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US4245036A Expired / Lapsed US ⏱️ 0.0 years remaining

Emulsifier-free latexes and photographic light-sensitive elements containing them

Assignee: Agfa Gevaert NV
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Filing: 1979-10-19
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Granted: 1981-01-13
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Expires: 1999-10-19
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Abstract

Abstract A latex is formed of a copolymer of 90 to 98% by weight of ethyl acrylate and 2 to 10% by weight of an ionogenic comonomer. The latter comprises in its structure a polymerizable ethylenically unsaturated bond, a hydrophobic chain comprising at least 8 carbon atoms, and a strong hydrophilic group taken from a sulpho group, a sulphato group or a phosphono group in acid or salt form. Photographic layers are described wherein the above latex is used as plasticizer for gelatin.

Inventors

  • 👤 Walter F. De Winter
  • 👤 Marcel J. Monbaliu
  • 👤 August M. Marien
  • 👤 Antoine R. Van Rossen

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 00:15
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/005; G03C1/04; G03C1/053; C; C08; C08F; C08F220/00; C08F220/02; C08F220/10; C08F220/12; C08F220/16; C08F220/18; C08F220/1802

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 230 words
A photographic element comprising a support and one or more hydrophilic colloid layers including at least one light-sensitive silver halide emulsion layer, wherein at least one of said hydrophilic colloid layers is formed from a coating composition comprising a mixture of an aqueous solution of gelatin and a latex of a copolymer of ethyl acrylate, characterized in that the copolymer comprises 90 to 98% by weight of ethyl acrylate units and 2 to 10% by weight of units of an ionogenic comonomer corresponding to the general formula: ##STR5## wherein: R 1 is hydrogen or methyl, n is 0 or an integer from 1 to 20, L is a trivalent linking moiety of the group consisting of ##STR6## R 2 is a hydrogen atom or an aliphatic branched or unbranched, saturated or unsaturated hydrocarbon group, R 3 is a monovalent chemical bond or a bivalent aliphatic hydrocarbon group, which may be interrupted by the group --COO-- or --CONR--, wherein R is hydrogen or C 1 -C 4 alkyl, Y is a hydrophilic group selected from sulpho, sulphato and phosphono in acid or salt form, wherein at least one of the groups represented by --(CH 2 ) n --, R 2 and R 3 is or comprises a hydrocarbon chain of at least 8 C-atoms, and wherein the copolymer particles in said latex have an average diameter of less than 100 nm.
Claim 2
Dependent Claim 230 words
A photographic element comprising a support and one or more hydrophilic colloid layers including at least one light-sensitive silver halide emulsion layer, wherein at least one of said hydrophilic colloid layers is formed from a coating composition comprising a mixture of an aqueous solution of gelatin and a latex of a copolymer of ethyl acrylate, characterized in that the copolymer comprises 90 to 98% by weight of ethyl acrylate units and 2 to 10% by weight of units of an ionogenic comonomer corresponding to the general formula: ##STR5## wherein: R 1 is hydrogen or methyl, n is 0 or an integer from 1 to 20, L is a trivalent linking moiety of the group consisting of ##STR6## R 2 is a hydrogen atom or an aliphatic branched or unbranched, saturated or unsaturated hydrocarbon group, R 3 is a monovalent chemical bond or a bivalent aliphatic hydrocarbon group, which may be interrupted by the group --COO-- or --CONR--, wherein R is hydrogen or C 1 -C 4 alkyl, Y is a hydrophilic group selected from sulpho, sulphato and phosphono in acid or salt form, wherein at least one of the groups represented by --(CH 2 ) n --, R 2 and R 3 is or comprises a hydrocarbon chain of at least 8 C-atoms, and wherein the copolymer particles in said latex have an average diameter of less than 100 nm.
Claim 3
Dependent Claim 47 words
A photographic element according to claim 1, wherein the latex is added to the aqueous gelatin-containing coating composition in an amount such that between 15 and 25% by weight of dry copolymer particles are present with respect to the combined dry weight of gelatin and copolymer particles.
Claim 4
Dependent Claim 34 words
A photographic element according to claim 1, wherein the layer formed from a coating composition comprising a mixture of an aqueous solution of gelatin and said latex is the light-sensitive silver halide emulsion layer.

References Cited (Backward Citations)

US3411911A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-01-13 1984-07-14 1985-01-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-01-13 1988-07-14 1989-01-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-01-13 1992-07-14 1993-01-13 $7700.00 Window Closed / Lapsed

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