← Back to Patent Explorer
US4248976A Expired / Lapsed US ⏱️ 0.0 years remaining

Flame-resistant polymer compositions

Assignee: FMC Corp
•
Filing: 1978-11-27
•
Granted: 1981-02-03
•
Expires: 1998-11-27
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Flameproofing of aromatic polymers is achieved by adding a synergistic combination of (a) a phosphorus compound and (b) a compound of formula R(CH 2 X) n , wherein R is an aromatic or heterocyclic residue, X is a leaving group and n is at least 2. Preferred phosphorus compounds are esters of phosphoric acid. The flameproofed polymers may contain aromatic groups in the main chain or as side-groups, for instance styrene polymers and copolymers, aromatic polyesters, polycarbonates and polyphenylene oxides.

Inventors

  • 👤 Brian G. Clubley
  • 👤 Boyce I. D. Davis
  • 👤 Thomas G. Hyde
  • 👤 Frank Lamb
  • 👤 Donald R. Randell

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 04:36
CPC Classifications
C; C08; C08L; C08L101/00; C08L101/02; C08K; C08K5/00; C08K5/0008; C08K5/0066

Claims Analysis

Total Claims: 28
Claim 1
Independent Claim 242 words
A composition which comprises a polymer selected from the group consisting of (1) a homopolymer or copolymer of styrene or α-methyl styrene, (2) a blend of (1) with polyphenylene oxide, polysulfone, vinyl chloride resin or polycarbonate, (3) a styrene cured unsaturated polyester resin, and (4) a polymer containing an aromatic group in the polymer chain and selected from the group consisting of polycarbonates, polyphenylene ethers, polysulfides, polyurethanes, polyhydrazides, linear polyesters, polysulfonates, polyamides, polyimides, polybenzimidazoles and polyanhydrides, and a flame-retarding combination of (a) a phosphorus compound selected from the group consisting of a phosphine oxide, a phosphorous oxy acid, a salt of a phosphorous oxy acid and an ester of a phosphorous oxy acid, and (b) a compound of the formula R(CH.sub.2 X).sub.n wherein R represents a monocyclic aromatic hydrocarbon radical or a di- or polycyclic-aromatic hydrocarbon radical the rings of which are fused or are linked directly and wherein R is unsubstituted other than by (CH 2 X) or is substituted by one or more groups selected from alkyl of 1 to 12 carbon atoms, cycloalkyl of 5 to 12 carbon atoms, hydroxyl, alkoxy of 1 to 12, alkoxy of 1 to 12 carbon atoms which contains an epoxide group, cycloalkoxy of 5 to 12 carbon atoms, aralkyloxy of 7 to 12 carbon atoms, acyloxy of 1 to 12 carbon atoms, carboxyl and carboalkoxy of 2 to 12 carbon atoms, n is an integer of 2 to 12, and X is OH.
Claim 2
Dependent Claim 242 words
A composition which comprises a polymer selected from the group consisting of (1) a homopolymer or copolymer of styrene or α-methyl styrene, (2) a blend of (1) with polyphenylene oxide, polysulfone, vinyl chloride resin or polycarbonate, (3) a styrene cured unsaturated polyester resin, and (4) a polymer containing an aromatic group in the polymer chain and selected from the group consisting of polycarbonates, polyphenylene ethers, polysulfides, polyurethanes, polyhydrazides, linear polyesters, polysulfonates, polyamides, polyimides, polybenzimidazoles and polyanhydrides, and a flame-retarding combination of (a) a phosphorus compound selected from the group consisting of a phosphine oxide, a phosphorous oxy acid, a salt of a phosphorous oxy acid and an ester of a phosphorous oxy acid, and (b) a compound of the formula R(CH.sub.2 X).sub.n wherein R represents a monocyclic aromatic hydrocarbon radical or a di- or polycyclic-aromatic hydrocarbon radical the rings of which are fused or are linked directly and wherein R is unsubstituted other than by (CH 2 X) or is substituted by one or more groups selected from alkyl of 1 to 12 carbon atoms, cycloalkyl of 5 to 12 carbon atoms, hydroxyl, alkoxy of 1 to 12, alkoxy of 1 to 12 carbon atoms which contains an epoxide group, cycloalkoxy of 5 to 12 carbon atoms, aralkyloxy of 7 to 12 carbon atoms, acyloxy of 1 to 12 carbon atoms, carboxyl and carboalkoxy of 2 to 12 carbon atoms, n is an integer of 2 to 12, and X is OH.
Claim 3
Dependent Claim 17 words
A composition according to claim 1 wherein component (a) is an ester of a phosphorus oxy acid.
Claim 4
Dependent Claim 28 words
A composition according to claim 1 wherein the amount of component (a) plus component (b) is from 1 to 100 parts by weight per 100 parts of polymer.
Claim 5
Dependent Claim 28 words
A composition according to claim 3 wherein the amount of component (a) plus component (b) is from 2 to 35 parts by weight per 100 parts of polymer.
Claim 6
Dependent Claim 22 words
A composition according to claim 1 wherein the ratio of component (a) to component (b) is from 1:10 to 10:1 by weight.
Claim 7
Dependent Claim 14 words
A composition according to claim 5 wherein the ratio is from 1:1 to 8:1.
Claim 8
Dependent Claim 16 words
A composition according to claim 5 wherein the ratio is from 2:1 to 4:1 by weight.
Claim 9
Dependent Claim 19 words
A composition according to claim 1 wherein the polymer is a homopolymer or copolymer of styrene or α-methyl styrene.
Claim 10
Dependent Claim 18 words
A composition according to claim 1 wherein the polymer is a copolymer of styrene with butadiene or butadiene/acrylonitrile.
Claim 11
Dependent Claim 18 words
A composition according to claim 1 wherein the polymer is a copolymer of styrene and an unsaturated polyester.
Claim 12
Dependent Claim 26 words
A composition according to claim 1 wherein the component (a) is an ester derived from phosphoric acid, phosphorus acid, a phosphonic acid, or a phosphinic acid.
Claim 13
Dependent Claim 18 words
A composition according to claim 11 wherein component (a) is an ester of an acid containing pentavalent phosphorus.
Claim 14
Dependent Claim 16 words
A composition according to claim 11 wherein the ester is a triaryl phosphate or tri-haloalkyl phosphate.
Claim 15
Dependent Claim 13 words
A composition according to claim 1 wherein component (a) is a phosphine oxide.
Claim 16
Dependent Claim 14 words
A composition according to claim 14 wherein component (a) is a triaryl phosphine oxide.
Claim 17
Dependent Claim 16 words
A composition according to claim 1 wherein component (a) is a salt of a phosphorus acid.
Claim 18
Dependent Claim 28 words
A composition according to claim 16 wherein component (a) is an alkali metal, ammonium or amine salt of phosphoric acid, phosphorous acid, a phosphonic or a phosphinic acid.
Claim 19
Dependent Claim 35 words
A composition according to claim 1 additionally containing a heat stabilizer, light stabilizer, UV absorber, antioxidant, filler, pigment, lubricant, blowing agent, fungicide, additive to improve mould release, optical brightening agent or other fire retardant additive.
Claim 20
Dependent Claim 26 words
A composition as claimed in claim 1 in which the component (a) is a derivative or a salt of a phosphorus acid or a phosphine oxide.
Claim 21
Dependent Claim 21 words
A composition as claimed in claim 1 in which the polymer is polystyrene or a blend of polystyrene with another polymer.
Claim 22
Dependent Claim 21 words
A composition as claimed in claim 1 in which the polymer is a copolymer of styrene with butadiene or with butadiene/acrylonitrile.
Claim 23
Dependent Claim 20 words
A composition as claimed in claim 1 in which the polymer is a copolymer of styrene and an unsaturated polyester.
Claim 24
Dependent Claim 24 words
A composition as claimed in claim 1 in which the polymer is a polycarbonate based on 2,2-bis (4-hydroxyphenyl)propane or its polyblend with other polymers.
Claim 25
Dependent Claim 28 words
A composition as claimed in claim 1 in which the polymer is a linear polyester derived from phthalic, terephthalic or isophthalic acid, a maleic acid and a glycol.
Claim 26
Dependent Claim 20 words
A composition as claimed in claim 1 in which the polymer is poly-2,6-dimethyl-1,4-phenylene oxide or its polyblend with other polymers.
Claim 27
Dependent Claim 24 words
A composition as claimed in claim 1 in which the polymer is a polyurethane based on adipic acid, 1,4-butane diol and 4,4'-diphenyl methane di-isocyanate.
Claim 28
Dependent Claim 21 words
A composition as claimed in claim 1 in which (b) is a compound of the formula ##STR63## where X represents OH.

References Cited (Backward Citations)

US2631768A Cited
US3400085A Cited
US3582510A Cited
US3658634A Cited
US3899466A Cited
US3901834A Cited
US3981936A Cited
US4057531A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-02-03 1984-08-04 1985-02-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-02-03 1988-08-04 1989-02-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-02-03 1992-08-04 1993-02-03 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag