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US4256867A Expired / Lapsed US ⏱️ 0.0 years remaining

Novel vinyl ethers, process for their preparation, and their use for the preparation of polymers

Assignee: BASF Corp
•
Filing: 1979-09-04
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Granted: 1981-03-17
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Expires: 1999-09-04
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Abstract

Abstract The present invention relates to new hydantoin vinyl ethers of the formula ##STR1## in which R 1 is hydrogen or an organic radical, R 2 is an alkylene group, and R 3 and R 4 are preferably lower alkyl groups. These compounds are used for the preparation of homopolymers and copolymers, which can be used as thickeners, solubilizing agents, binders, thixotropic agents, complexing agents, stabilizers and so forth.

Inventors

  • 👤 Sameer H. Eldin
  • 👤 Friedrich Stockinger

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 11:01
CPC Classifications
C; C07; C07D; C07D233/00; C07D233/54; C07D233/66; C07D233/72

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 147 words
An addition polymer which consists essentially of (a) from 0.005 to 100 mol percent of repeating units derived from a hydantoin vinyl ether of the formula I ##STR20## in which R 1 is hydrogen, phenyl, methyl, cyanoethyl, glycidyl, hydroxymethyl, hydroxyethyl, hydroxypropyl, acetyl, 2-hydroxy-2-phenyl-ether or ##STR21## R 2 is an alkylene group having 1 to 6 carbon atoms or the (-alkylene-O-)n-alkylene- group, in which the alkylene groups contain 1 to 6 carbon atoms and n is a number from 1 to 6, and R 3 and R 4 independently of one another are each hydrogen, an alkyl group having 1 to 6 carbon atoms, or together are a tetramethylene or pentamethylene group, and (b) from 99.995 to 0 mol percent of repeating units derived from one or two monomers selected from the group consisting of vinyl acetate, acrylonitrile, vinyl ethers, diketene, anhydrides of α,β-unsaturated dicarboxylic acids and styrene.
Claim 2
Dependent Claim 147 words
An addition polymer which consists essentially of (a) from 0.005 to 100 mol percent of repeating units derived from a hydantoin vinyl ether of the formula I ##STR20## in which R 1 is hydrogen, phenyl, methyl, cyanoethyl, glycidyl, hydroxymethyl, hydroxyethyl, hydroxypropyl, acetyl, 2-hydroxy-2-phenyl-ether or ##STR21## R 2 is an alkylene group having 1 to 6 carbon atoms or the (-alkylene-O-)n-alkylene- group, in which the alkylene groups contain 1 to 6 carbon atoms and n is a number from 1 to 6, and R 3 and R 4 independently of one another are each hydrogen, an alkyl group having 1 to 6 carbon atoms, or together are a tetramethylene or pentamethylene group, and (b) from 99.995 to 0 mol percent of repeating units derived from one or two monomers selected from the group consisting of vinyl acetate, acrylonitrile, vinyl ethers, diketene, anhydrides of α,β-unsaturated dicarboxylic acids and styrene.
Claim 3
Dependent Claim 13 words
A polymer according to claim 1 wherein the hydantoin vinyl ether is 3-(2-vinyloxyethyl)-5,5-dimethylhydantoin.
Claim 4
Dependent Claim 13 words
A polymer according to claim 1 wherein the hydantoin vinyl ether is 3-(2-vinyloxyethyl)-5-methyl-5-ethylhydantoin.
Claim 5
Dependent Claim 13 words
A polymer according to claim 1 wherein the hydantoin vinyl ether is 3-(2-vinyloxyethyl)-5,5-pentamethylenehydantoin.
Claim 6
Dependent Claim 16 words
A polymer according to claim 1 wherein the comonomer is styrene, acrylonitrile or a vinyl ether.
Claim 7
Dependent Claim 17 words
A polymer according to claim 1 wherein the comonomer is an anhydride of an α,β-unsaturated dicarboxylic acid.
Claim 8
Dependent Claim 12 words
A polymer according to claim 6 wherein the comonomer is maleic anhydride.
Claim 9
Dependent Claim 18 words
A polymer according to claim 1 wherein the molar ratio of component (a) to component (b) is 1:1.
Claim 10
Dependent Claim 30 words
A polymer according to claim 1 wherein component (b) is derived from two comonomers and the molar ratio of component (a) to the two comonomers of component (b) is 1:1:1.
Claim 11
Dependent Claim 17 words
A polymer according to claim 1 wherein two comonomers of component (b) are maleic anhydride and styrene.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-03-16 1984-09-15 1985-03-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-03-16 1988-09-15 1989-03-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-03-16 1992-09-15 1993-03-17 $7700.00 Window Closed / Lapsed

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