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US4252777A Expired / Lapsed US ⏱️ 0.0 years remaining

Recovery of aluminum and other metal values from fly ash

Assignee: United States Department of Energy
•
Filing: 1979-11-01
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Granted: 1981-02-24
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Expires: 1999-11-01
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Abstract

Abstract The invention described herein relates to a method for improving the acid leachability of aluminum and other metal values found in fly ash which comprises sintering the fly ash, prior to acid leaching, with a calcium sulfate-containing composition at a temperature at which the calcium sulfate is retained in said composition during sintering and for a time sufficient to quantitatively convert the aluminum in said fly ash into an acid-leachable form.

Inventors

  • 👤 William J. McDowell
  • 👤 Forest G. Seeley

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 13:18
CPC Classifications
C; C01; C01F; C01F7/00; C01F7/02; C01F7/20; C01F7/26; C01F7/68; C01F7/74; C01F7/741; C22; C22B; C22B21/00; C22B21/0007

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 65 words
A method for improving the acid leachability of aluminum and other metal values found in fly ash which comprises sintering the fly ash, prior to acid leaching, with a calcium sulfate-containing composition at a temperature at which the calcium sulfate is retained in said composition during sintering and for a time sufficient to quantitatively convert the aluminum in said fly ash into an acid-leachable form.
Claim 2
Independent Claim 65 words
A method for improving the acid leachability of aluminum and other metal values found in fly ash which comprises sintering the fly ash, prior to acid leaching, with a calcium sulfate-containing composition at a temperature at which the calcium sulfate is retained in said composition during sintering and for a time sufficient to quantitatively convert the aluminum in said fly ash into an acid-leachable form.
Claim 3
Dependent Claim 17 words
The method according to claim 1 in which the sintering temperature is in the range 800°-1300° C.
Claim 4
Dependent Claim 45 words
The method according to claim 1 in which the calcium sulfate-containing composition is selected from the group consisting of calcium sulfate, mixtures of calcium sulfate with magnesium sulfate or calcium carbonate or the sludge resulting from treating SO 2 -containing effluents with lime or limestone.
Claim 5
Dependent Claim 18 words
The method according to claim 1 in which the acid leachant is sulfuric acid and aqueous solutions thereof.
Claim 6
Dependent Claim 18 words
The method according to claim 1 in which the acid leachant is nitric acid or aqueous solutions thereof.
Claim 7
Dependent Claim 18 words
The method according to claim 1 in which the acid leachant is hydrochloric acid or aqueous mixtures thereof.

References Cited (Backward Citations)

US1310413A Cited
US1125007A Cited
US1170418A Cited
US1178384A Cited
US1891608A Cited
US2174825A Cited
US4024220A Cited
US4113833A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-02-24 1984-08-25 1985-02-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-02-24 1988-08-25 1989-02-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-02-24 1992-08-25 1993-02-24 $7700.00 Window Closed / Lapsed

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