US4253849A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Granulation of sodium metasilicate
Assignee: Rhone Poulenc Industries SA
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Filing: 1978-09-26
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Granted: 1981-03-03
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Expires: 1998-09-26
Abstract
Abstract Sodium metasilicate is granulated by (i) establishing, in a first zone, a cloud of anhydrous sodium metasilicate powder; (ii) injecting into said cloud (i), and intimately contacting therewith, an atomized liquid phase which comprises a liquid formulation of a sodium silicate; (iii) said intimate contacting (ii) being conducted in an atmosphere of a drying gas, whereby crystallization of the anhydrous metasilicate and agglomeration of the thus coated particulates are effected, (iv) next subjecting the effluent cohered granules of said first zone to a state of agitation in a second discrete zone, in an atmosphere of a heating gas and whereby the agitated granules are at least partially converted to the sodium metasilicate pentahydrate; (v) and thence recovering from said second discrete zone a granular sodium metasilicate comprising from about 2 to 6% by weight water, and useful in the manufacture of a variety of detergent compositions.
Inventors
- 👤 Georges Vrisakis
- 👤 Jacques Chastel
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 00:36
CPC Classifications
C; C01; C01B; C01B33/00; C01B33/20; C01B33/32; C01B33/325
Claims Analysis
Total Claims: 21
Claim 1
Independent Claim
210 words
A process for the granulation of sodium metasilicate, comprising (i) establishing, in a first zone, a cloud of anhydrous sodium metasilicate powder; (ii) injecting into said cloud (i), and intimately contacting therewith, an atomized liquid phase which comprises a liquid formulation of a sodium silicate; (iii) said intimate contacting (ii) being conducted in an atmosphere of a drying gas heated to a drying but non-flashing temperature of between about 200° C. and 500° C., whereby crystallization of the anhydrous metasilicate and agglomeration of the thus coated particulates are effected; (iv) next subjecting the effluent cohered granules of said first zone to a state of agitation in a second discrete zone, in an atmosphere of a heating gas having an average temperature of from greater than 42° C. to less than 72° C., which is less than the temperature of the drying gas in said first zone and less than the crystallization temperature of sodium metasilicate pentahydrate and whereby the agitated granules are at least partially converted to the sodium metasilicate pentahydrate; (v) and thence recovering from said second discrete zone a granular sodium metasilicate comprising from about 2 to 6% by weight water with from about 55-80% by weight of this water being in the form of sodium metasilicate pentahydrate.
Claim 2
Dependent Claim
210 words
A process for the granulation of sodium metasilicate, comprising (i) establishing, in a first zone, a cloud of anhydrous sodium metasilicate powder; (ii) injecting into said cloud (i), and intimately contacting therewith, an atomized liquid phase which comprises a liquid formulation of a sodium silicate; (iii) said intimate contacting (ii) being conducted in an atmosphere of a drying gas heated to a drying but non-flashing temperature of between about 200° C. and 500° C., whereby crystallization of the anhydrous metasilicate and agglomeration of the thus coated particulates are effected; (iv) next subjecting the effluent cohered granules of said first zone to a state of agitation in a second discrete zone, in an atmosphere of a heating gas having an average temperature of from greater than 42° C. to less than 72° C., which is less than the temperature of the drying gas in said first zone and less than the crystallization temperature of sodium metasilicate pentahydrate and whereby the agitated granules are at least partially converted to the sodium metasilicate pentahydrate; (v) and thence recovering from said second discrete zone a granular sodium metasilicate comprising from about 2 to 6% by weight water with from about 55-80% by weight of this water being in the form of sodium metasilicate pentahydrate.
Claim 3
Dependent Claim
22 words
The process as defined in claim 1, wherein the average temperature of the heating gas is no greater than about 65° C.
Claim 4
Dependent Claim
28 words
The process as defined by claim 2, wherein the temperature of the drying gas at the outlet of said first zone is between about 50° and 130° C.
Claim 5
Dependent Claim
17 words
The process as defined in claim 3, wherein the drying gas is essentially free of carbon dioxide.
Claim 6
Dependent Claim
14 words
The process as defined by claim 3, wherein the heating gas is hot air.
Claim 7
Dependent Claim
22 words
The process as defined by claim 1, wherein the retention time in the second zone is between about 5 and 30 minutes.
Claim 8
Dependent Claim
29 words
The process as defined by claim 1, wherein the liquid formulation of a sodium silicate defining the atomized liquid phase is comprised of anhydrous sodium metasilicate dissolved in water.
Claim 9
Dependent Claim
30 words
The process as defined by claim 1, wherein the liquid formulation of a sodium silicate defining the atomized liquid phase is comprised of a sodium silicate treated with sodium hydroxide.
Claim 10
Dependent Claim
30 words
The process as defined by claims 1, 3 or 2, wherein the granules cohered in said first zone have a water content of between about 1 and 8% by weight.
Claim 11
Dependent Claim
26 words
The process as defined by claim 1, wherein said liquid formulation displays a weight ratio of formulated silicate to anhydrous, ungranulated powder of at least 20/100.
Claim 12
Dependent Claim
28 words
The process as defined by claim 1, further comprising recycling a portion of the granular metasilicate recovered in the step (v) as feed to the said first zone.
Claim 13
Dependent Claim
26 words
The process as defined by claim 11, wherein the amount of product recycled per amount of final product recovered, by weight, ranges between 20 and 80.
Claim 14
Dependent Claim
16 words
The process as defined by claim 12, the recycle ratio being on the order of 40/60.
Claim 15
Dependent Claim
44 words
The process as defined by claim 1, wherein the temperature of the drying gas at the outlet of said first zone is between about 50° and 70° C., and the recovered granular sodium metasilicate comprises from about 3 to 6% by weight of water.
Claim 16
Dependent Claim
36 words
The process as defined by claim 1, wherein the said cohered granules are concomitantly treated in said second zone with an additive selected from the group comprising citric acid, a phosphorus compound and a gluconic compound.
Claim 17
Dependent Claim
27 words
The process as defined by claim 1, wherein the said cloud of metasilicate powder is established essentially entirely in the upstream end of the said first zone.
Claim 18
Dependent Claim
23 words
The process as defined by claim 1, wherein both the said first and said second zones are defined by a rotating granulator drum.
Claim 19
Dependent Claim
29 words
The process as defined by claim 1, wherein the drying gas is charged concurrently through said first zone, and said heating gas is charged countercurrently through said second zone.
Claim 20
Dependent Claim
28 words
The process as defined by claim 1, wherein the anhydrous powder feed to the said first zone has an average particle diameter on the order of 0.15 mm.
Claim 21
Dependent Claim
13 words
The product of the process as defined by claims 1, 11 or 15.
References Cited (Backward Citations)
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Cited
FR1100817A
Cited
US3227789A
Cited
US3208822A
Cited
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Cited
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Cited
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-03-02 | 1984-09-01 | 1985-03-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-03-02 | 1988-09-01 | 1989-03-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-03-02 | 1992-09-01 | 1993-03-03 | $7700.00 | Window Closed / Lapsed |