US4245084A
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Thermotropic, wholly aromatic polythiolesters capable of forming an anisotropic melt and a process for preparing the polythiolesters
Assignee: Celanese Corp
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Filing: 1979-05-07
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Granted: 1981-01-13
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Expires: 1999-05-07
Abstract
Abstract Thermotropic, wholly aromatic polythiolesters exhibit an anisotropic melt. The polythiolesters may be prepared from monomers selected such that all or substantially all of the repeating groups are thiolester groups. Alternatively, the monomers can be selected such that sufficient thiolester groups are present to impart processability to a normally non-tractable polyester. Preparation of the polythiolesters is typically accomplished by melt polymerization of an esterified aromatic mercaptan compound, either alone or with other copolymerizable monomers. The polythiolesters may be melt processed into fibers, films or other types of shaped articles.
Inventors
- 👤 Eui W. Choe
- 👤 Gordon W. Calundann
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 10:08
CPC Classifications
C; C08; C08G; C08G75/00; C08G75/26
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
61 words
A thermotropic, wholly aromatic polythiolester capable of forming an anisotropic melt, said polythiolester being comprised of a recurring unit selected from the group consisting of: ##STR9## III mixtures of I and II, IV mixtures of at least one of I or II and wherein Ar is unsubstituted or substituted aromatic moieties selected from the group consisting of: ##STR10## (k) mixtures thereof.
Claim 2
Dependent Claim
61 words
A thermotropic, wholly aromatic polythiolester capable of forming an anisotropic melt, said polythiolester being comprised of a recurring unit selected from the group consisting of: ##STR9## III mixtures of I and II, IV mixtures of at least one of I or II and wherein Ar is unsubstituted or substituted aromatic moieties selected from the group consisting of: ##STR10## (k) mixtures thereof.
Claim 3
Dependent Claim
18 words
The polythiolester of claim 1 wherein Ar is selected from the group consisting of: ##STR11## (d) mixtures thereof.
Claim 4
Dependent Claim
49 words
A thermotropic, wholly aromatic polythiolester capable of forming an anisotropic melt, said polythiolester being tractable and being comprised of recurring units selected from the group consisting of: ##STR12## III mixtures thereof, wherein Ar is unsubstituted or substituted aromatic moieties selected from the group consisting of: ##STR13## (k) mixtures thereof.
Claim 5
Dependent Claim
49 words
A thermotropic, wholly aromatic polythiolester capable of forming an anisotropic melt, said polythiolester being tractable and being comprised of recurring units selected from the group consisting of: ##STR12## III mixtures thereof, wherein Ar is unsubstituted or substituted aromatic moieties selected from the group consisting of: ##STR13## (k) mixtures thereof.
Claim 6
Dependent Claim
121 words
A process for preparing a thermotropic, wholly aromatic polythiolester capable of forming an anisotropic melt comprising: (a) esterifying at least one aromatic mercapto compound selected from the group consisting of: ##STR14## and H S--Ar--X--H wherein X is S or O and Ar is selected from the group consisting of: ##STR15## (11) mixtures thereof, (b) heating the esterified compound to a temperature of from about 240° to about 340° C. for from about 2 to about 6 hours; (c) reducing the ambient pressure to from about ambient pressure to about 1.0 mm. Hg. for from about 10 to about 30 minutes, while maintaining the reaction temperature in the range of from about 300° to about 325° C.; and (d) recovering the polythiolester.
Claim 7
Dependent Claim
121 words
A process for preparing a thermotropic, wholly aromatic polythiolester capable of forming an anisotropic melt comprising: (a) esterifying at least one aromatic mercapto compound selected from the group consisting of: ##STR14## and H S--Ar--X--H wherein X is S or O and Ar is selected from the group consisting of: ##STR15## (11) mixtures thereof, (b) heating the esterified compound to a temperature of from about 240° to about 340° C. for from about 2 to about 6 hours; (c) reducing the ambient pressure to from about ambient pressure to about 1.0 mm. Hg. for from about 10 to about 30 minutes, while maintaining the reaction temperature in the range of from about 300° to about 325° C.; and (d) recovering the polythiolester.
Claim 8
Dependent Claim
13 words
The process of claim 4 wherein the aromatic mercapto compound is initially acetylated.
Claim 9
Dependent Claim
19 words
The process of claim 5 wherein steps (b), (c), and (d) are performed in the substantial absence of oxygen.
Claim 10
Dependent Claim
46 words
The process of claim 6 wherein the acetylated aromatic mercapto compound is present in an amount ranging from about 10 to about 30 mole %, based on the total number of moles present, and the balance is comprised of monomers which form a normally non-tractable polyester.
Claim 11
Dependent Claim
22 words
The process of claim 7 wherein the acetylated aromatic mercapto compound is 4-mercaptophenol diacetate and the polyester forming monomer is p-hydroxy-benzoic acid.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-01-13 | 1984-07-14 | 1985-01-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-01-13 | 1988-07-14 | 1989-01-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-01-13 | 1992-07-14 | 1993-01-13 | $7700.00 | Window Closed / Lapsed |