US4252743A
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Quaternaries of halogen derivatives of alkynoxymethyl amines
Assignee: Baker Hughes Holdings LLC
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Filing: 1978-11-03
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Granted: 1981-02-24
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Expires: 1998-11-03
Abstract
Abstract This invention relates to quaternaries of halogen derivatives of alkynoxymethyl amines and uses thereof. These may be summarized by the following formulae: ##STR1## where R and R' are substituted groups such as alkyl, aryl, etc.; R" is an alkyldene group; and X is halogen and A is an anion; and ##STR2## where R, R' and R" having the same meaning as in (1) and Z is a bridging group, preferably hydrocarbon such as alkylene, alkinylene, alkenylene, arylene, etc.
Inventors
- 👤 Patrick M. Quinlan
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 23:16
CPC Classifications
A; A01; A01N; A01N33/00; A01N33/02; A01N33/12; C; C02; C02F; C02F1/00; C02F1/50; C23; C23F; C23F11/00; C23F11/04; C23G; C23G1/00; C23G1/02; C23G1/04; C23G1/06; C23G1/068
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
162 words
Quaternaries of halo alkynoxymethyl amines having one to two quaternary nitrogen atoms to each of which are attached up to two halogen derivatives of alkynoxymethyl moieties of the formula XC.tbd.CR"OCH 2 -- where R" is alkylidene and X is halogen, the groups directly attached to the quaternary nitrogen atoms in the said quaternary amines being said halo alkynoxymethyl groups and being R and R' groups when there is but one quaternary nitrogen atom present per molecule and being said halo alkynoxymethyl groups and being R and Z groups when there are two quaternary nitrogen atoms present per molecule, the Z groups constituting bridging groups linking the two quaternary nitrogen atoms, the R groups being monovalent hydrocarbon, hydroxy substituted alkyl or furfuryl groups, the R' groups being monovalent hydrocarbon of up to 30 carbon atoms and the Z groups being divalent alkylene, alkenylene, alkynylene, hydrocarbon alkaralkylene, or alkylenether groups, the counter anions balancing the positive charge on the quaternary nitrogen being halide anions.
Claim 2
Dependent Claim
162 words
Quaternaries of halo alkynoxymethyl amines having one to two quaternary nitrogen atoms to each of which are attached up to two halogen derivatives of alkynoxymethyl moieties of the formula XC.tbd.CR"OCH 2 -- where R" is alkylidene and X is halogen, the groups directly attached to the quaternary nitrogen atoms in the said quaternary amines being said halo alkynoxymethyl groups and being R and R' groups when there is but one quaternary nitrogen atom present per molecule and being said halo alkynoxymethyl groups and being R and Z groups when there are two quaternary nitrogen atoms present per molecule, the Z groups constituting bridging groups linking the two quaternary nitrogen atoms, the R groups being monovalent hydrocarbon, hydroxy substituted alkyl or furfuryl groups, the R' groups being monovalent hydrocarbon of up to 30 carbon atoms and the Z groups being divalent alkylene, alkenylene, alkynylene, hydrocarbon alkaralkylene, or alkylenether groups, the counter anions balancing the positive charge on the quaternary nitrogen being halide anions.
Claim 3
Dependent Claim
28 words
The quaternaries of claim 1 having the formula ##STR36## where R and R' are hydrocarbon groups, R" is alkylidine, X is halogen and Y.sup.⊖ is a halide anion.
Claim 4
Dependent Claim
33 words
The quaternaries of claim 1 having the formula ##STR37## where R and R' are hydrocarbon group; R" is alkylidene, X is halogen, Y.sup.⊖ is a halide anion, and Z is a bridging group.
Claim 5
Dependent Claim
20 words
The quaternaries of claim 2 where R and R' are alkyl, hydrocarbon aryl, or hydrocarbon aralkyl, and R" is alkylidene.
Claim 6
Dependent Claim
20 words
The quaternaries of claim 3 where R and R' are alkyl, hydrocarbon aryl, or hydrocarbon aralkyl, and R" is alkylidene.
Claim 7
Dependent Claim
64 words
The quaternaries of claim 2 having the formula ##STR38## where X is halogen, Y.sup.⊖ is a halide anion, where R is alkyl of 3 to 18 carbon atoms, benzyl, or cyclohexyl, R' is alkyl or alkenyl containing up to 30 carbon atoms, or benzyl, R 3 is CH 3 or H and R 4 is hydrogen or alkyl containing up to 18 carbon atoms.
Claim 8
Dependent Claim
108 words
The quaternaries of claim 3 having the formula ##STR39## where X is halogen, Y.sup.⊖ is a halide anion, where R and R' are each alkyl of 3 to 18 carbon atoms, benzyl or cyclohexyl, Z is alkylene containing 2 to 25 carbon atoms or hydrocarbon alkaralkylene containing 8 to 30 carbon atoms or is an alkylenether radical A(OA) n where A is alkylene containing 1 to 10 carbon atoms, and n is 1 to 10, or is an unsaturated aliphatic radical containing up to 4 carbon atoms, R 3 is hydrogen or CH 3 , and R 4 is hydrogen or hydrocarbon containing up to 18 carbon atoms.
Claim 9
Dependent Claim
9 words
The quaternary of claim 6 having the formula ##STR40##
Claim 10
Dependent Claim
9 words
The quaternary of claim 7 having the formula ##STR41##
Claim 11
Dependent Claim
160 words
Quaternaries of halo alkynoxymethyl amines having one to two quaternary nitrogen atoms to each of which are attached up to two halogen derivatives of alkynoxymethyl moieties of the formula XC.tbd.CR"OCH 2 -- where R" is alkylidene and X is halogen, the groups directly attached to the quaternary nitrogen atoms in the said quaternary amines being said halo alkynoxymethyl groups and being R and R' groups when there is but one quaternary nitrogen atom present per molecule and being said halo alkynoxymethyl groups and being R and Z groups when there are two quaternary nitrogen atoms present per molecule, the Z groups constituting bridging groups linking the two quaternary nitrogen atoms, each R group being monovalent hydrocarbon, hydroxy substituted alkyl or furfuryl, each R' group being monovalent hydrocarbon of up to 30 carbon atoms and each Z group being divalent alkylene, alkenylene, alkynylene, hydrocarbon alkaralkylene, or alkylenether, the counter anions balancing the positive charge on the quaternary nitrogen being halide anions.
Claim 12
Dependent Claim
160 words
Quaternaries of halo alkynoxymethyl amines having one to two quaternary nitrogen atoms to each of which are attached up to two halogen derivatives of alkynoxymethyl moieties of the formula XC.tbd.CR"OCH 2 -- where R" is alkylidene and X is halogen, the groups directly attached to the quaternary nitrogen atoms in the said quaternary amines being said halo alkynoxymethyl groups and being R and R' groups when there is but one quaternary nitrogen atom present per molecule and being said halo alkynoxymethyl groups and being R and Z groups when there are two quaternary nitrogen atoms present per molecule, the Z groups constituting bridging groups linking the two quaternary nitrogen atoms, each R group being monovalent hydrocarbon, hydroxy substituted alkyl or furfuryl, each R' group being monovalent hydrocarbon of up to 30 carbon atoms and each Z group being divalent alkylene, alkenylene, alkynylene, hydrocarbon alkaralkylene, or alkylenether, the counter anions balancing the positive charge on the quaternary nitrogen being halide anions.
References Cited (Backward Citations)
US4012446A
Cited
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1984-02-24 | 1984-08-25 | 1985-02-24 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-02-24 | 1988-08-25 | 1989-02-24 | $3760.00 | Window Closed / Lapsed |
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