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US4246170A Expired / Lapsed US ⏱️ 0.0 years remaining

Phenol phosphorus compounds as polyolefin stabilizers

Assignee: Novartis Corp
•
Filing: 1979-01-18
•
Granted: 1981-01-20
•
Expires: 1999-01-18
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Abstract

Abstract Phenols of the formula I ##STR1## wherein n has a value from 1 to 15, each of R 1 , R 2 , R 3 and R 4 independently is a hydrogen atom, a C 1 - 18 -alkyl group, an aryl group, a C 5 -C 12 -cycloalkyl group or a C 7 -C 13 -aralkyl group, R 5 is a hydrogen atom or a C 1 -C 18 -alkyl group, Y is a carbonyl, thiocarbonyl, sulphinyl, sulphonyl, -P(OR 7 )-, -P(═O) (OR 7 )-, -P(═O) (R 7 )- or -P(R 7 )- group, and R 6 is a radical --CHR 8 --CHR 9 --S--CR 10 R 11 R 12 , wherein each of R 8 and R 9 independently is a hydrogen atom or a C 1 -C 6 -alkyl group, R 10 is a hydrogen atom, a C 1 -C 19 -alkyl group, a C 2 -C 4 -alkenyl group or an aryl group, R 11 is a hydrogen atom or a methyl group and R 12 is a hydrogen atom or a methyl group, or, if R 11 is a hydrogen atom, is a C 2 -C 6 -alkyl group, or, if R 10 is a hydrogen atom, R 11 and R 12 together with the carbon atom to which they are attached represent a cycloalkyl group, or R 10 , R 11 and R 12 together with the carbon atom to which they are attached represent an aryl group, or if Y is a thiocarbonyl, sulphinyl or sulphonyl group, R 6 can also be a hydrogen atom or a C 1 -C 18 -alkyl group or an aryl group, and R 7 is a hydrogen atom, a C 1 -C 18 -alkyl group or an aryl group, as stabilizers for organic material.

Inventors

  • 👤 Samuel Evans

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 18:54
CPC Classifications
C; C09; C09K; C09K15/00; C09K15/04; C09K15/32; C09K15/322; C07; C07C; C07C301/00; C07C301/02; C07C305/00; C07C305/22; C07C305/24; C07C323/00; C07C323/10; C07C323/11; C07C323/16; C07C329/00; C07C329/02; C07C329/04; C07F; C07F9/00; C07F9/02; C07F9/06; C07F9/08; C07F9/09; C07F9/12; C07F9/141; C07F9/145; C07F9/28; C07F9/38; C07F9/40; C07F9/4071; C07F9/4075; C07F9/4084; C07F9/48; C07F9/4866; C07F9/4875; C08; C08K; C08K5/00; C08K5/0008; C08K5/005; C08K5/49; C08K5/51; C09K15/12; C09K15/14

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 115 words
A phenol of the formula I ##STR5## wherein n is 1 to 4, R 1 is hydrogen or methyl, R 2 is hydrogen, methyl, ethyl or tert.-butyl, R 3 is hydrogen, methyl, ethyl or tert.-butyl, R 4 and R 5 are each hydrogen, Y is -P(OR 7 )-, -P(═O)(OR 7 )-, -P(═O)(R 7 )- or -P(R 7 )-, wherein R 7 is hydrogen, C 1 -C 18 -alkyl or phenyl, and R 6 is a radical -CHR 8 -CHR 9 -S-CR 10 R 11 R 12 , wherein R 8 is hydrogen, R 9 is hydrogen or methyl, R 10 is C 4 -C 19 -n-alkyl, and R 11 and R 12 are each hydrogen.
Claim 2
Dependent Claim 115 words
A phenol of the formula I ##STR5## wherein n is 1 to 4, R 1 is hydrogen or methyl, R 2 is hydrogen, methyl, ethyl or tert.-butyl, R 3 is hydrogen, methyl, ethyl or tert.-butyl, R 4 and R 5 are each hydrogen, Y is -P(OR 7 )-, -P(═O)(OR 7 )-, -P(═O)(R 7 )- or -P(R 7 )-, wherein R 7 is hydrogen, C 1 -C 18 -alkyl or phenyl, and R 6 is a radical -CHR 8 -CHR 9 -S-CR 10 R 11 R 12 , wherein R 8 is hydrogen, R 9 is hydrogen or methyl, R 10 is C 4 -C 19 -n-alkyl, and R 11 and R 12 are each hydrogen.
Claim 3
Dependent Claim 36 words
A phenol according to claim 1, wherein Y is -P(OR 7 )- or -P(═O)(OR 7 )-, wherein R 7 is C 1 -C 18 -n-alkyl or phenyl, and R 10 is C 4 -C 18 -n-alkyl.
Claim 4
Dependent Claim 49 words
A phenol according to claim 1, wherein r 1 is methyl, R 2 is hydrogen, R 3 is tert.-butyl, Y is -P(O-phenyl), R 6 is a radical -CH 2 -CHR 9 -S-CH 2 R 10 , R 9 is methyl, and R 10 is C 4 -C 12 -n-alkyl.
Claim 5
Dependent Claim 37 words
A phenol according to claim 1, wherein R 1 is methyl, R 2 is hydrogen, R 3 is tert.-butyl, R 6 is -CH 2 -CH(CH 3 )-S-(CH 2 ) 9 -CH 3 , and Y is -P(O-phenyl)-.
Claim 6
Dependent Claim 12 words
A stabilizing polyolefin according to claim 4, wherein the polyolefin is polypropylene.
Claim 7
Dependent Claim 20 words
A polyolefin which contains a compound according to claim 1 in an amount sufficient to stabilize the polyolefin against oxidation.

References Cited (Backward Citations)

US3662032A Cited
US3655718A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-01-20 1984-07-21 1985-01-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-01-20 1988-07-21 1989-01-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-01-20 1992-07-21 1993-01-20 $7700.00 Window Closed / Lapsed

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