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Process for the polymerization of olefins

Assignee: Solvay SA
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Filing: 1975-12-04
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Granted: 1981-03-24
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Expires: 1995-12-04
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Abstract

Abstract A process for low temperature polymerization and copolymerization of alpha-olefins comprising conducting the polymerization in the presence of a catalytic system comprising an organic compound of a metal of Group IA, IIA, IIB, IIIA and IVA of the Periodic Table and a solid catalytic complex which is prepared by reacting a compound of a metal of Groups IVB, VB and VIB of the Periodic Table with a porous aluminum oxide on which a magnesium compound is deposited.

Inventors

  • 👤 Charles Bienfait

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 11:38
CPC Classifications
C; C08; C08F; C08F10/00; C08F2410/00; C08F2410/04

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 215 words
A process for the low pressure polymerization and copolymerization of alpha-olefins which comprises conducting the polymerization and copolymerization in the presence of a catalyst system comprising: (a) an organic compound of a metal of Groups IA, IIA, IIB, IIIA and IVA of the Periodic Table, being selected from alkyl metal compounds, alkyl metal hydrides and alkyl metal halides; and (b) a solid catalyst complex, said complex prepared by reacting (1) a transition metal compound of the metals of Groups IVB, VB and VIB of the Periodic Table selected from halides, oxyhalides, alkoxyhalides, oxyalkoxides, and alkoxides with (2) a porous aluminum oxide having an internal porosity of greater than 0.3 cm 3 /g and a specific surface area of between 200 and 400 m 2 /g on which is chemically attached an amount of magnesium compound selected from organic oxygen containing magnesium compounds containing only C 1 -C 20 organic radical bonded to magnesium via oxygen and magnesium dihalides, said amount being such that between 1×10 -3 and 5×10 -3 milligram-atom of magnesium is present per square meter of specific surface area of the porous oxide and the magnesium compound having been chemically attached on the porous aluminum oxide in a liquid medium, said medium being in the form of water or of an organic diluent.
Claim 2
Dependent Claim 215 words
A process for the low pressure polymerization and copolymerization of alpha-olefins which comprises conducting the polymerization and copolymerization in the presence of a catalyst system comprising: (a) an organic compound of a metal of Groups IA, IIA, IIB, IIIA and IVA of the Periodic Table, being selected from alkyl metal compounds, alkyl metal hydrides and alkyl metal halides; and (b) a solid catalyst complex, said complex prepared by reacting (1) a transition metal compound of the metals of Groups IVB, VB and VIB of the Periodic Table selected from halides, oxyhalides, alkoxyhalides, oxyalkoxides, and alkoxides with (2) a porous aluminum oxide having an internal porosity of greater than 0.3 cm 3 /g and a specific surface area of between 200 and 400 m 2 /g on which is chemically attached an amount of magnesium compound selected from organic oxygen containing magnesium compounds containing only C 1 -C 20 organic radical bonded to magnesium via oxygen and magnesium dihalides, said amount being such that between 1×10 -3 and 5×10 -3 milligram-atom of magnesium is present per square meter of specific surface area of the porous oxide and the magnesium compound having been chemically attached on the porous aluminum oxide in a liquid medium, said medium being in the form of water or of an organic diluent.
Claim 3
Dependent Claim 23 words
The process according to claim 1 in which the metal of the organic compound (a) is aluminum and the transition metal is titanium.
Claim 4
Dependent Claim 16 words
The process according to claim 1 wherein the magnesium compound is a magnesium alkoxide or phenoxide.
Claim 5
Dependent Claim 46 words
The process according to claim 1 wherein the magnesium compound is chemically attached on the porous aluminum oxide in the presence of an oxygen-containing organic compound (M) of a metal of Groups IA, IIB, IIIA, IVA, IVB, VB, VIB, VIIB and VIII of the Periodic Table.
Claim 6
Dependent Claim 84 words
Process according to claim 4 wherein the oxygen-containing organic compound (M) is a compound of the general formula [MeO x (OR) y ] m wherein Me is a metal selected from lithium, sodium, potassium, zinc, boron, aluminum, silicon, tin, titanium, zirconium, vanadium, chromium, manganese, iron, cobalt, and nickel, R is an organic radical containing from 1 to 20 carbon atoms, x and y are any number such that x≧o and y>o compatible with the valency of the metal Me, and m is an integer.
Claim 7
Dependent Claim 41 words
The process according to claim 5 wherein the metal Me is aluminum, silicon, titanium, zirconium, vanadium, or chromium, R is a hydrocarbon radical containing from 1 to 6 carbon atoms, x is such that o≦x≦1 and m is such that 1≦m≦6.
Claim 8
Dependent Claim 42 words
The process according to claim 4 wherein the magnesium compound is chemically attached on the porous aluminum oxide in the form of a solution in an organic diluent or of a mixture of the magnesium compound with the oxygen-containing organic compound (M).
Claim 9
Dependent Claim 45 words
The process according to claim 4 wherein the magnesium compound and the oxygen containing organic compound (M) are mixed in such amounts that the atomic ratio of the metal Me of the oxygen-containing organic compound to magnesium is between 0.5 and 100 gram atom/gram atom.
Claim 10
Dependent Claim 23 words
The process according to claim 1 wherein the porous aluminum oxide is a complex oxide of aluminum and at least one other metal.
Claim 11
Dependent Claim 26 words
The process according to claim 1 wherein the porous aluminum oxide is subjected to a halogenation treatment before being brought into contact with the magnesium compound.
Claim 12
Dependent Claim 27 words
The process according to claim 10 wherein the porous aluminum oxide is a fluorinated alumina such that the atomic ratio of fluorine/aluminum is between 0.01 and 1.
Claim 13
Dependent Claim 39 words
The process according to claim 1 wherein the magnesium compound is chemically attached on the porous aluminum oxide in the form of a solution in water or in an organic diluent which is capable of dissolving said magnesium compound.

References Cited (Backward Citations)

GB1264416A Cited
DE2000566A1 Cited
US3803105A Cited
US3705886A Cited
DE2123357C3 Cited
DE2146686C3 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-03-23 1984-09-22 1985-03-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-03-23 1988-09-22 1989-03-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-03-23 1992-09-22 1993-03-24 $7700.00 Window Closed / Lapsed

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