Polyimide oligomers

Claim 2

A product selected from the group consisting of: A. An acetylene end-capped polyimide oligomer having the structure: ##STR11## where R has the structure: ##STR12## where X is ##STR13## or a bond, and where R' is selected from the group consisting of a phenylene group, a naphthylene group, or ##STR14## where X is as defined above; and where R" is an aryl group bearing a substituent having the structure: ##STR15## B. A first precursor of an acetylene end-capped polyimide oligomer of (A) having the structure: ##STR16## where R, R' and R" are as defined above; and C. A second precursor of an acetylene end-capped polyimide oligomer of (A) having the structure: ##STR17## where R, R' and R" are as defined above and R''' is the alcohol moiety from which the diester of the aromatic tetracarboxylic acid was prepared, and where in each of the above formulas n has an average value from 1 to about 4.

Claim 3

An acetylene end-capped polyimide oligomer having the structure: ##STR18## where R has the structure: ##STR19## where X is ##STR20## or a bond, and where R' is selected from the group consisting of a phenylene group, a naphthylene group, or ##STR21## where X is as defined above; and where R" is an aryl group bearing a substituent having the structure: ##STR22## and where n has a value of from 1 to about 4.

Claim 4

An acetylene end-capped polyimide oligomer having the structure: ##STR18## where R has the structure: ##STR19## where X is ##STR20## or a bond, and where R' is selected from the group consisting of a phenylene group, a naphthylene group, or ##STR21## where X is as defined above; and where R" is an aryl group bearing a substituent having the structure: ##STR22## and where n has a value of from 1 to about 4.

Claim 5

A precursor of an acetylene end-capped polyimide oligomer having the structure: ##STR23## where R has the structure: ##STR24## where X is ##STR25## or a bond; where R' is selected from the group consisting of a phenylene group, a naphthylene group, or ##STR26## where X is as defined above; and where R" is an aryl group bearing a substituent having the structure: ##STR27## and where n has a value of from 1 to about 4.

Claim 6

A precursor of an acetylene end-capped polyimide oligomer having the structure: ##STR23## where R has the structure: ##STR24## where X is ##STR25## or a bond; where R' is selected from the group consisting of a phenylene group, a naphthylene group, or ##STR26## where X is as defined above; and where R" is an aryl group bearing a substituent having the structure: ##STR27## and where n has a value of from 1 to about 4.

Claim 7

A precursor of an acetylene end-capped polyimide oligomer having the structure: ##STR28## where R has the structure: ##STR29## where X is ##STR30## or a bond; where R' is selected from the group consisting of a phenylene group, a naphthylene group, or ##STR31## where X is as defined above; where R" is an aryl group bearing a substituent having the structure: ##STR32## and where R''' is the alcohol moiety from which the diester of the aromatic tetracarboxylic acid was prepared, and where n has a value of from 1 to about 4.

Claim 8

A precursor of an acetylene end-capped polyimide oligomer having the structure: ##STR28## where R has the structure: ##STR29## where X is ##STR30## or a bond; where R' is selected from the group consisting of a phenylene group, a naphthylene group, or ##STR31## where X is as defined above; where R" is an aryl group bearing a substituent having the structure: ##STR32## and where R''' is the alcohol moiety from which the diester of the aromatic tetracarboxylic acid was prepared, and where n has a value of from 1 to about 4.

Claim 9

A product of claim 1, 2, 3, or 4 in which R has the structure: ##STR33## and where R" has the structure: ##STR34##

Claim 10

A process for preparing a product of claim 3 which consists essentially of: a. Dissolving at least 17 weight % of an aromatic tetracarboxylic acid dianhydride in a solvent at a temperature of at least 60° C., b. Maintaining a solution of step (a) containing substantially 1 molar portion of said aromatic tetracarboxylic acid dianhydride at a temperature in a range of about 30°-100° C. and adding substantially 0.50 molar portion of an aromatic diamine thereto and forming a reaction product consisting essentially of a chemical having the structure: ##STR35## c. Adding substantially 1.0 molar portion of an aromatic monoamine to the product of step (b) and forming a reaction product consisting essentially of a chemical having the structure: ##STR36## said aromatic tetracarboxylic acid dianhydride having the formula: ##STR37## where R has the structure: ##STR38## where X is ##STR39## or a bond; said aromatic diamine having the formula: H.sub.2 N--R'--NH.sub.2 where R 1 is selected from the group consisting of a phenylene group, a naphthylene group, or ##STR40## where X is as defined above; and said aromatic monoamine having the formula: R"--NH.sub.2 ; where R" is an aryl group bearing a substituent having the structure: ##STR41## and the solvent employed in step (a) is selected from the group consisting of N-methyl-2-pyrrolidone, cyclohexanone, diethyl carbonate, and gamma-butyrolactone, and where in each of the above formulas n has an average value from 1 to about 4.

Claim 11

A process for preparing a product of claim 4 which consists essentially of: a. Adding, with stirring, a solution containing substantially 0.50 molar portion of an aromatic diamine to a solution containing substantially 1.0 molar portion of a dialkyl ester of an aromatic tetracarboxylic acid, and b. Adding substantially 1.0 molar portion of an aromatic monoamine to the solution of (a); said dialkyl ester of the aromatic tetracarboxylic acid having the formula: ##STR42## where R has the structure: ##STR43## where X is ##STR44## or a bond, and where R''' is the moiety of an alkanol containing up to about 5 carbon atoms; said aromatic diamine having the formula: H.sub.2 N--R'--NH.sub.2 where R 1 is selected from the group consisting of a phenylene group, a naphthylene group, or ##STR45## where X is as defined above; and said aromatic monoamine having the formula: ##STR46## where R" is an aryl group; and the solvent employed in step (a) having an atmospheric boiling point of less than about 150° C. and is selected from the group consisting of lower alkanols containing up to about 5 carbon atoms, lower ethers containing up to about 6 carbon atoms, and mixtures thereof.

Claim 12

A process of claim 6 or 7 in which R has the structure: ##STR47## and where R" has the structure: ##STR48##

Claim 13

A coating and laminating varnish consisting essentially of a product of claim 3 dissolved in a solvent selected from the group consisting of N-methyl-2-pyrrolidone, cyclohexanone, diethyl carbonate, and gamma-butyrolactone.

Claim 14

A coating and laminating varnish consisting essentially of a product of claim 4 dissolved in a solvent having an atmospheric boiling point of less than about 150° C. and selected from the group consisting of lower alkanols containing up to about 5 carbon atoms, lower ethers containing up to about 6 carbon atoms, and mixtures thereof.

Claim 15

A process for preparing a product of claim 2 which consists essentially of preparing a product of claim 3 by the method of claim 6 and effecting ring closure of the amic acid groups by a dehydration reaction.

Claim 16

A process for preparing a product of claim 2 which consists essentially of preparing a product of claim 4 by the process of claim 7 and heating said product to effect a ring closure to form imide groups.

Claim 17

A process of claim 11 or 12 in which R has the structure: ##STR49## and where R" has the structure: ##STR50##

Claim 18

A product of claim 1, 2, 3, 4, 9, or 10 in which up to 50 mol % of the terminal ##STR51## groups of R" is replaced with a hydrogen atom.

Claim 19

A process of claim 6, 7, 11, or 12 in which up to 50 mol % of the terminal ##STR52## groups of R" of the aromatic monoamine is replaced with a hydrogen atom.