US4244807A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for the preparation of a hydrocarbon mixture rich in aromatics
Assignee: Shell USA Inc
•
Filing: 1979-05-21
•
Granted: 1981-01-13
•
Expires: 1999-05-21
Abstract
Abstract A process is disclosed for the preparation of a hydrocarbon mixture rich in aromatics from a gasoline boiling range hydrocarbon mixture low in aromatics which comprises catalytically reforming said hydrocarbon mixture followed by contacting the reformate with certain crystalline silicates at an elevated temperature.
Inventors
- 👤 Frits M. Dautzenberg
- 👤 Martinus M. P. Janssen
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 16:49
CPC Classifications
B; B01; B01J; B01J29/00; B01J29/87; B01J29/04; B01J29/88; C; C10; C10G; C10G59/00; C10G59/02
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
137 words
A process for the preparation of a hydrocarbon mixture rich in aromatics from a hydrocarbon mixture low in aromatics and boiling in the gasoline range, which comprises (a) catalytically reforming said hydrocarbon mixture; and (b) contacting at least part of the reformate from step (a) at a temperature from 250° to 625° C. with a catalyst containing a crystalline silicate, which (i) is thermally stable to temperatures above 600° C., (ii) after dehydration at 400° C. in vacuum, is capable of adsorbing more than 3%w water at 25° C. and saturated water vapor pressure, and (iii) in dehydrated form, has the following overall composition, expressed in moles of the oxides: (1.0±0.3)(R).sub.2/n O.[aFe.sub.2 O.sub.3.b.Al.sub.2 O.sub.3.cGa.sub.2 O.sub.3 ].y(dSiO.sub.2.eGeO.sub.2), where R=one or more mono or bivalent cations, a>0.5, b≧0, c≧0, a+b+c=1, y=10-300 d≧0.1, e≧0, d+e=1, and n=the valency of R.
Claim 2
Dependent Claim
137 words
A process for the preparation of a hydrocarbon mixture rich in aromatics from a hydrocarbon mixture low in aromatics and boiling in the gasoline range, which comprises (a) catalytically reforming said hydrocarbon mixture; and (b) contacting at least part of the reformate from step (a) at a temperature from 250° to 625° C. with a catalyst containing a crystalline silicate, which (i) is thermally stable to temperatures above 600° C., (ii) after dehydration at 400° C. in vacuum, is capable of adsorbing more than 3%w water at 25° C. and saturated water vapor pressure, and (iii) in dehydrated form, has the following overall composition, expressed in moles of the oxides: (1.0±0.3)(R).sub.2/n O.[aFe.sub.2 O.sub.3.b.Al.sub.2 O.sub.3.cGa.sub.2 O.sub.3 ].y(dSiO.sub.2.eGeO.sub.2), where R=one or more mono or bivalent cations, a>0.5, b≧0, c≧0, a+b+c=1, y=10-300 d≧0.1, e≧0, d+e=1, and n=the valency of R.
Claim 3
Dependent Claim
87 words
A process according to claim 1 wherein step (a), the catalytic reforming, is carried out by contacting the hydrocarbon mixture low in aromatics together with hydrogen at a temperature of from 400° to 600° C., a pressure of from 5 to 50 bar, and a space velocity of from 0.5 to 10 l.l -1 .h -1 with a catalyst containing from 0.01 to 3%w of one or more additional metals with an electronegativity between 1.6 and 2.0 and from 0.1 to 3%w halogen on a porous carrier.
Claim 4
Dependent Claim
75 words
A process according to claim 2 wherein the catalytic reforming is carried out at a temperature of from 450° to 550° C., a pressure of from 10 to 30 bar, and a space velocity of from 1 to 5 l.l -1 .h -1 and in the presence of a catalyst containin from 0.1 to 1%w platinum, from 0.05 to 2% w rhenium or germanium, and from 0.5 to 1.5%w chlorine on alumina as the carrier.
Claim 5
Dependent Claim
48 words
A process according to claim 1 wherein step (b), the contacting of the reformate, is carried out at a temperature of from 250° to 550° C., a pressure of from 5 to 225 bar, and a space velocity of from 0.1 to 250 l.l -1 .h -1 .
