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US4256779A Expired / Lapsed US ⏱️ 0.0 years remaining

Plasma spray method and apparatus

Assignee: United Technologies Metal Products Inc
•
Filing: 1979-06-11
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Granted: 1981-03-17
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Expires: 1999-06-11
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Abstract

Abstract A plasma spray method capable of directing plasticized powders against a substrate for deposition of a protective coating thereon is disclosed. Various structural details of the apparatus described enable the attainment of high particle velocities without melting the particles. The technical concepts employed are directed to normalizing the temperature of the plasma stream at a reduced value prior to the injection of coating particles. A general reduction in temperature and substantial elimination of a thermal spike at the core of the stream are achieved. Coating particles are injected into the plasma stream only after the plasma is first cooled and then preferably accelerated. In detailed embodiments, a nozzle extension assembly having a plasma cooling zone, a plasma acceleration zone, a powder injection zone and a plasma/powder discharge zone is affixed to the downstream end of a conventional plasma generator.

Inventors

  • 👤 Larry S. Sokol
  • 👤 Charles C. McComas
  • 👤 Earl M. Hanna

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 00:45
CPC Classifications
B; B05; B05B; B05B7/00; B05B7/16; B05B7/22; B05B7/222; B05B7/226; C; C23; C23C; C23C4/00; C23C4/12; C23C4/134

Claims Analysis

Total Claims: 27
Claim 1
Independent Claim 230 words
In a method for applying a high temperature capability material onto a substrate of the type in which the material to be applied is carried to the substrate in a high energy plasma stream, the improvement which comprises: providing a stream of high temperature plasma which is characterized by an average temperature in degrees Fahrenheit across the stream and a temperature spike at the center of the stream which has a magnitude approximately one-third (1/3) greater in degrees Fahrenheit than the average temperature; passing the high temperature plasma through an extended cooling zone of sufficient length and of sufficient cooling capacity to achieve an average plasma temperature reduction of approximately ten to fifteen percent (10-15%) as expressed in degrees Fahrenheit and a reduction in the magnitude of the temperature spike to within approximately fifteen percent (15%) as expressed in degrees Fahrenheit of the reduced average temperature; introducing powders of said high temperature capability material into the reduced temperature plasma stream; confining the plasma stream and introduced powders within an elongated passageway; accelerating and heating said introduced powders within the elongated passageway; further reducing the average temperature of the provided stream within the elongated passageway to approximately two-thirds (2/3) of the original provided average temperature as expressed in degrees Fahrenheit; and discharging said accelerated and heated powders from said elongated passageway and directing said powders against the substrate to be coated.
Claim 2
Dependent Claim 230 words
In a method for applying a high temperature capability material onto a substrate of the type in which the material to be applied is carried to the substrate in a high energy plasma stream, the improvement which comprises: providing a stream of high temperature plasma which is characterized by an average temperature in degrees Fahrenheit across the stream and a temperature spike at the center of the stream which has a magnitude approximately one-third (1/3) greater in degrees Fahrenheit than the average temperature; passing the high temperature plasma through an extended cooling zone of sufficient length and of sufficient cooling capacity to achieve an average plasma temperature reduction of approximately ten to fifteen percent (10-15%) as expressed in degrees Fahrenheit and a reduction in the magnitude of the temperature spike to within approximately fifteen percent (15%) as expressed in degrees Fahrenheit of the reduced average temperature; introducing powders of said high temperature capability material into the reduced temperature plasma stream; confining the plasma stream and introduced powders within an elongated passageway; accelerating and heating said introduced powders within the elongated passageway; further reducing the average temperature of the provided stream within the elongated passageway to approximately two-thirds (2/3) of the original provided average temperature as expressed in degrees Fahrenheit; and discharging said accelerated and heated powders from said elongated passageway and directing said powders against the substrate to be coated.
Claim 3
Dependent Claim 122 words
The method according to claim 1 wherein said step of providing a stream of high temperature plasma includes the step of providing a stream which is characterized by an average temperature across the stream of approximately fifteen thousand degrees Fahrenheit (15,000° F.) and a temperature spike at the center of the stream in excess of twenty thousand degrees Fahrenheit (20,000° F.); and wherein said step of reducing the average temperature of the provided stream includes the steps of reducing the average temperature of the provided stream to approximately thirteen thousand degrees Fahrenheit (13,000° F.), and reducing the magnitude of the temperature spike at the center of the stream to within approximately two thousand degrees Fahrenheit (2000° F.) of the reduced average temperature.
Claim 4
Dependent Claim 31 words
The method according to claim 1 or 2 which includes the step of accelerating said reduced temperature plasma prior to the step of introducing powders of said high temperature capability material.
Claim 5
Dependent Claim 38 words
The method according to claim 3 wherein the step of accelerating said reduced temperature plasma includes the step of accelerating said reduced temperature plasma to a velocity of approximately eleven to fourteen thousand feet per second (11,000-14,000 fps).
Claim 6
Dependent Claim 261 words
In a plasma generator and spray device of the type for depositing particles of coating material on a substrate and of the type in which the particles of coating material are heated and accelerated by a plasma stream generated within the device, the improvement which comprises: a plasma generator capable of producing a columnar stream of plasma effluent at an average plasma velocity within the stream which is approximately two thousand feet per second (2000 fps) and at an average plasma temperature which is approximately fifteen thousand degrees Fahrenheit (15,000° F.); and a coolable nozzle having an elongated passageway therethrough which is adapted to receive said plasma effluent having an average velocity of approximately two thousand feet per second (2000 fps) and an average temperature of approximately fifteen thousand degrees Fahrenheit (15,000° F.) wherein said nozzle has means having sufficient length and sufficient cooling capacity at the upstream end of the passageway for reducing the average temperature of the plasma stream, means along the passageway immediately downstream of said temperature reducing means for accelerating the reduced temperature plasma to an average velocity in excess of the average velocity of the plasma at the upstream end of said temperature reducing means, means along the passageway immediately downstream of said accelerating means for admitting particles of coating material into said cooled and accelerated plasma, and means along the passageway immediately downstream of said particle admitting means for confining said particles within the cooled and accelerated plasma stream for a sufficient time interval to enable the particles to be heated to a plasticized state.
Claim 7
Dependent Claim 261 words
In a plasma generator and spray device of the type for depositing particles of coating material on a substrate and of the type in which the particles of coating material are heated and accelerated by a plasma stream generated within the device, the improvement which comprises: a plasma generator capable of producing a columnar stream of plasma effluent at an average plasma velocity within the stream which is approximately two thousand feet per second (2000 fps) and at an average plasma temperature which is approximately fifteen thousand degrees Fahrenheit (15,000° F.); and a coolable nozzle having an elongated passageway therethrough which is adapted to receive said plasma effluent having an average velocity of approximately two thousand feet per second (2000 fps) and an average temperature of approximately fifteen thousand degrees Fahrenheit (15,000° F.) wherein said nozzle has means having sufficient length and sufficient cooling capacity at the upstream end of the passageway for reducing the average temperature of the plasma stream, means along the passageway immediately downstream of said temperature reducing means for accelerating the reduced temperature plasma to an average velocity in excess of the average velocity of the plasma at the upstream end of said temperature reducing means, means along the passageway immediately downstream of said accelerating means for admitting particles of coating material into said cooled and accelerated plasma, and means along the passageway immediately downstream of said particle admitting means for confining said particles within the cooled and accelerated plasma stream for a sufficient time interval to enable the particles to be heated to a plasticized state.
Claim 8
Dependent Claim 41 words
The invention according to claim 5 wherein the cross sectional area of said passageway is reduced across the means for accelerating the cooled plasma to approximately one-fourth (1/4) of the cross sectional area of said passageway at the temperature reducing means.
Claim 9
Dependent Claim 37 words
The invention according to claim 6 wherein the cross sectional area of the passageway at said confining means is approximately six (6) times greater than the cross sectional area of the passageway at said particle admitting means.
Claim 10
Dependent Claim 78 words
The apparatus according to claim 7 wherein said generator includes a pintle shaped cathode and an anode having a cylindrical wall to which an electric arc is struck in the plasma generation process and through which the generated plasma stream is flowable, and wherein the passageway at said means for reducing the temperature of the generated plasma has a cross sectional area which is larger than the cross sectional area bounded by said cylindrical wall of the anode.
Claim 11
Dependent Claim 42 words
The apparatus according to claim 7 wherein said passageway at the temperature reducing means has an approximate two hundred eighty seven thousandths of an inch (0.287 in.) diameter, circular cross section geometry, and has an approximate one inch (1 in.) axial length.
Claim 12
Dependent Claim 60 words
The apparatus according to claim 9 wherein said passageway at the accelerating means has an approximate two hundred eighty seven thousandths of an inch (0.287 in.) diameter, circular cross section geometry, at the upstream end thereof and has an approximate one hundred fifty two thousandths of an inch (0.152 in.) diameter, circular cross section geometry at the downstream end thereof.
Claim 13
Dependent Claim 55 words
The apparatus according to claim 10 wherein said passageway at the particle admitting means has an approximate one hundred fifty two thousandths of an inch (0.152 in.) diameter, circular cross section geometry and at least one aperture along said passageway through which particles of said coating material are flowable into said cooled and accelerated plasma.
Claim 14
Dependent Claim 20 words
The apparatus according to claim 11 which includes two of said apertures located in diametrically opposed relationships along said passageway.
Claim 15
Dependent Claim 36 words
The apparatus according to claim 11 or 12 wherein said passageway at the confining means has a circular cross section geometry of a diameter in excess of the diameter of the passageway at the admitting means.
Claim 16
Dependent Claim 27 words
The apparatus according to claim 13 wherein said passageway at the confining means has a diameter of approximately three hundred seventy thousandths of an inch (0.370 in.).
Claim 17
Dependent Claim 34 words
The apparatus according to claim 13 wherein said passageway at the confining means extends to a distance of approximately one inch (1 in.) downstream of the apertures through which said coating particles are admitted.
Claim 18
Dependent Claim 34 words
The apparatus according to claim 14 wherein said passageway of the confining means extends to a distance of approximately one inch (1 in.) downstream of the apertures through which said coating particles are admitted.
Claim 19
Dependent Claim 42 words
The apparatus according to claim 8 wherein said passageway at the temperature reducing means has an approximate two hundred eighty seven thousandths of an inch (0.287 in.) diameter, circular cross section geometry, and has an approximate one inch (1 in.) axial length.
Claim 20
Dependent Claim 60 words
The apparatus according to claim 17 wherein said passageway at the accelerating means has an approximate two hundred eighty seven thousandths of an inch (0.287 in.) diameter, circular cross section geometry, at the upstream end thereof and has an approximate one hundred fifty two thousandths of an inch (0.152 in.) diameter, circular cross section geometry at the downstream end thereof.
Claim 21
Dependent Claim 55 words
The apparatus according to claim 18 wherein said passageway at the particle admitting means has an approximate one hundred fifty two thousandths of an inch (0.152 in.) diameter, circular cross section geometry and at least one aperture along said passageway through which particles of said coating material are flowable into said cooled and accelerated plasma.
Claim 22
Dependent Claim 20 words
The apparatus according to claim 19 which includes two of said apertures located in diametrically opposed relationships along said passageway.
Claim 23
Dependent Claim 36 words
The apparatus according to claim 19 or 20 wherein said passageway at the confining means has a circular cross section geometry of a diameter in excess of the diameter of the passageway at the admitting means.
Claim 24
Dependent Claim 27 words
The apparatus according to claim 21 wherein said passageway at the confining means has a diameter of approximately three hundred seventy thousandths of an inch (0.370 in.).
Claim 25
Dependent Claim 34 words
The apparatus according to claim 21 wherein said passageway at the confining means extends to a distance of approximately one inch (1 in.) downstream of the apertures through which said coating particles are admitted.
Claim 26
Dependent Claim 34 words
The apparatus according to claim 22 wherein said passageway of the confining means extends to a distance of approximately one inch (1 in.) downstream of the apertures through which said coating particles are admitted.
Claim 27
Dependent Claim 43 words
The apparatus according to claim 7, 8, 9 or 10 wherein said means for accelerating the reduced temperature plasma is capable of accelerating said reduced temperature plasma to a velocity of approximately eleven to fourteen thousand feet per second (11,000 to 14,000 fps).

References Cited (Backward Citations)

US2960594A Cited
US3010009A Cited
US3075065A Cited
US3145287A Cited
US3301995A Cited
US3676638A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-03-16 1984-09-15 1985-03-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-03-16 1988-09-15 1989-03-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-03-16 1992-09-15 1993-03-17 $7700.00 Window Closed / Lapsed

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