US4249965A
Expired / Lapsed
US
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Method of generating carrier gas
Assignee: Surface Combustion Corp
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Filing: 1978-09-19
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Granted: 1981-02-10
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Expires: 1998-09-19
Abstract
Abstract The present invention is a method of generating Class 302 type carrier gas for use in carburizing processes. The gas has a composition of approximately 40% nitrogen, 40% hydrogen and 20% carbon monoxide. The nitrogen is mixed with the methanol in a vaporizer where the methanol is vaporized. The vaporized methanol and nitrogen mixture is heated in a catalyst filled retort where methanol reacts to yield hydrogen and carbon monoxide. The relative volume percents of the nitrogen, hydrogen, and carbon monoxide is substantially the same as in the Class 302 type carrier gas.
Inventors
- 👤 Thomas J. Schultz
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 11:32
CPC Classifications
C; C23; C23C; C23C8/00; C23C8/06; C23C8/08; C23C8/20; C01; C01B; C01B3/00; C01B3/02; C01B3/22; C21; C21D; C21D1/00; C21D1/74; C21D1/76; C21D1/763
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
101 words
A method of generating a carrier gas for use in a carburizing process, the gas having a composition of approximately 40% nitrogen, 40% hydrogen and 20% carbon monoxide comprising the steps of: mixing gaseous nitrogen and liquid methanol in a vaporizer; vaporizing the methanol; feeding the vaporized methanol and nitrogen mixture into a retort heated to between 400° F. and 1200° F. and containing a metal based catalyst selected from the group consisting of copper, nickel and platinum; reacting the methanol in the retort to yield hydrogen and carbon monoxide; passing the hydrogen, carbon monoxide and nitrogen out of the retort.
Claim 2
Independent Claim
101 words
A method of generating a carrier gas for use in a carburizing process, the gas having a composition of approximately 40% nitrogen, 40% hydrogen and 20% carbon monoxide comprising the steps of: mixing gaseous nitrogen and liquid methanol in a vaporizer; vaporizing the methanol; feeding the vaporized methanol and nitrogen mixture into a retort heated to between 400° F. and 1200° F. and containing a metal based catalyst selected from the group consisting of copper, nickel and platinum; reacting the methanol in the retort to yield hydrogen and carbon monoxide; passing the hydrogen, carbon monoxide and nitrogen out of the retort.
Claim 3
Dependent Claim
18 words
The method as recited in claim 1 wherein the methanol is vaporized at 100° F. to 130° F.
Claim 4
Dependent Claim
16 words
The method as recited in claim 2 wherein the retort is heated to approximately 600° F.
Claim 5
Dependent Claim
52 words
The method as recited in claim 1 wherein the carrier gas is generated in the same equipment which can be used to generate a Class 302 type carrier gas from natural gas or methane and air, the equipment having a suitable catalyst for the cracking of methanol to hydrogen and carbon monoxide.
Claim 6
Independent Claim
203 words
A method of generating a carrier gas for use in a carburizing process, the gas having a composition of approximately 40% nitrogen, 40% hydrogen and 20% carbon monoxide, in an apparatus having a vaporizer section in which there is a recycle line in which there is disposed a recirculating pump, a heating means having a control means and a vaporizer, and the apparatus having a generator section having a retort, comprising the steps of: feeding methanol to the vaporizer section; feeding liquid methanol from the recycle line into the top of the vaporizer; feeding nitrogen into the bottom of the vaporizer; vaporizing the methanol passing down through the vaporizer, in the nitrogen flowing up through the vaporizer; recycling unvaporized liquid methanol in the recycle line from the bottom of the vaporizer through the recirculating pump and the heating means to the top of the vaporizer; feeding the vaporized methanol and nitrogen mixture into a retort heated to between 400° F. and 1200° F. and containing a metal based catalyst selected from the group consisting of copper, nickel and platinum; reacting the methanol in the retort to yield hydrogen and carbon monoxide; and passing the hydrogen, carbon monoxide and nitrogen out of the retort.
Claim 7
Independent Claim
203 words
A method of generating a carrier gas for use in a carburizing process, the gas having a composition of approximately 40% nitrogen, 40% hydrogen and 20% carbon monoxide, in an apparatus having a vaporizer section in which there is a recycle line in which there is disposed a recirculating pump, a heating means having a control means and a vaporizer, and the apparatus having a generator section having a retort, comprising the steps of: feeding methanol to the vaporizer section; feeding liquid methanol from the recycle line into the top of the vaporizer; feeding nitrogen into the bottom of the vaporizer; vaporizing the methanol passing down through the vaporizer, in the nitrogen flowing up through the vaporizer; recycling unvaporized liquid methanol in the recycle line from the bottom of the vaporizer through the recirculating pump and the heating means to the top of the vaporizer; feeding the vaporized methanol and nitrogen mixture into a retort heated to between 400° F. and 1200° F. and containing a metal based catalyst selected from the group consisting of copper, nickel and platinum; reacting the methanol in the retort to yield hydrogen and carbon monoxide; and passing the hydrogen, carbon monoxide and nitrogen out of the retort.
Claim 8
Dependent Claim
19 words
The method as recited in claim 5 wherein methanol is fed to the vaporizer section at the recycle line.
Claim 9
Dependent Claim
18 words
The method as recited in claim 5 wherein methanol is fed to the vaporizer section at the vaporizer.
Claim 10
Dependent Claim
38 words
The method as recited in claim 5 further comprising the steps of: maintaining the pressure in the recycle line at a nominal constant positive pressure; and heating the liquid methanol to about 100° F. as it is recycled.
Claim 11
Independent Claim
114 words
A method of generating a carrier gas for use in a carburizing process, the gas having a composition of approximately 40% nitrogen, 40% hydrogen and 20% carbon monoxide which comprises: feeding liquid methanol to a vaporizer; vaporizing the methanol; feeding the vaporized methanol into a retort, heated to between 400° F. and 1200° F. and containing a metal based catalyst selected from the group consisting of copper, nickel and platinum; reacting the methanol in the retort to yield hydrogen and carbon monoxide; passing the hydrogen and carbon monoxide out of the retort; mixing nitrogen to the hydrogen and carbon monoxide which has passed out of the retort until the composition is approximately 40% nitrogen.
Claim 12
Independent Claim
114 words
A method of generating a carrier gas for use in a carburizing process, the gas having a composition of approximately 40% nitrogen, 40% hydrogen and 20% carbon monoxide which comprises: feeding liquid methanol to a vaporizer; vaporizing the methanol; feeding the vaporized methanol into a retort, heated to between 400° F. and 1200° F. and containing a metal based catalyst selected from the group consisting of copper, nickel and platinum; reacting the methanol in the retort to yield hydrogen and carbon monoxide; passing the hydrogen and carbon monoxide out of the retort; mixing nitrogen to the hydrogen and carbon monoxide which has passed out of the retort until the composition is approximately 40% nitrogen.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-02-10 | 1984-08-11 | 1985-02-10 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-02-10 | 1988-08-11 | 1989-02-10 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-02-10 | 1992-08-11 | 1993-02-10 | $7700.00 | Window Closed / Lapsed |