← Back to Patent Explorer
US4248679A Expired / Lapsed US ⏱️ 0.0 years remaining

Electrolysis of alkali metal chloride in a cell having a nickel-molybdenum cathode

Assignee: PPG Industries Inc
•
Filing: 1979-01-24
•
Granted: 1981-02-03
•
Expires: 1999-01-24
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Disclosed herein is a cathode having an electroconductive substrate and a porous surface. The porous surface is characterized by containing a major portion of nickel and a hydrogen overvoltage reducing amount of molybdenum. The molybdenum may be present as elemental molybdenum, as an alloy with nickel, or as a molybdenum compound. Also disclosed is an electrolytic cell having an anode, a cathode, and a separator between the anode and cathode, where the cathode is characterized by a porous surface having a major portion of nickel and a hydrogen over voltage reducing amount of molybdenum, which molybdenum may be present as elemental molybdenum, and molybdenum alloy with nickel or a molybdenum compound. Further disclosed is a method of electrolyzing an alkali metal chloride brine by passing an electrical current from an anode to a cathode to evolve chlorine at the anode and hydroxyl ion at the cathode. The cathode is characterized by a porous surface containing a major portion of nickel and hydrogen overvoltage reducing amount of molybdenum. Also disclosed is a method of preparing a porous nickel electrode by flame spraying nickel bearing particles, leachable constituent bearing particles and molybdenum bearing particles onto a metal substrate and leaching out the leachable constituent whereby to form the porous surface.

Inventors

  • 👤 Cletus N. Welch
  • 👤 John O. Snodgrass

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 15:28
CPC Classifications
C; C25; C25B; C25B11/00; C25B11/04; C25B11/051; C25B11/073; C25B11/091

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 114 words
In a method of electrolyzing an alkali metal chloride brine comprising passing an electrical current from an anode to a cathode whereby to evolve Cl 2 at said hydroxyl ion and hydrogen at said cathode, said cathode comprising an electroconductive substrate and a porous surface comprising a major portion of nickel; the improvement wherein said porous surface consists essentially of nickel and a hydrogen overvoltage reducing amount of molybdenum; said porous surface having been prepared by depositing said nickel, said molybdenum, and a leachable material on said substrate and leaching out said leachable material; and the cathode has a substantially impermeable film consisting essentially of nickel interposed between said substrate and said porous surface.
Claim 2
Dependent Claim 114 words
In a method of electrolyzing an alkali metal chloride brine comprising passing an electrical current from an anode to a cathode whereby to evolve Cl 2 at said hydroxyl ion and hydrogen at said cathode, said cathode comprising an electroconductive substrate and a porous surface comprising a major portion of nickel; the improvement wherein said porous surface consists essentially of nickel and a hydrogen overvoltage reducing amount of molybdenum; said porous surface having been prepared by depositing said nickel, said molybdenum, and a leachable material on said substrate and leaching out said leachable material; and the cathode has a substantially impermeable film consisting essentially of nickel interposed between said substrate and said porous surface.
Claim 3
Dependent Claim 87 words
In an electrolytic cell having an anode, a cathode, and a separator therebetween, which cathode comprises a porous nickel surface on an electroconductive substrate; the improvement wherein said porous surface consists essentially of nickel and a hydrogen overvoltage reducing amount of molybdenum; said porous surface having been prepared by depositing said nickel, said molybdenum, and a leachable material on said substrate and leaching out said leachable material; and said cathode has a substantially impermeable film consisting essentially of nickel interposed between said substrate and said porous surface.
Claim 4
Dependent Claim 87 words
In an electrolytic cell having an anode, a cathode, and a separator therebetween, which cathode comprises a porous nickel surface on an electroconductive substrate; the improvement wherein said porous surface consists essentially of nickel and a hydrogen overvoltage reducing amount of molybdenum; said porous surface having been prepared by depositing said nickel, said molybdenum, and a leachable material on said substrate and leaching out said leachable material; and said cathode has a substantially impermeable film consisting essentially of nickel interposed between said substrate and said porous surface.
Claim 5
Dependent Claim 80 words
In a cathode having an electroconductive substrate and a porous surface comprising a major portion of nickel, the improvement wherein said porous surface consists essentially of nickel and a hydrogen overvoltage reducing amount of molybdenum; said porous surface having been prepared by depositing said nickel, said molybdenum and a leachable material on said substrate and leaching out said leachable material; and said cathode has a substantially impermeable film consisting essentially of nickel interposed between said substrate and said porous surface.
Claim 6
Dependent Claim 80 words
In a cathode having an electroconductive substrate and a porous surface comprising a major portion of nickel, the improvement wherein said porous surface consists essentially of nickel and a hydrogen overvoltage reducing amount of molybdenum; said porous surface having been prepared by depositing said nickel, said molybdenum and a leachable material on said substrate and leaching out said leachable material; and said cathode has a substantially impermeable film consisting essentially of nickel interposed between said substrate and said porous surface.

References Cited (Backward Citations)

US4080278A Cited
US4049841A Cited
US4024044A Cited
US4033837A Cited
US4170536A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-02-03 1984-08-04 1985-02-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-02-03 1988-08-04 1989-02-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-02-03 1992-08-04 1993-02-03 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag