mixtures or amide-forming derivatives thereof, wherein R' and R" independently of one another are each hydrogen or methyl, R 1 to R 4 independently of one another are each hydrogen or alkyl having 1-4 C atoms, R 5 is alkyl having 1-12 C atoms, aryl having 6-10 C atoms, or said aryl substituted by alkyl having 1-4 C atoms, R 6 is hydrogen or alkyl having 1-6 C atoms, or R 5 and R 6 together are alkylene having 4-7 C atoms, R 7 is alkyl having 1-8 C atoms, R 8 is hydrogen or alkyl having 1-5 C atoms, R 9 is cycloalkyl which has 5-12 ring C atoms and which is unsubstituted or substituted by alkyl of 1-4 C atoms, R 10 is hydrogen or methyl, and R 11 is methyl, or R 10 and R 11 together are alkylene having 4-11 C atoms, the proportion of mixture (C) being 60-80 percent by weight, based on the total copolyamide, or the proportion of mixture (B) being 50-80 percent by weight, based on the total copolyamide, with the proviso that with a proportion of mixture (B) of up to 65 percent by weight, at most 70 mol.% of isophthalic acid, or of an amide-forming derivative thereof, in mixture (A) can be replaced by terephthalic acid or by an amide-forming derivative thereof, these weight percentages in the case of amide-forming derivatives of isophthalic acid or of terephthalic acid relating to identical functional groups.
Claim 3
Dependent Claim 181 words
A transparent copolyamide according to claim 1, which is obtained by reaction of a mixture (A) consisting of essentially stoichiometric amounts of a diamine of the formula I and isophthalic acid or terephthalic acid or a mixture of isophthalic acid and terephthalic acid, or amide-forming derivatives thereof, with a mixture (B) consisting of essentially stoichiometric amounts of a diamine of the formula II and terephthalic acid or an amide-forming derivative thereof, wherein R' and R" are each hydrogen, R 1 to R 4 independently of one another are hydrogen or methyl, R 5 is phenyl, straight-chain alkyl having 1-6 C atoms or --CH(R 12 ) (R 13 ), R 6 is hydrogen or methyl, R 7 and R 13 independently of one another are each alkyl having 1-6 C atoms, and R 8 and R 12 independently of one another are each alkyl having 1-4 C atoms, the proportion of mixture (B) being 50-75 percent by weight based on the total copolyamide, these weight percentages in the case of amide-forming derivatives of iso- or terephthalic acid relating to identical functional groups.
Claim 4
Dependent Claim 78 words
A transparent copolyamide according to claim 2, wherein R' and R" are each hydrogen, R 1 and R 4 are each methyl, R 2 and R 3 are each hydrogen, R 6 is hydrogen, R 5 is --CH(R 12 ) (R 13 ), and R 7 and R 13 and R 8 and R 12 are each methyl, ethyl, n-propyl or n-butyl, and the proportion of mixture (B) is 50-70 percent by weight, based on the total copolyamide.
Claim 5
Dependent Claim 141 words
A transparent copolyamide according to claim 1, which is obtained by reaction of a mixture (A) consisting of essentially stoichiometric amounts of a diamine of the formula I and isophthalic acid or an amide-forming derivative thereof with a mixture (C) consisting of essentially stoichiometric amounts of a diamine of the formula III and terephthalic acid or an amide-forming derivative thereof, wherein R' and R" are each hydrogen, R 1 to R 4 independently of one another are each hydrogen or methyl, R 9 is cycloalkyl having 5-8 ring C atoms, and R 10 and R 11 are each methyl or together are alkylene having 4-7 C atoms, the proportion of mixture (C) being 65-75 percent by weight, based on the total copolyamide, these weight percentages in the case of amide-forming derivatives of iso- or terephthalic acid relating to identical functional groups.
Claim 6
Dependent Claim 73 words
A transparent copolyamide according to claim 4, wherein R' and R" are each hydrogen, R 1 and R 4 are each methyl, R 2 and R 3 are each hydrogen, R 9 is cyclopentyl, and R 10 and R 11 together are tetramethylene, or R 9 is cyclohexyl, and R 10 and R 11 together are pentamethylene, and the proportion of mixture (C) is 65-75 percent by weight, based on the total copolyamide.
Claim 7
Dependent Claim 180 words
A transparent copolyamide according to claim 1, which is obtained by reaction of a mixture (A) consisting of essentially stoichiometric amounts of a diamine of the formula Ia ##STR19## and isophthalic acid or terephthalic acid, or amide-forming derivatives thereof, or a mixture of isophthalic acid and terephthalic acid, or amide-forming derivatives thereof, in a molar ratio of isophthalic acid(derivative): terephthalic acid(derivative) of 5:5, with a mixture (B) consisting of essentially stoichiometric amounts of a diamine of the formula IIa ##STR20## wherein R 7 , R 8 , R 12 and R 13 are each methyl or ethyl, and terephthalic acid or an amide-forming derivative thereof, the proportion of mixture (B) where R 7 , R 8 , R 12 and R 13 are each methyl being 60-75 percent by weight based on the total copolyamide, and where R 7 , R 8 , R 12 and R 13 are each ethyl being 50-65 percent by weight based on the total copolyamide, these weight percentages in the case of amide-forming derivatives of iso- or terephthalic acid relating to identical functional groups.
Claim 8
Dependent Claim 55 words
A transparent copolyamide as claimed in claim 1, which is obtained by reacting a mixture (A) of essentially stoichiometric amounts of 4,4'-diamino-3,3'-dimethyldicyclohexylmethane and isophthalic acid with a mixture (B) of essentially stoichiometric amounts of 1-isopropyl-10,10-dimethyl-1,11-diaminoundecane and terephthalic acid, said mixture (B) amounting to from 60 to 75 percent by weight, based on the total copolyamide.
Claim 9
Dependent Claim 55 words
A transparent copolyamide as claimed in claim 1, which is obtained by reacting a mixture (A) of essentially stoichiometric amounts of 4,4'-diamino-3,3'-dimethyldicyclohexylamine and isophthalic acid with a mixture (B) of essentially stoichiometric amounts of 1-(3-pentyl)-10,10-diethyl-1,11-diaminoundecane and terephthalic acid, said mixture (B) amounting to from 50 to 65 percent by weight based on the total copolyamide.
Claim 10
Dependent Claim 55 words
A transparent copolyamide as claimed in claim 1, which is obtained by reacting a mixture (A) of essentially stoichiometric amounts of 4,4'-diamino-3,3'-dimethyldicyclohexylamine and terephthalic acid with a mixture (B) of essentially stoichiometric amounts of 1-isopropyl-10,10-dimethyl-1,11-diaminoundecane and terephthalic acid, said mixture (B) amounting to from 65 to 75 percent by weight, based on the total copolyamide.

References Cited (Backward Citations)

US3563959A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-03-23 1984-09-22 1985-03-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-03-23 1988-09-22 1989-03-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-03-23 1992-09-22 1993-03-24 $7700.00 Window Closed / Lapsed

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