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US4248755A
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Composition and method for sizing textiles
Assignee: Solutia Inc
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Filing: 1979-09-14
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Granted: 1981-02-03
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Expires: 1999-09-14
Abstract
Abstract Disclosed herein is a composition and method for sizing textiles which employs as the sizing agent a mixed salt comprising the reaction product of an interpolymer with a fixed alkali base and a fugitive alkali base; the latter subsequently being volatilized away during processing of the sized textile. The interpolymer comprises (a) 1.0 molar proportion of a maleic or fumaric acid or anhydride or partial ester, (b) from 0.1 to 3.0 molar proportion of a monovinylidene aromatic monomer and (c) from zero to a finite molar proportion of an alpha-olefin, a vinyl ester, alpha-beta-ethylenically unsaturated nitrile, an acrylic or methacrylic ester or a vinyl alkyl ether. From 10 to 70% of the free carboxyl groups of the interpolymer are combined with fixed base, i.e., non-valatile amine or alkali metal base, and from 5 to 90% of said free carboxyl groups are combined with fugitive base, i.e., ammonia, ammonium hydroxide or volatile amine.
Inventors
- 👤 Charles R. Williams
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 16:01
CPC Classifications
D; D06; D06M; D06M15/00; D06M15/19; D06M15/21; D06M15/263; D06M11/00; D06M11/32; D06M11/36; D06M11/38
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
225 words
A method for preparing and finishing textile materials which comprises: treating a textile material with an aqueous solution of a mixed salt of an interpolymer, said interpolymer consisting of: (1) 1.0 molar proportion of maleic anhydride, (2) from 0.1 to 3.0 molar proportion of styrene, and (3) from zero to X molar proportion of vinyl acetate the total of monomers (2) and (3) being at least 1.0 molar proportion; wherein the specific viscosity of the interpolymer determined at 25° C. on a solution of 0.5 gram of interpolymer per deciliter of dimethyl formamide is in the range from about 2 to 8, and wherein (a) from 10 to 70 percent of the free carboxyl groups of said interpolymer are combined with at least one fixed base selected from the group consisting of non-volatile monobasic amines and alkali metal bases, and (b) from 5 to 90 percent of the free carboxyl groups of said interpolymer are combined with at least one fugitive base selected from the group consisting of ammonia, ammonium bases and volatile monobasic amines, to provide a workable viscosity for application of the solution to the textile material and such that a total of from 20 to 100 percent of said free carboxyl groups are so combined, and `(B) heating the treated textile material at a temperature high enough to volatilize the fugitive base.
Claim 2
Independent Claim
225 words
A method for preparing and finishing textile materials which comprises: treating a textile material with an aqueous solution of a mixed salt of an interpolymer, said interpolymer consisting of: (1) 1.0 molar proportion of maleic anhydride, (2) from 0.1 to 3.0 molar proportion of styrene, and (3) from zero to X molar proportion of vinyl acetate the total of monomers (2) and (3) being at least 1.0 molar proportion; wherein the specific viscosity of the interpolymer determined at 25° C. on a solution of 0.5 gram of interpolymer per deciliter of dimethyl formamide is in the range from about 2 to 8, and wherein (a) from 10 to 70 percent of the free carboxyl groups of said interpolymer are combined with at least one fixed base selected from the group consisting of non-volatile monobasic amines and alkali metal bases, and (b) from 5 to 90 percent of the free carboxyl groups of said interpolymer are combined with at least one fugitive base selected from the group consisting of ammonia, ammonium bases and volatile monobasic amines, to provide a workable viscosity for application of the solution to the textile material and such that a total of from 20 to 100 percent of said free carboxyl groups are so combined, and `(B) heating the treated textile material at a temperature high enough to volatilize the fugitive base.
Claim 3
Dependent Claim
22 words
The method of claim 1 wherein the specific viscosity of the interpolymer is in the range of from about 3 to 5.
Claim 4
Dependent Claim
21 words
The method of claim 1 wherein the fixed base is sodium hydroxide and the fugitive base is ammonia or ammonium hydroxide.
Claim 5
Dependent Claim
23 words
The method of claim 1 wherein the interpolymer consists of maleic anhydride and styrene in the molar ratio of from 1:1 to 1:1.4.
Claim 6
Dependent Claim
25 words
The method of claim 3 wherein when the fugitive base has been volatilized, the interpolymer salt has a tensile strength greater than about 3000 psi.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-02-03 | 1984-08-04 | 1985-02-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-02-03 | 1988-08-04 | 1989-02-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-02-03 | 1992-08-04 | 1993-02-03 | $7700.00 | Window Closed / Lapsed |