US4247600A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Metallized plastic camera housing and method
Assignee: Minolta Co Ltd
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Filing: 1978-07-28
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Granted: 1981-01-27
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Expires: 1998-07-28
Abstract
Abstract An improved plastic camera housing having an exterior decorative metallic coating and method of producing the same is disclosed. The camera housing assembly can comprise a polycarbonate glass fiber filled molded part that has been plasma etched in an inert argon gas filled pressure vessel. The camera part is plasma etched for a brief period of time to deteriorate the cross linkage of plastic bonding of the surface polymers without causing any outgassing of the elements of the plastic. A layer of copper is deposited to an approximate thickness of 1 to 3 microns in the inert subatmospheric environment. A second exterior layer of chromium approximately 0.2 to 0.5 microns is subsequently deposited to provide a hard abrasion resistant surface. Alternatively, a lacquer subsurface layer can be sprayed onto the camera part before the initial plasma etching.
Inventors
- 👤 Iwao P. Adachi
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 19:14
CPC Classifications
C; C08; C08J; C08J7/00; C08J7/12; C08J7/123; C08J7/04; C08J7/042; C08J7/0423; C08J7/043; C08J7/046; C08J7/06; C23; C23C; C23C14/00; C23C14/02; C23C14/021; C23C14/022; C23C14/06; C23C14/14; C23C14/20; C23C14/205; Y; Y10; Y10T; Y10T428/00; Y10T428/12; Y10T428/12431; Y10T428/12438; Y10T428/12493; Y10T428/12535; Y10T428/12556
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
132 words
An improved fiber reinforced plastic article having an exterior decorative metal coating formed by a process of preliminary preparation of the plastic surface with a gas plasma etching comprising: an article substrate having at least one portion formed from a molded plastic material having a gas plasma etched surface, the surface configuration being characteristic of gas plasma etching for a sufficient period of time to deteriorate the cross linkage of bonds between the plastic polymers adjacent the surface without outgassing any significant material to effect the subsequent metal coating, and an exterior metallized coating on the gas plasma etched surface including a first layer adjacent the plastic material of a first metal transitional element and a second exterior layer on the first metal transitional element layer of a second metal transitional element.
Claim 2
Dependent Claim
132 words
An improved fiber reinforced plastic article having an exterior decorative metal coating formed by a process of preliminary preparation of the plastic surface with a gas plasma etching comprising: an article substrate having at least one portion formed from a molded plastic material having a gas plasma etched surface, the surface configuration being characteristic of gas plasma etching for a sufficient period of time to deteriorate the cross linkage of bonds between the plastic polymers adjacent the surface without outgassing any significant material to effect the subsequent metal coating, and an exterior metallized coating on the gas plasma etched surface including a first layer adjacent the plastic material of a first metal transitional element and a second exterior layer on the first metal transitional element layer of a second metal transitional element.
Claim 3
Dependent Claim
47 words
The invention of claim 1 wherein the article substrate surface has been plasma etched preparatory to receiving the first layer, the plasma etching is done for approximately two minutes at approximately 13.6 megahertz at about 500 watts in an environment of argon gas at 10 -2 torr.
Claim 4
Dependent Claim
22 words
The invention of claim 1 wherein the first metal transitional element is a copper layer approximately 1 to 3 microns in thickness.
Claim 5
Dependent Claim
22 words
The invention of claim 3 wherein the second metal transitional element is a chromium layer approximately 0.2 to 0.5 microns in thickness.
Claim 6
Dependent Claim
19 words
The invention of claim 3 further including a sublayer coating between the copper layer and the molded plastic material.
Claim 7
Dependent Claim
13 words
The invention of claim 5 wherein the sublayer coating is a plastic epoxy.
Claim 8
Dependent Claim
13 words
The invention of claim 5 wherein the sublayer coating is a polyurethane material.
Claim 9
Dependent Claim
22 words
The invention of claim 7 wherein the sublayer coating further has particles of powder of approximately 1 to 5 microns in size.
Claim 10
Dependent Claim
22 words
The invention of claim 8 wherein the particles of powder are selected from a group consisting of carbon, graphite, copper and chromium.
Claim 11
Dependent Claim
148 words
In an improved plastic camera housing of fiber reinforced plastic material such as a glass fiber filled polycarbonate plastic formed by a process of preliminary preparation of the plastic surface with plasma etching, the improvement comprising; at least one portion of the camera housing having a plasma etched surface with a metallized coating, the coating including a first layer adjacent the plastic housing of approximately 1 to 3 microns of thickness of sputtered copper deposited in an inert subatmospheric environment and a second exterior layer of chromium of at least approximately 0.2 to 0.5 microns deposited in an inert subatmospheric environment onto the copper layer, the plastic housing portion surface has been plasma etched preparatory to receiving the first layer, the plasma etching was done for approximately two minutes at approximately 13.6 megahertz at about 500 watts in an environment of argon gas at approximately 10 -2 torr.
Claim 12
Dependent Claim
148 words
In an improved plastic camera housing of fiber reinforced plastic material such as a glass fiber filled polycarbonate plastic formed by a process of preliminary preparation of the plastic surface with plasma etching, the improvement comprising; at least one portion of the camera housing having a plasma etched surface with a metallized coating, the coating including a first layer adjacent the plastic housing of approximately 1 to 3 microns of thickness of sputtered copper deposited in an inert subatmospheric environment and a second exterior layer of chromium of at least approximately 0.2 to 0.5 microns deposited in an inert subatmospheric environment onto the copper layer, the plastic housing portion surface has been plasma etched preparatory to receiving the first layer, the plasma etching was done for approximately two minutes at approximately 13.6 megahertz at about 500 watts in an environment of argon gas at approximately 10 -2 torr.
Claim 13
Dependent Claim
25 words
The invention of claim 10 wherein the first layer is deposited in an atmosphere of argon gas at a pressure of approximately 10 -2 torr.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-01-27 | 1984-07-28 | 1985-01-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-01-27 | 1988-07-28 | 1989-01-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-01-27 | 1992-07-28 | 1993-01-27 | $7700.00 | Window Closed / Lapsed |