Claim 6
Dependent Claim
23 words
A process according to claim 1 wherein in step (b), the catalyst containing the silicate comprises one or more metals having hydrogenation activity.
Claim 7
Dependent Claim
23 words
A process according to claim 1 wherein in the formula which gives the overall composition of the silicate, a is at least 0.5.
Claim 8
Dependent Claim
44 words
A process according to claim 1 wherein in step (a), a full range naphtha is catalytically reformed, that the reformate is separated by distillation into a light reformate and a heavy reformate and that the light reformate is used as feed to step (b).
Claim 9
Dependent Claim
57 words
A process according to claim 1 wherein prior to step (a), a full range naphtha is separated by distillation into a light naphtha and a heavy naphtha that the light naphtha and the heavy naphtha are separately reformed in step (a) and that the reformate obtained from the light naphtha is used as feed to step (b).
Claim 10
Dependent Claim
56 words
A process according to claim 1 which comprises separating a full range naphtha by distillation into a light naphtha and a heavy naphtha, catalytically reforming in step (a) and the light naphtha, and mixing the reformate with the heavy naphtha, contacting said mixture in step (b) at an elevated temperature with the catalyst containing the silicate.
Claim 11
Dependent Claim
36 words
A process according to any one of claims 7-9 wherein a light hydrocarbon mixture consisting substantially of paraffins is added to the reformate which is contacted at an elevated temperature with the catalyst containing the silicate.
Claim 12
Dependent Claim
80 words
A process according to claim 1 which comprises catalytically reforming a full range naphtha in step (a), separating the reformate by distillation into a C 8 -fraction and a C 9 +fraction, contacting the C 9 +fraction in step (b) at an elevated temperature with the catalyst containing the silicate, separating from the product of step (b) by distillation, benzene, toluene, C 8 aromatics, and a C 9 +residual fraction, and recycling the C 9 +residual fraction to step (b).
Claim 13
Dependent Claim
142 words
A process according to claim 1 which comprises catalytically reforming a full range naphtha, splitting the reformate in the first separation section into a C 5 -fraction, a C 6 /C 7 fraction, and a C 7 +fraction, contacting separately the C 6 /C 7 fraction and part of the C 7 +fraction in step (b) at an elevated temperature with the catalyst containing the silicate, separating the product obtained in the conversion of the C 6 /C 7 fraction into a C 2 -fraction and a C 3 +fraction and recycling the C 3 +fraction to the first separation section, separating benzene, toluene, and C 8 aromatics from the product obtained in the conversion of the C 7 +fraction while recycling the remainder of said product to the first separation section, and separating liquified petroleum gas from the C 5 -fraction.
Claim 14
Dependent Claim
74 words
A process according to any one of claims 11 or 12 which comprises carrying out the conversion of the heavy reformate of step (b) in a reaction zone which holds a suspension of the catalyst containing the silicate at a temperature of from 475° to 625° C., a pressure of from 1 to 3 bar, a catalyst/oil weight ratio of from 4 to 25, and a residence time of from 2 to 15 seconds.
Claim 15
Dependent Claim
70 words
A process according to claim 11 or 12 which comprises separating from the mixture of C 8 aromatics obtained, paraxylene and ethylbenzene as the end products and that of the remaining mixture of orthoxylene and metaxylene at least the metaxylene is recycled to the reaction zone of step (b) in which the conversion of the heavy part of the reformate in presence of the catalyst containing the silicate takes place.
Claim 16
Dependent Claim
29 words
A process according to claim 14 which comprises separating paraxylene and ethylbenzene from the mixture of C 8 aromatics by adsorption onto a silicate as defined in claim 1.
References Cited (Backward Citations)
US3700585A
Cited
US3702886A
Cited
US3770614A
Cited
US3767568A
Cited
US3893906A
Cited
US3894939A
Cited
US3950241A
Cited
US3945913A
Cited
US3928174A
Cited
NL7613957A
Cited
US4208305A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-01-13 | 1984-07-14 | 1985-01-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-01-13 | 1988-07-14 | 1989-01-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-01-13 | 1992-07-14 | 1993-01-13 | $7700.00 | Window Closed / Lapsed |