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US4247359A Expired / Lapsed US ⏱️ 0.0 years remaining

Preparation of epitaxial rare earth thin films

Assignee: Honeywell Inc
•
Filing: 1978-10-30
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Granted: 1981-01-27
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Expires: 1998-10-30
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Abstract

Abstract A method of preparing epitaxial thin films of metallic rare earth garnets by chemical vapor deposition utilizes organometallic ligand compounds of rare earth metals including scandium, yttrium, lanthanum and the lanthanides (Z=58 through 71) with organic compounds including acetylacetone, benzoylacetone, thenoyl trifluoroacetone, fluorinated benzoylacetone, tri-n-butylphosphate, tri-n-octylphosphine oxide and sodium cyclopentadienide and 2,2,6,6-tetramethyl 3,5-heptanedione.

Inventors

  • 👤 Hanumanthiya V. Venkatasetty

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 08:48
CPC Classifications
C; C30; C30B; C30B25/00; C30B25/02; C30B29/00; C30B29/10; C30B29/16; C30B29/22; C30B29/28

Claims Analysis

Total Claims: 3
Claim 1
Independent Claim 86 words
In a method of preparing epitaxial thin films of metallic rare earth garnets by chemical vapor deposition in an inert atmosphere, the improvement comprising the step of depositing said rare earth metals in an epitaxial layer on a substrate from organic ligand compound forms which include at least one element from the group consisting of scandium, yttrium, lanthanum, and the lanthanide series combined with the compound selected from the group consisting of acetylacetone, thenoyl trifluoroacetone, benzoylacetone, fluorinated benzoylacetone, sodium cyclopentadienide, tri-n-butylphosphate, tri-n-octylphosphine oxide, and 2,2,6,6-tetramathyl 3,5-heptanedione.
Claim 2
Dependent Claim 86 words
In a method of preparing epitaxial thin films of metallic rare earth garnets by chemical vapor deposition in an inert atmosphere, the improvement comprising the step of depositing said rare earth metals in an epitaxial layer on a substrate from organic ligand compound forms which include at least one element from the group consisting of scandium, yttrium, lanthanum, and the lanthanide series combined with the compound selected from the group consisting of acetylacetone, thenoyl trifluoroacetone, benzoylacetone, fluorinated benzoylacetone, sodium cyclopentadienide, tri-n-butylphosphate, tri-n-octylphosphine oxide, and 2,2,6,6-tetramathyl 3,5-heptanedione.
Claim 3
Dependent Claim 19 words
The method of claim 1 wherein said lanthanide metal is selected from the group consisting of yttrium and gadolinium.

References Cited (Backward Citations)

US3326948A Cited
US3131082A Cited
US3615168A Cited
FR2092896A1 Cited
US3856582A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-01-27 1984-07-28 1985-01-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-01-27 1988-07-28 1989-01-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-01-27 1992-07-28 1993-01-27 $7700.00 Window Closed / Lapsed

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