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US4249915A Expired / Lapsed US ⏱️ 0.0 years remaining

Removal of water and carbon dioxide from air

Assignee: Air Products and Chemicals Inc
•
Filing: 1979-05-30
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Granted: 1981-02-10
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Expires: 1999-05-30
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Abstract

Abstract Moisture and CO 2 are removed from atmospheric air by adsorption of these respectively in separate beds. The moisture laden bed is regenerated by pressure swing adsorption in a relatively short operating cycle while the CO 2 -laden bed is regenerated thermally at considerably longer time intervals. The described method is of particular advantage in connection with the pretreatment of air prior to cryogenic distillation for separation of oxygen and nitrogen therein.

Inventors

  • 👤 Shivaji Sircar
  • 👤 Wilbur C. Kratz

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 07:31
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/02; B01D53/04; B01D53/047; B01D53/0462; B01D2253/00; B01D2253/10; B01D2253/104; B01D2253/106; B01D2253/108; B01D2257/00; B01D2257/50; B01D2257/504; B01D2257/80; B01D2259/00; B01D2259/40; B01D2259/40011; B01D2259/40058; B01D2259/40062; B01D2259/40064; B01D2259/402; B01D2259/416; B01D53/0473; B01D53/26; B01D53/261; Y; Y02; Y02C; Y02C20/00; Y02C20/40

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 324 words
The process of removing water and CO 2 from an air feed stream containing the same, which comprises the steps of: introducing the air stream at superatmospheric pressure into a first bed of solid adsorbent effective in adsorption of water from said feed air stream, discharging the dried air from the first bed and introducing a major portion thereof into an initial second bed containing adsorbent effective in retention of CO 2 , collecting the clean dry air thus obtained as product gas; regenerating said first bed after a relatively short on-stream operating period and, during said regenerating of said first bed, introducing the air feed stream into a companion parallel bed of similar composition as said first bed and operated in alternating sequence therewith, the regeneration of said first bed being effected by the sequential steps of: (a) reducing the pressure at the air feed inlet of the bed thus venting at least voids gas from the bed, (b) purging the bed at the reduced pressure with a dry gas, and (c) introducing dried air discharged from said companion bed into the purged bed to bring said bed to initial superatmospheric pressure for further adsorption of water; said alternating introduction of feed air into said first bed and said companion bed being continued for a relatively long period while continuing to discharge dried air from said first bed and said companion bed each in turn to said initial second bed; independently regenerating said initial second bed after said relatively long on-stream period by the sequential steps of (d) depressurizing the CO 2 -laden bed by venting therefrom a gas effluent including voids gas, (e) elevating the temperature of the bed to drive off adsorbed CO 2 , (f) introducing cool gas into the bed to restore the same to near ambient temperature, and (g) bringing the cooled bed to its initial adsorption pressure level by introduction of dry CO 2 -free product gas.
Claim 2
Dependent Claim 324 words
The process of removing water and CO 2 from an air feed stream containing the same, which comprises the steps of: introducing the air stream at superatmospheric pressure into a first bed of solid adsorbent effective in adsorption of water from said feed air stream, discharging the dried air from the first bed and introducing a major portion thereof into an initial second bed containing adsorbent effective in retention of CO 2 , collecting the clean dry air thus obtained as product gas; regenerating said first bed after a relatively short on-stream operating period and, during said regenerating of said first bed, introducing the air feed stream into a companion parallel bed of similar composition as said first bed and operated in alternating sequence therewith, the regeneration of said first bed being effected by the sequential steps of: (a) reducing the pressure at the air feed inlet of the bed thus venting at least voids gas from the bed, (b) purging the bed at the reduced pressure with a dry gas, and (c) introducing dried air discharged from said companion bed into the purged bed to bring said bed to initial superatmospheric pressure for further adsorption of water; said alternating introduction of feed air into said first bed and said companion bed being continued for a relatively long period while continuing to discharge dried air from said first bed and said companion bed each in turn to said initial second bed; independently regenerating said initial second bed after said relatively long on-stream period by the sequential steps of (d) depressurizing the CO 2 -laden bed by venting therefrom a gas effluent including voids gas, (e) elevating the temperature of the bed to drive off adsorbed CO 2 , (f) introducing cool gas into the bed to restore the same to near ambient temperature, and (g) bringing the cooled bed to its initial adsorption pressure level by introduction of dry CO 2 -free product gas.
Claim 3
Dependent Claim 47 words
The process as defined in claim 1 wherein the regeneration of said first bed is carried out after on-stream adsorption of water for not more than fifteen minutes, and said second bed continues adsorption of CO 2 for at least several hours before being subjected to regeneration.
Claim 4
Dependent Claim 20 words
The process as defined in claim 1 wherein the air is introduced into said first bed at near ambient temperature.
Claim 5
Dependent Claim 29 words
The process as defined in claim 3 wherein the feed air is introduced into said first bed at an absolute pressure of 40 to 300 pounds per square inch.
Claim 6
Dependent Claim 44 words
The process as defined in claim 1 wherein the dry, CO 2 -free product air obtained, is subjected to separation of oxygen and nitrogen therein by cryogenic distillation and the obtained nitrogen from said cryogenic distillation is employed as purge gas in step (b).
Claim 7
Dependent Claim 31 words
The process as defined in claim 5 wherein nitrogen gas from said cryogenic distillation is employed after heating said gas for elevating the temperature of the second bed during step (e).
Claim 8
Dependent Claim 24 words
The process as defined in claim 5 wherein nitrogen gas from said cryogenic distillation is employed for cooling the second bed in step (f).
Claim 9
Dependent Claim 55 words
The process as defined in claim 1 wherein said purging in step (b) is effected with a gas stream comprising, at least in part, effluent gas discharged from the second bed during regeneration of such second bed, said gas being flowed through said first bed in a direction counter to initial feed air flow therein.
Claim 10
Dependent Claim 34 words
The process as defined in claim 1 wherein introduction of feed air into said first bed and into said companion parallel bed is switched alternately at time periods of less than every 10 minutes.
Claim 11
Dependent Claim 58 words
The process as defined in claim 1 wherein during the period of regeneration of said second bed, dried air effluent from the first bed and from its parallel companion bed in alternate turns is introduced into another CO 2 -adsorbent bed operated in parallel to said second bed and similar in composition to that of said second bed.
Claim 12
Dependent Claim 36 words
The method as defined in claim 10 wherein during depressuring of said second bed in step (d), at least part of the effluent gas is employed as purge gas in a first bed undergoing step (b).
Claim 13
Dependent Claim 33 words
The method as defined in claim 10 wherein during depressuring of said second bed in step (d) at least part of the effluent is employed in pressuring a first bed undergoing step (c).
Claim 14
Dependent Claim 46 words
The method as defined in claim 10 wherein said second bed is brought to its initial adsorption pressure level in step (g) by admission into said bed of compressed CO 2 -free effluent from another CO 2 -adsorbent bed operated in parallel to said second bed.
Claim 15
Dependent Claim 47 words
The method as defined in claim 10 wherein said second bed continues to receive dried air effluent alternately from the first bed and from the parallel companion to the first bed during a period of at least several hours before said second bed is subjected to regeneration.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-02-10 1984-08-11 1985-02-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-02-10 1988-08-11 1989-02-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-02-10 1992-08-11 1993-02-10 $7700.00 Window Closed / Lapsed

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