Polyurethane polymers characterized by carboxylate groups and hydroxyl groups in the polymer backbone

Claim 2

A water insoluble polyurethane polyether resin that is soluble in ethanol at pH 11, containing carboxylic acid groups and hydroxyl groups in the polymer backbone, the number of hydroxyl groups in the polymer backbone being at least equal to the number of carboxylic acid groups; said polyurethane polyether being characterized by a molecular weight above 6,000.

Claim 3

A water insoluble salt of the polyurethane polyether resin of claim 1.

Claim 4

The water insoluble polyurethane polyether resin of claim 2 wherein said salt is a quaternary ammonium salt.

Claim 5

The water insoluble polyurethane polyether resin of claim 3 wherein said quaternary ammonium salt is an ammonium salt.

Claim 6

The water insoluble polyurethane polyether resin of claim 2 wherein said salt is an alkali metal salt.

Claim 7

A water insoluble polyurethane polyether resin that is soluble in ethanol at pH 11 containing a hydroxyl group and a carboxylate radical selected from the group consisting of carboxylic acid and salts thereof in the polymer backbone, the number of hydroxyl groups in the polymer backbone being at least equal to the number of said carboxylate radicals, said polyurethane polyether resin being characterized by a molecular weight above 6,000; obtained by: (1) Reacting to form a lactone polymer (a) A polyfunctional lactone selected from group consisting of (i) lactones having the formula: ##STR3## wherein R 1 is a monovalent radical selected from the group consisting of --H, CH 2 NH 2 , --SO 2 CH 3 ,--CHOHCOOH, and --(CHOH) n CH 2 OH; n being an integer from 0 to 5; and R is a divalent radical --(CHOH) m --; m being an integer from 3 to 10 and (ii) D-glucuronolactone; (b) One or more diols having an equivalent weight in the range of from about 100 to 3,000 selected from the group consisting of (1) diethylene glycol, (ii) long chain polyalkylene diols, (iii) linear polyester diols derived from the condensation of one or more diols with one or more dibasic acids; and (iv) the reaction product of one or more alkylene diols with a difunctional linear polyester derived from the condensation of one or more diols with one or more dibasic acids; and (c) A urethane precursor selected from the group consisting of (i) organic polyisocyanates and (ii) nitrile carbonates. (2) Dissolving the lactone polymer so obtained in a mixture of a water miscible organic solvent and an aqueous base to form a solution; and (3) Precipitating said polyurethane polyether resin containing a hydroxyl group and a carboxylate radical by pouring the solution into an excess of water with stirring.

Claim 8

A water insoluble polyurethane polyether resin that is soluble in ethanol at pH 11 containing a hydroxyl group and a carboxylate radical selected from the group consisting of carboxylic acid and salts thereof in the polymer backbone, the number of hydroxyl groups in the polymer backbone being at least equal to the number of said carboxylate radicals, said polyurethane polyether resin being characterized by a molecular weight above 6,000; obtained by: (1) Reacting to form a lactone polymer (a) A polyfunctional lactone selected from group consisting of (i) lactones having the formula: ##STR3## wherein R 1 is a monovalent radical selected from the group consisting of --H, CH 2 NH 2 , --SO 2 CH 3 ,--CHOHCOOH, and --(CHOH) n CH 2 OH; n being an integer from 0 to 5; and R is a divalent radical --(CHOH) m --; m being an integer from 3 to 10 and (ii) D-glucuronolactone; (b) One or more diols having an equivalent weight in the range of from about 100 to 3,000 selected from the group consisting of (1) diethylene glycol, (ii) long chain polyalkylene diols, (iii) linear polyester diols derived from the condensation of one or more diols with one or more dibasic acids; and (iv) the reaction product of one or more alkylene diols with a difunctional linear polyester derived from the condensation of one or more diols with one or more dibasic acids; and (c) A urethane precursor selected from the group consisting of (i) organic polyisocyanates and (ii) nitrile carbonates. (2) Dissolving the lactone polymer so obtained in a mixture of a water miscible organic solvent and an aqueous base to form a solution; and (3) Precipitating said polyurethane polyether resin containing a hydroxyl group and a carboxylate radical by pouring the solution into an excess of water with stirring.

Claim 9

The polyurethane polyether resin of claim 6 wherein said resin is obtained by reacting a polyfunctional lactone with a long chain polyalkylene diol and a urethane precursor.

Claim 10

The polyurethane polyether resin of claim 7 wherein said polyfunctional lactone is delta gluconolactone.

Claim 11

The polyurethane polyether resin of claim 7 wherein said urethane precursor is methylene di(cyclohexyl isocyanate).

Claim 12

The polyurethane polyether resin of claim 7 wherein said polyalkylene diol is polyethylene diol.

Claim 13

A burn dressing comprising the polyether polyurethane resin of claim 1 in the form of a sterile film.

Claim 14

A surgical drape comprising the polyether polyurethane resin of claim 1 in the form of a sheet.