US4246016A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method of making graded refractive index fibers and rods
Assignee: Warner Lambert Technologies Inc
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Filing: 1979-03-07
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Granted: 1981-01-20
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Expires: 1999-03-07
Abstract
Abstract Gradient refractive index fibers or rods are formed of leachable glass clad glass core preforms drawn to a desired diametral size, bundled together, fused under high compressing forces and rapidly interdiffused at a temperature above their deformation point. Cooling, annealing and separation of the fibers or rods by leaching provides the end product devices which may be cut into lengths required for the lens power desired and end polished. The refractive index gradient is produced by interdiffusion of T1 + and K + ions between core and cladding glasses which are selected to contain substantial proportions of thallium oxide and potassium oxide respectively.
Inventors
- 👤 Walter P. Siegmund
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 17:23
CPC Classifications
C; C03; C03C; C03C21/00; C03B; C03B23/00; C03B23/04; C03B23/047; C03B23/20; C03B23/207; C03B37/00; C03B37/01; C03B37/012; C03B37/01205; C03B37/02; C03B37/025; C03B37/027; C03B37/10; C03B37/14; C03B37/15; C03B2201/00; C03B2201/06; C03B2201/30; C03B2201/50; C03B2203/00; C03B2203/10; C03B2203/22; C03B2203/26; C03B2203/34; C03C2218/00; C03C2218/30; C03C2218/355; G; G02; G02B; G02B6/00; G02B6/02; G02B6/028; G02B6/0281
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
189 words
The method of producing a graded refractive index rod or fiber article comprising the steps of: applying to a glass preform containing a substantial proportion of a modifying oxide a leachable glass cladding having an affinity to ions of the modifying oxide; heating and drawing the clad preform into an element of a reduced cross-sectional size corresponding to that desired of said article; supporting said clad element against the deformation with applied high isostatic pressure; reheating said clad element while supported against deformation to a temperature above its deformation temperature and for a period of time sufficient to effect extraction of ions of the modifying oxide into said cladding through the contact surface between said drawn preform and cladding, the rate of extraction of ions being a function of temperature and said isostatic supporting pressure permitting application of higher than deformation temperatures for rapid diffusion of ions of said modifying oxide into said cladding; cooling and annealing said modified clad element following said extraction of ions and removing said applied pressure; and leaching said cladding away from said element, said element constituting said graded refractive index rod or fiber.
Claim 2
Independent Claim
189 words
The method of producing a graded refractive index rod or fiber article comprising the steps of: applying to a glass preform containing a substantial proportion of a modifying oxide a leachable glass cladding having an affinity to ions of the modifying oxide; heating and drawing the clad preform into an element of a reduced cross-sectional size corresponding to that desired of said article; supporting said clad element against the deformation with applied high isostatic pressure; reheating said clad element while supported against deformation to a temperature above its deformation temperature and for a period of time sufficient to effect extraction of ions of the modifying oxide into said cladding through the contact surface between said drawn preform and cladding, the rate of extraction of ions being a function of temperature and said isostatic supporting pressure permitting application of higher than deformation temperatures for rapid diffusion of ions of said modifying oxide into said cladding; cooling and annealing said modified clad element following said extraction of ions and removing said applied pressure; and leaching said cladding away from said element, said element constituting said graded refractive index rod or fiber.
Claim 3
Dependent Claim
35 words
The method according to claim 1 wherein said modifying oxide is thallium oxide and said cladding having an affinity to ions of the modifying oxide comprises a glass containing a substantial proportion of potassium oxide.
Claim 4
Dependent Claim
26 words
The method according to claim 2 wherein said reheating of said clad element effects interdiffusion of Tl + and K + ions through said contact surface.
Claim 5
Dependent Claim
17 words
A method according to claim 1 wherein said high isostatic pressure is applied with a mechanical press.
Claim 6
Dependent Claim
29 words
The method according to claim 2 wherein said cladding is leached in an acid and said element is cleaned of residue of said acid following said step of leaching.
Claim 7
Independent Claim
235 words
The method of mass producing graded refractive index rod or fiber articles comprising the steps of: applying to a glass preform containing a substantial proportion of a modifying oxide a leachable glass cladding having an affinity to ions of the modifying oxide; heating and drawing the clad preform into a long clad element of a reduced cross-sectional size corresponding to that desired of each of said articles; dividing said long element into a number of shorter lengths; bundling said shorter lengths of said element together; heating said bundle sufficiently to fuse said claddings of said lengths of said element together; applying a high substantially isostatic compressing force to said bundle for support against deformation and further heating said bundle while supported against deformation to a temperature above the deformation temperature of said lengths of said element for a period of time sufficient to effect extraction of ions of the modifying oxide into said claddings of said lengths of said elements, the rate of extraction of ions being a function of temperature and said isostatic supporting pressure permitting application of higher than deformation temperatures for rapid diffusion of ions of said modifying oxide into said cladding; cooling and annealing said bundle following said extraction of ions and removing said applied pressure; and leaching said claddings away from said lengths of said element, said leached lengths constituting said mass produced graded refractive index rod or fiber articles.
Claim 8
Independent Claim
235 words
The method of mass producing graded refractive index rod or fiber articles comprising the steps of: applying to a glass preform containing a substantial proportion of a modifying oxide a leachable glass cladding having an affinity to ions of the modifying oxide; heating and drawing the clad preform into a long clad element of a reduced cross-sectional size corresponding to that desired of each of said articles; dividing said long element into a number of shorter lengths; bundling said shorter lengths of said element together; heating said bundle sufficiently to fuse said claddings of said lengths of said element together; applying a high substantially isostatic compressing force to said bundle for support against deformation and further heating said bundle while supported against deformation to a temperature above the deformation temperature of said lengths of said element for a period of time sufficient to effect extraction of ions of the modifying oxide into said claddings of said lengths of said elements, the rate of extraction of ions being a function of temperature and said isostatic supporting pressure permitting application of higher than deformation temperatures for rapid diffusion of ions of said modifying oxide into said cladding; cooling and annealing said bundle following said extraction of ions and removing said applied pressure; and leaching said claddings away from said lengths of said element, said leached lengths constituting said mass produced graded refractive index rod or fiber articles.
Claim 9
Dependent Claim
26 words
The method according to claim 6 wherein said modifying oxide is thallium oxide and said claddings comprise a glass containing a substantial proportion of potassium oxide.
Claim 10
Dependent Claim
24 words
The method according to claim 7 wherein said further heating of said bundle effects diffusion of Tl + ions into claddings of said elements.
Claim 11
Dependent Claim
18 words
The method according to claim 8 wherein said high isostatic compressing force is applied with a mechanical press.
Claim 12
Dependent Claim
39 words
The method according to claim 6 wherein said claddings are leached from said lengths of said element in an acid and said leached lengths of said element are cleaned of residue of said acid following said step of leaching.
References Cited (Backward Citations)
US3004368A
Cited
US2980957A
Cited
US3037241A
Cited
US4002452A
Cited
US3941474A
Cited
US3801181A
Cited
US3843228A
Cited
US3626040A
Cited
US3791806A
Cited
US3624816A
Cited
US3674452A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-01-20 | 1984-07-21 | 1985-01-20 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-01-20 | 1988-07-21 | 1989-01-20 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-01-20 | 1992-07-21 | 1993-01-20 | $7700.00 | Window Closed / Lapsed |