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US4246904A Expired / Lapsed US ⏱️ 0.0 years remaining

Surgical suture derived from segmented polyether-ester block copolymers

Assignee: Wyeth Holdings LLC
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Filing: 1979-01-29
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Granted: 1981-01-27
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Expires: 1999-01-29
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Abstract

Abstract A synthetic nonabsorbable surgical suture compound of segmented polyether--ester block copolymers is disclosed.

Inventors

  • 👤 Donald S. Kaplan

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 19:41
CPC Classifications
A; A61; A61L; A61L17/00; A61L17/04

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 176 words
A annealed non-absorbable monofilament sterile surgical suture or ligature having an attached needle comprising a polymeric block (A) consisting of a polyalkylene ether of the formula ##STR10## having a number average molecular weight of from about 500-3000 wherein R is a straight or branched chain alkyl group of from about 2 to 10 carbon atoms and R 2 is 1,4-phenylene or cyclohexylene and n is the number of repeating units; and a polymeric block (B) which is the reaction product of an aromatic dicarboxylic acid or a cycloaliphatic acid, and a short chain aliphatic or cycloaliphatic diol, having the formula ##STR11## wherein R 1 is a straight or branched chain alkyl group of from about 2 to 10 carbon atoms or a cyclic group having the formula ##STR12## and R 2 is 1,4-phenylene or cyclohexylene, said block (B) comprising from about 30% to 95% of said copolymer, and said copolymer having a number average molecular weight of from about 25,000 to 30,000, such that said suture has good flexibility, good fatigue life and high tensile strength.
Claim 2
Dependent Claim 176 words
A annealed non-absorbable monofilament sterile surgical suture or ligature having an attached needle comprising a polymeric block (A) consisting of a polyalkylene ether of the formula ##STR10## having a number average molecular weight of from about 500-3000 wherein R is a straight or branched chain alkyl group of from about 2 to 10 carbon atoms and R 2 is 1,4-phenylene or cyclohexylene and n is the number of repeating units; and a polymeric block (B) which is the reaction product of an aromatic dicarboxylic acid or a cycloaliphatic acid, and a short chain aliphatic or cycloaliphatic diol, having the formula ##STR11## wherein R 1 is a straight or branched chain alkyl group of from about 2 to 10 carbon atoms or a cyclic group having the formula ##STR12## and R 2 is 1,4-phenylene or cyclohexylene, said block (B) comprising from about 30% to 95% of said copolymer, and said copolymer having a number average molecular weight of from about 25,000 to 30,000, such that said suture has good flexibility, good fatigue life and high tensile strength.
Claim 3
Dependent Claim 22 words
The surgical suture or ligature of claim 1, wherein the polymeric block (B) comprises from about 50% to 85% of the copolymer.
Claim 4
Dependent Claim 22 words
The surgical suture or ligature of claim 1, wherein the polymeric block (B) comprises from about 55% to 80% of the copolymer.
Claim 5
Dependent Claim 21 words
The surgical suture or ligature of claim 1, wherein R is selected from the group consisting of ethylene, propylene or butylene.
Claim 6
Dependent Claim 12 words
The surgical suture or ligature of claim 4, wherein R is butylene.
Claim 7
Dependent Claim 21 words
A surgical suture package comprising a sterile enclosure and therein a non-absorbable monofilament sterile surgical suture or ligature of claim 1.
Claim 8
Dependent Claim 11 words
The surgical suture package of claim 6 wherein R is butylene.
Claim 9
Dependent Claim 24 words
The surgical suture or ligature of claim 1 or 3 or 5 or 7 wherein said suture or ligature is heated at constant length.

References Cited (Backward Citations)

US3359983A Cited
US3652713A Cited
US3766146A Cited
DE2265294A1 Cited
US3784520A Cited
US3861521A Cited
US3875946A Cited
US4032993A Cited
US4127127A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-01-27 1984-07-28 1985-01-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-01-27 1988-07-28 1989-01-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-01-27 1992-07-28 1993-01-27 $7700.00 Window Closed / Lapsed

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