US4246134A
Expired / Lapsed
US
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Catalyst for di-, oligo-, co- and poly- merization of vinyl monomers
Assignee: Individual
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Filing: 1978-11-27
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Granted: 1981-01-20
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Expires: 1998-11-27
Abstract
Abstract A catalyst according to the present invention for di-, oligo-, co- and poly- merization of vinyl monomers consists of an active phase comprising a compound of a transition metal of Groups IV-V of the periodic system deposited onto a polymeric carrier, viz, a macroporous copolymer of vinyl and divinyl monomers with a specific surface area of 30 to 700 m 2 /g and a co-catalyst such as an organo-aluminum compound. The catalyst according to the present invention makes it possible to obtain dimers in high yields of more than 6,000 kg as calculated for 1 g of the transition metal for 2 hours and polymers in yields of up to 72 kg per 1 g of the transition metal. The catalyst according to the present invention makes it possible to control the particle size of the resulting (co) polymer which enables the use of the (co) polymer avoiding the stage of granulation.
Inventors
- 👤 Boris A. Uvarov
- 👤 Valentina I. Tsvetkova
- 👤 Fridrikh S. Dyachkovsky
- 👤 Oleg M. Zvyagin
- 👤 Vladimir P. Konovalov
- 👤 Elvira A. Uvarova
- 👤 Elena I. Ljustgarten
- 👤 Ljudmila A. Novokshonova
- 👤 Olga I. Kudinova
- 👤 Tatyana A. Maklakova
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 03:53
CPC Classifications
C; C08; C08F; C08F10/00; B; B01; B01J; B01J27/00; B01J27/06; B01J27/08; B01J27/10; B01J31/00; B01J31/02; B01J31/06; B01J31/12; B01J31/14; B01J31/143; B01J31/26; B01J31/36; B01J31/38; C07; C07C; C07C2/00; C07C2/02; C07C2/04; C07C2/06; C07C2/08; C07C2/26; C07C2/30; B01J2231/00; B01J2231/10; B01J2231/12; B01J2231/20; C07C2527/00; C07C2527/06; C07C2527/133; C07C2527/135; C07C2531/00; C07C2531/02; C07C2531/06; C07C2531/12; C07C2531/14; C07C2531/26; C07C2531/36; C07C2531/38; Y; Y10; Y10S; Y10S526/00; Y10S526/904
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
75 words
In a catalyst for di-, oligo-, co- and poly- merization of the vinyl monomers comprising an active phase, which consists of a transition metal compound selected from Groups IV-V of the periodic system and a co-catalyst consisting of an organo-aluminum compound, the improvement of which comprises depositing said catalyst onto a polymeric carrier comprising a macroporous copolymer of vinyl and divinyl monomers with a specific surface area of from 30 to 700 m 2 /g.
Claim 2
Dependent Claim
75 words
In a catalyst for di-, oligo-, co- and poly- merization of the vinyl monomers comprising an active phase, which consists of a transition metal compound selected from Groups IV-V of the periodic system and a co-catalyst consisting of an organo-aluminum compound, the improvement of which comprises depositing said catalyst onto a polymeric carrier comprising a macroporous copolymer of vinyl and divinyl monomers with a specific surface area of from 30 to 700 m 2 /g.
Claim 3
Dependent Claim
22 words
A catalyst as claimed in claim 1, wherein said carrier has a pore volume of from 0.3 to 2.8 cm 3 /g.
Claim 4
Dependent Claim
19 words
A catalyst as claimed in claim 1, wherein the carrier is made of a copolymer of styrene and divinylbenzene.
Claim 5
Dependent Claim
19 words
A catalyst as claimed in claim 1, wherein the carrier is made of a copolymer of styrene and diisopropenylbenzene.
Claim 6
Dependent Claim
20 words
A catalyst as claimed in claim 1, wherein the carrier is made of a copolymer of styrene, divinylbenzene and methylmethacrylate.
Claim 7
Dependent Claim
20 words
A catalyst as claimed in claim 1, wherein the carrier is made of a copolymer of styrene, ethyldivinylbenzene and vinylpyridine.
Claim 8
Dependent Claim
17 words
A catalyst as claimed in claim 1, having a particle size of from 0.001 to 1 mm.
Claim 9
Dependent Claim
11 words
A catalyst as claimed in claim 1, having a granulated form.
Claim 10
Dependent Claim
28 words
A catalyst as claimed in claim 1, wherein the active phase is made of a compound of a metal selected from the group consisting of vanadium and titanium.
Claim 11
Dependent Claim
21 words
A catalyst as claimed in claim 1, wherein the content of the active phase ranges from 1 to 60% by weight.
Claim 12
Dependent Claim
14 words
A catalyst as claimed in claim 9, wherein the active phase is titanium chloride.
Claim 13
Dependent Claim
14 words
A catalyst as claimed i claim 9, wherein the active phase is vanadium chloride.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-01-20 | 1984-07-21 | 1985-01-20 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-01-20 | 1988-07-21 | 1989-01-20 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-01-20 | 1992-07-21 | 1993-01-20 | $7700.00 | Window Closed / Lapsed |