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US4257972A Expired / Lapsed US ⏱️ 0.0 years remaining

Catalyst for producing polyhydric alcohols and derivatives

Assignee: Union Carbide Corp
•
Filing: 1979-07-31
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Granted: 1981-03-24
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Expires: 1999-07-31
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Abstract

Abstract A novel catalyst and process for the manufacture of polyhydric alcohol(s) from synthesis gas. This novel catalyst is a rhodium carbonyl phosphido cluster compound. In particular, the anion cluster of the rhodium carbonyl phosphido compound is of the following empirical formula: [Rh.sub.9 P (CO).sub.21 ].sup.-2

Inventors

  • 👤 Jose L. Vidal
  • 👤 Wellington E. Walker

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 12:13
CPC Classifications
B; B01; B01J; B01J31/00; B01J31/16; B01J31/20; B01J31/18; B01J31/1845; C; C07; C07C; C07C29/00; C07C29/15; C12; C12C; C12C11/00; C12C11/02; B01J2531/00; B01J2531/80; B01J2531/82; B01J2531/822; Y; Y02; Y02P; Y02P20/00; Y02P20/50; Y02P20/52

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 25 words
A rhodium carbonyl phosphido cluster compound which is the combination of an anion of the following empirical formula: [Rh.sub.9 P(CO).sub.21 ].sup.-2 associated with a cation.
Claim 2
Dependent Claim 25 words
A rhodium carbonyl phosphido cluster compound which is the combination of an anion of the following empirical formula: [Rh.sub.9 P(CO).sub.21 ].sup.-2 associated with a cation.
Claim 3
Dependent Claim 14 words
A rhodium carbonyl phosphido cluster compound of the following formula: Cs.sub.2 [Rh.sub.9 P(CO).sub.21 ].
Claim 4
Dependent Claim 14 words
A rhodium carbonyl phosphido cluster compound of the following formula: Cs.sub.2 [Rh.sub.9 P(CO).sub.21 ].
Claim 5
Dependent Claim 20 words
A rhodium carbonyl phosphido cluster compound of the following formula: [C.sub.6 H.sub.5 CH.sub.2 N(C.sub.2 H.sub.5).sub.3 ].sub.2 [Rh.sub.9 P(CO).sub.21 ]CH.sub.3 C(O)CH.sub.3.
Claim 6
Dependent Claim 20 words
A rhodium carbonyl phosphido cluster compound of the following formula: [C.sub.6 H.sub.5 CH.sub.2 N(C.sub.2 H.sub.5).sub.3 ].sub.2 [Rh.sub.9 P(CO).sub.21 ]CH.sub.3 C(O)CH.sub.3.

References Cited (Backward Citations)

US3948965A Cited
US4133776A Cited
US4115433A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-03-23 1984-09-22 1985-03-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-03-23 1988-09-22 1989-03-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-03-23 1992-09-22 1993-03-24 $7700.00 Window Closed / Lapsed

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