← Back to Patent Explorer
US4250246A Expired / Lapsed US ⏱️ 0.0 years remaining

Photographic light-sensitive sheet for the color diffusion transfer process

Assignee: Fujifilm Holdings Corp
•
Filing: 1979-06-25
•
Granted: 1981-02-10
•
Expires: 1999-06-25
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A photographic light-sensitive sheet for the color diffusion transfer process which comprises a support having thereon at least one light-sensitive silver halide emulsion layer having associated therewith a magenta dye releasing redox (DRR) compound.

Inventors

  • 👤 Isamu Itoh
  • 👤 Yoshinobu Yoshida

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 06:44
CPC Classifications
C; C07; C07D; C07D295/00; C07D295/04; C07D295/08; C07D295/096; C07D295/12; C07D295/135; C09; C09B; C09B29/00; C09B29/0003; C09B29/24; C09B29/28; G; G03; G03C; G03C8/00; G03C8/02; G03C8/08; G03C8/10; Y; Y10; Y10S; Y10S430/00; Y10S430/156; Y10S430/159

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 506 words
A photographic light-sensitive sheet for the color diffusion transfer process which comprises a support having thereon at least one light-sensitive silver halide emulsion layer having associated therewith a compound represented by the following general formula (I): ##STR25## wherein Q 1 represents a hydrogen atom; a halogen atom; a sulfamoyl group represented by the formula --SO 2 NR 3 R 4 wherein R 3 represents a hydrogen atom or an alkyl group, R 4 represents a hydrogen atom or an R 4a group wherein R 4a represents an alkyl group, an aralkyl group or a phenyl group, and R 3 and R 4 may combine directly or through an oxygen atom to form a ring; a group represented by the formula --SO 2 R 5 wherein R 5 represents an alkyl group or an aralkyl group; a carboxy group; a group represented by the formula --COOR 6 wherein R 6 represents an alkyl group or a phenyl group; or a group represented by the formula --CONR 3 R 4 wherein R 3 and R 4 each has the same meaning as defined above; Q 2 is positioned at the 5- or the 8-position to the hydroxy group and represents a hydroxy group, a group represented by the formula --NHCOR 4a or a group represented by the formula --NHSO 2 R 4a wherein R 4a has the same meaning as defined above; G represents a hydroxyl group, a salt thereof, or a hydrolyzable acyloxy group represented by the formula ##STR26## wherein E represents an alkyl group or a phenyl group; R 1 and R 2 , which may be the same or different, each represents an alkyl group; and R 1 and R 2 may combine with each other and represent an atomic group necessary to form a 5-membered or 6-membered heterocyclic ring; m and q each represents 0 or 1; J represents a sulfonyl group or a carbonyl group; Z represents a hydrogen atom or an alkyl group; X represents a divalent bonding group represented by the formula --A 1 --L n --A 2 ) p wherein A 1 and A 2 , which may be the same or different, each represents an alkylene group, an aralkylene group, a phenylene group or a substituted phenylene group; L represents a divalent group selected from the group consisting of an oxy group, a carbonyl group, a carboxyamido group, a carbamoyl group, a sulfonamido group, a sulfamoyl group, a sulfinyl group and a sulfonyl group, and p and n each represents 0 or 1; and the group represented by the formula Y--NHSO 2 -- is a redox center which functions to release a diffusible dye as a result of self cleavage due to oxidation with Y representing a carboxylic ring containing at least one unsaturated double bond and a ballast group and substituted with (a) a hydroxy group or a precursor thereof or (b) an amino group, the substitution of said hydroxy group or said amino group being at the position ortho or para to the SO 2 NH-- group.
Claim 2
Dependent Claim 506 words
A photographic light-sensitive sheet for the color diffusion transfer process which comprises a support having thereon at least one light-sensitive silver halide emulsion layer having associated therewith a compound represented by the following general formula (I): ##STR25## wherein Q 1 represents a hydrogen atom; a halogen atom; a sulfamoyl group represented by the formula --SO 2 NR 3 R 4 wherein R 3 represents a hydrogen atom or an alkyl group, R 4 represents a hydrogen atom or an R 4a group wherein R 4a represents an alkyl group, an aralkyl group or a phenyl group, and R 3 and R 4 may combine directly or through an oxygen atom to form a ring; a group represented by the formula --SO 2 R 5 wherein R 5 represents an alkyl group or an aralkyl group; a carboxy group; a group represented by the formula --COOR 6 wherein R 6 represents an alkyl group or a phenyl group; or a group represented by the formula --CONR 3 R 4 wherein R 3 and R 4 each has the same meaning as defined above; Q 2 is positioned at the 5- or the 8-position to the hydroxy group and represents a hydroxy group, a group represented by the formula --NHCOR 4a or a group represented by the formula --NHSO 2 R 4a wherein R 4a has the same meaning as defined above; G represents a hydroxyl group, a salt thereof, or a hydrolyzable acyloxy group represented by the formula ##STR26## wherein E represents an alkyl group or a phenyl group; R 1 and R 2 , which may be the same or different, each represents an alkyl group; and R 1 and R 2 may combine with each other and represent an atomic group necessary to form a 5-membered or 6-membered heterocyclic ring; m and q each represents 0 or 1; J represents a sulfonyl group or a carbonyl group; Z represents a hydrogen atom or an alkyl group; X represents a divalent bonding group represented by the formula --A 1 --L n --A 2 ) p wherein A 1 and A 2 , which may be the same or different, each represents an alkylene group, an aralkylene group, a phenylene group or a substituted phenylene group; L represents a divalent group selected from the group consisting of an oxy group, a carbonyl group, a carboxyamido group, a carbamoyl group, a sulfonamido group, a sulfamoyl group, a sulfinyl group and a sulfonyl group, and p and n each represents 0 or 1; and the group represented by the formula Y--NHSO 2 -- is a redox center which functions to release a diffusible dye as a result of self cleavage due to oxidation with Y representing a carboxylic ring containing at least one unsaturated double bond and a ballast group and substituted with (a) a hydroxy group or a precursor thereof or (b) an amino group, the substitution of said hydroxy group or said amino group being at the position ortho or para to the SO 2 NH-- group.
Claim 3
Dependent Claim 26 words
The photographic light-sensitive sheet of claim 1, wherein said amino group NR 1 R 2 is positioned at the 4- or 6-position to the azo group.
Claim 4
Dependent Claim 28 words
The photographic light-sensitive sheet of claim 1, wherein said alkyl group represented by R 1 or R 2 is an alkyl group having 1 to 6 carbon atoms.
Claim 5
Dependent Claim 33 words
The photographic light-sensitive sheet of claim 1, wherein said alkyl group is a substituted alkyl group having 1 to 10 carbon atoms and is substituted with an alkoxy group or a halogen atom.
Claim 6
Dependent Claim 79 words
The photographic light-sensitive sheet of claim 1, wherein said sulfamoyl group represented by Q 1 is a sulfamoyl group represented by the formula --SO 2 NR 3 R 4 wherein R 3 is a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, R 4 and represents a hydrogen atom, an alkyl group having 1 to 8 carbon atoms, an aralkyl group, a phenyl group or a substituted phenyl group having 6 to 9 carbon atoms.
Claim 7
Dependent Claim 19 words
The photographic light-sensitive sheet of claim 5, wherein said R 3 and R 4 each represents a hydrogen atom.
Claim 8
Dependent Claim 40 words
The photographic light-sensitive sheet of claim 5, wherein one of said R 3 and R 4 represents a hydrogen atom and the other of said R 3 and R 4 represents an alkyl group having 1 to 4 carbon atoms.
Claim 9
Dependent Claim 12 words
The photographic light-sensitive sheet of claim 1, wherein said m is 0.
Claim 10
Dependent Claim 94 words
The photographic light-sensitive sheet of claim 1, wherein said Y--NHSO 2 -- is a sulfamoyl group represented by the following formula: ##STR27## wherein Ball represents a ballast group; T represents the carbon atoms necessary to complete a benzene ring, which may be unsubstituted or substituted, or a naphthalene ring, which may be a unsubstituted or substituted; the NHSO 2 -- group is present at the o- or p-position to the hydroxy group; and when T represents the atoms necessary to complete a naphthalene ring, Ball can be bonded to either of the two rings.
Claim 11
Dependent Claim 21 words
The photographic light-sensitive sheet of claim 9, wherein said ballast group contains a hydrophobic residue having 8 to 32 carbon atoms.
Claim 12
Dependent Claim 95 words
The photographic light-sensitive sheet of claim 9, wherein said ballast group is represented by the following formulae: ##STR28## wherein R 7 represents an alkylene group having 1 to 10 carbon atoms, R 8 represents a hydrogen atom or an alkyl group having 1 to 10 carbon atoms, n represents an integer of 1 to 5, R 9 represents an alkyl group having 4 to 30 carbon atoms and in the formula ##STR29## the R 9 's may be the same or different, and R 10 represents an alkyl group having 1 to 8 carbon atoms.
Claim 13
Dependent Claim 159 words
The photographic light-sensitive sheet of claim 9, wherein R 1 and R 2 combine to form a pyrrolidine ring or a morpholine ring, or R 1 represents --CH 2 CH 2 --O--CH 3 and R 2 represents an alkyl group having 1 to 4 carbon atoms; Q 1 represents a sulfamoyl group represented by the formula --SO 2 NR 3 R 4 wherein R 3 and R 4 , which may be the same or different, each represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms or R 3 and R 4 combine directly or through an oxygen atom to form a 5- or 6-membered ring; Q 2 represents a hydroxy group positioned at the 5- or 8-position to G or a group represented by the formula --NHSO 2 R 4a wherein R 4a is an alkyl group having 1 to 4 carbon atoms positioned at the 5-position to G; and m is 0.
Claim 14
Dependent Claim 129 words
The photographic light-sensitive sheet of claim 1, wherein the amino group --NR 1 R 2 is positioned at the 4-position to the azo group; R 1 and R 2 are bonded to each other to form a pyrrolidine ring or a morpholine ring; Q 1 is a sulfamoyl group represented by the formula --SO 2 NR 3 R 4 wherein R 3 represents a hydrogen atom and R 4 represents a tertbutyl group or an isopropyl group; Q 2 represents a group represented by the formula --NHSO 2 R 4a wherein R 4a is a methyl group at the 5-position to G, m is O and Y represents an o-hydroxyphenylsulfamoyl group having an alkyl group at the meta position to the hydroxy group in addition to a ballast group.

References Cited (Backward Citations)

US3954476A Cited
US4139383A Cited
US4135929A Cited
US4156609A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-02-10 1984-08-11 1985-02-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-02-10 1988-08-11 1989-02-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-02-10 1992-08-11 1993-02-10 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag