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US4244848A Expired / Lapsed US ⏱️ 0.0 years remaining

Halogen containing resin composition

Assignee: Adeka Corp
•
Filing: 1979-01-31
•
Granted: 1981-01-13
•
Expires: 1999-01-31
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Abstract

Abstract An environmentally acceptable stabilizer composition is provided for enhancing the resistance to deterioration upon heating at 175 DEG C. of a vinyl chloride polymer from which lead, cadmium, mercury, thallium, and arsenic are substantially excluded, comprising (A) at least one zinc, alkali metal, or alkaline earth metal organic phosphate ester salt having per metal atom from one to a number equal to the valence of the metal of phosphate ester groups and from one to two organic groups per phosphate groups, the organic groups being alkyl, aryl, alkaryl, aralkyl, ether-interrupted allyl, or ether-interrupted aralkyl groups having from 1 to about 80 carbon atoms; and (B) at least one betadiketone compound having 5 to about 30 carbon atoms which is a cyclic or open-chain betadiketone or a zinc, alkali metal or alkaline earth metal salt thereof. A stabilized vinyl chloride polymer composition in which the environmentally acceptable composition is used as stabilizer is also provided.

Inventors

  • 👤 Motonobu Minagawa
  • 👤 Tetsuo Sekiguchi
  • 👤 Kenji Nakazawa

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 16:40
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/04; C08K5/07; C08K5/49; C08K5/51; C08K5/52; C08K5/521

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 253 words
An environmentally acceptable stabilizer composition for enhancing the resistance to deterioration upon heating at 175° C. of a vinyl chloride polymer from which lead, cadmium, mercury, thallium, and arsenic are substantially excluded, comprising (A) at least one dialkyltin, zinc, alkali metal, or alkaline earth metal organic phosphate ester salt having per metal atom from one to a number equal to the valence of the metal of phosphate ester groups and from one to two organic groups per phosphate groups, the organic groups being alkyl, aryl, alkaryl, aralkyl, ether-interrupted alkyl, or ether-interrupted aralkyl groups having from 1 to about 80 carbon atoms; and (B) at least one betadiketone compound having 5 to about 30 carbon atoms which is a cyclic or open-chain betadiketone or a zinc, alkali metal or alkaline earth metal salt thereof, and is represented by the formula ##STR23## in which n is one or two; X is linked with Y or with Z in a 5 to 6 membered carbocyclic or oxygen-heterocyclic ring structure or when not linked with Y or with Z is a hydrocarbon group, an alkoxyhydrocarbon group, or an alkylenedioxyhydrocarbon group having up to 18 carbon atoms; Y when not linked in a ring structure with X is a hydrogen atom, an acyl group ##STR24## where R'" is alkyl or aryl, or a hydrocarbon, alkoxyhydrocarbon, or alkylenedioxyhydrocarbon X group; Z is a hydrogen atom, a halohydrocarbon group, or a hydrocarbon, alkoxyhydrocarbon, or alkylenedioxyhydrocarbon X group; and M' is hydrogen, potassium, sodium, lithium, zinc, barium, strontium, calcium, or magnesium.
Claim 2
Dependent Claim 253 words
An environmentally acceptable stabilizer composition for enhancing the resistance to deterioration upon heating at 175° C. of a vinyl chloride polymer from which lead, cadmium, mercury, thallium, and arsenic are substantially excluded, comprising (A) at least one dialkyltin, zinc, alkali metal, or alkaline earth metal organic phosphate ester salt having per metal atom from one to a number equal to the valence of the metal of phosphate ester groups and from one to two organic groups per phosphate groups, the organic groups being alkyl, aryl, alkaryl, aralkyl, ether-interrupted alkyl, or ether-interrupted aralkyl groups having from 1 to about 80 carbon atoms; and (B) at least one betadiketone compound having 5 to about 30 carbon atoms which is a cyclic or open-chain betadiketone or a zinc, alkali metal or alkaline earth metal salt thereof, and is represented by the formula ##STR23## in which n is one or two; X is linked with Y or with Z in a 5 to 6 membered carbocyclic or oxygen-heterocyclic ring structure or when not linked with Y or with Z is a hydrocarbon group, an alkoxyhydrocarbon group, or an alkylenedioxyhydrocarbon group having up to 18 carbon atoms; Y when not linked in a ring structure with X is a hydrogen atom, an acyl group ##STR24## where R'" is alkyl or aryl, or a hydrocarbon, alkoxyhydrocarbon, or alkylenedioxyhydrocarbon X group; Z is a hydrogen atom, a halohydrocarbon group, or a hydrocarbon, alkoxyhydrocarbon, or alkylenedioxyhydrocarbon X group; and M' is hydrogen, potassium, sodium, lithium, zinc, barium, strontium, calcium, or magnesium.
Claim 3
Dependent Claim 30 words
A stabilizer composition according to claim 1 in which the organic phosphate ester salt is an alkyl phosphate ester salt having 8 to 18 carbon atoms in the alkyl group.
Claim 4
Dependent Claim 56 words
A stabilizer composition according to claim 1 in which the organic phosphate ester salt is an ether-interrupted alkyl phosphate ester salt having 3 to 50 carbon atoms and 1 to 24 ether oxygen atoms in each ether-interrupted alkyl group, the number of carbon atoms being at least one more than twice the number of etheroxygen atoms.
Claim 5
Dependent Claim 52 words
A stabilizer composition according to claim 1 in which the organic phosphate ester salt is an ether-interrupted aralkyl phosphate ester salt having 8 to 80 carbon atoms and 1 to 30 ether oxygen atoms, the number of carbon atoms being at least six more than twice the number of ether oxygen atoms.
Claim 6
Dependent Claim 28 words
A stabilizer composition according to claim 1 in which the organic phosphate ester salt is salt having one phosphate ester group and one organic group per metal atom.
Claim 7
Dependent Claim 22 words
A stabilizer composition according to claim 1 in which the organic phosphate ester salt has two organic groups per phosphate ester group.
Claim 8
Dependent Claim 18 words
A stabilizer composition according to claim 1 in which the organic phosphate ester salt is barium distearyl phosphate.
Claim 9
Dependent Claim 16 words
A stabilizer composition according to claim 1 in which the betadiketone compound is an open-chain betadiketone.
Claim 10
Dependent Claim 17 words
A stabilizer composition according to claim 1 in which the betadiketone compound is a betadiketone zinc salt.
Claim 11
Dependent Claim 54 words
A stabilizer composition according to claim 1 comprising as an added ingredient at least one stabilizer which is an organic phosphite, a 1,2-epoxide, or a zinc, magnesium, calcium, strontium or a barium salt of a non-nitrogenous monocarboxylic acid having 6 to 24 carbon atoms or a hydrocarbon-substituted phenol having 10 to 30 carbon atoms.
Claim 12
Dependent Claim 17 words
A stabilizer composition according to claim 1 in which the betadiketone compound is an oxygen-heterocyclic betadiketone compound.
Claim 13
Dependent Claim 14 words
A stabilizer composition according to claim 8 in which the betadiketone compound is dibenzoylmethane.
Claim 14
Dependent Claim 15 words
A stabilizer composition according to claim 11 in which the betakiketone compound is dehydrobenzoylacetic acid.
Claim 15
Dependent Claim 21 words
An environmentally acceptable stablized vinyl chloride polymer composition comprising a vinyl chloride polymer and a stabilizer composition according to claim 1.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-01-13 1984-07-14 1985-01-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-01-13 1988-07-14 1989-01-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-01-13 1992-07-14 1993-01-13 $7700.00 Window Closed / Lapsed

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