US4256867A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Novel vinyl ethers, process for their preparation, and their use for the preparation of polymers
Assignee: BASF Corp
•
Filing: 1979-09-04
•
Granted: 1981-03-17
•
Expires: 1999-09-04
Abstract
Abstract The present invention relates to new hydantoin vinyl ethers of the formula ##STR1## in which R 1 is hydrogen or an organic radical, R 2 is an alkylene group, and R 3 and R 4 are preferably lower alkyl groups. These compounds are used for the preparation of homopolymers and copolymers, which can be used as thickeners, solubilizing agents, binders, thixotropic agents, complexing agents, stabilizers and so forth.
Inventors
- 👤 Sameer H. Eldin
- 👤 Friedrich Stockinger
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 11:01
CPC Classifications
C; C07; C07D; C07D233/00; C07D233/54; C07D233/66; C07D233/72
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
147 words
An addition polymer which consists essentially of (a) from 0.005 to 100 mol percent of repeating units derived from a hydantoin vinyl ether of the formula I ##STR20## in which R 1 is hydrogen, phenyl, methyl, cyanoethyl, glycidyl, hydroxymethyl, hydroxyethyl, hydroxypropyl, acetyl, 2-hydroxy-2-phenyl-ether or ##STR21## R 2 is an alkylene group having 1 to 6 carbon atoms or the (-alkylene-O-)n-alkylene- group, in which the alkylene groups contain 1 to 6 carbon atoms and n is a number from 1 to 6, and R 3 and R 4 independently of one another are each hydrogen, an alkyl group having 1 to 6 carbon atoms, or together are a tetramethylene or pentamethylene group, and (b) from 99.995 to 0 mol percent of repeating units derived from one or two monomers selected from the group consisting of vinyl acetate, acrylonitrile, vinyl ethers, diketene, anhydrides of α,β-unsaturated dicarboxylic acids and styrene.
Claim 2
Dependent Claim
147 words
An addition polymer which consists essentially of (a) from 0.005 to 100 mol percent of repeating units derived from a hydantoin vinyl ether of the formula I ##STR20## in which R 1 is hydrogen, phenyl, methyl, cyanoethyl, glycidyl, hydroxymethyl, hydroxyethyl, hydroxypropyl, acetyl, 2-hydroxy-2-phenyl-ether or ##STR21## R 2 is an alkylene group having 1 to 6 carbon atoms or the (-alkylene-O-)n-alkylene- group, in which the alkylene groups contain 1 to 6 carbon atoms and n is a number from 1 to 6, and R 3 and R 4 independently of one another are each hydrogen, an alkyl group having 1 to 6 carbon atoms, or together are a tetramethylene or pentamethylene group, and (b) from 99.995 to 0 mol percent of repeating units derived from one or two monomers selected from the group consisting of vinyl acetate, acrylonitrile, vinyl ethers, diketene, anhydrides of α,β-unsaturated dicarboxylic acids and styrene.
Claim 3
Dependent Claim
13 words
A polymer according to claim 1 wherein the hydantoin vinyl ether is 3-(2-vinyloxyethyl)-5,5-dimethylhydantoin.
Claim 4
Dependent Claim
13 words
A polymer according to claim 1 wherein the hydantoin vinyl ether is 3-(2-vinyloxyethyl)-5-methyl-5-ethylhydantoin.
Claim 5
Dependent Claim
13 words
A polymer according to claim 1 wherein the hydantoin vinyl ether is 3-(2-vinyloxyethyl)-5,5-pentamethylenehydantoin.
Claim 6
Dependent Claim
16 words
A polymer according to claim 1 wherein the comonomer is styrene, acrylonitrile or a vinyl ether.
Claim 7
Dependent Claim
17 words
A polymer according to claim 1 wherein the comonomer is an anhydride of an α,β-unsaturated dicarboxylic acid.
Claim 8
Dependent Claim
12 words
A polymer according to claim 6 wherein the comonomer is maleic anhydride.
Claim 9
Dependent Claim
18 words
A polymer according to claim 1 wherein the molar ratio of component (a) to component (b) is 1:1.
Claim 10
Dependent Claim
30 words
A polymer according to claim 1 wherein component (b) is derived from two comonomers and the molar ratio of component (a) to the two comonomers of component (b) is 1:1:1.
Claim 11
Dependent Claim
17 words
A polymer according to claim 1 wherein two comonomers of component (b) are maleic anhydride and styrene.
References Cited (Backward Citations)
US2466177A
Cited
US3087853A
Cited
GB846601A
Cited
US3197477A
Cited
US3161538A
Cited
US3449353A
Cited
US3772326A
Cited
US3755350A
Cited
US3847776A
Cited
US3852302A
Cited
US4024146A
Cited
US3864358A
Cited
US3864357A
Cited
US4092479A
Cited
US4082635A
Cited
US4091223A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-03-16 | 1984-09-15 | 1985-03-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-03-16 | 1988-09-15 | 1989-03-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-03-16 | 1992-09-15 | 1993-03-17 | $7700.00 | Window Closed / Lapsed |