US4243638A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Iron EDTA chelate catalyzed oxidation of uranium
Assignee: Wyoming Mineral Corp
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Filing: 1978-06-15
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Granted: 1981-01-06
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Expires: 1998-06-15
Abstract
Abstract Uranium ore deposits which contain uranium in the relatively insoluble tetravalent state are readily selectively leached in situ to recover relatively pure uranium compounds, by: (a) passing through the ore deposit a relatively dilute aqueous leach solution of ammonium bicarbonate, ferric ammonium ethylenediaminetetraacetic acid (EDTA), and a source of oxygen, the leach solution converting the tetravalent uranium to hexavalent uranium which readily dissolves in the leach solution; (b) withdrawing the reacted leach solution enriched in dissolved uranium from the ore deposit; and (c) stripping the uranium from the withdrawn leach solution. The stripping of the uranium from the leach solution is preferably accomplished by countercurrent flow of the enriched leach solution to a column of base anion exchange material which preferentially extracts the uranium. Base anion exchange material loaded with uranium is separated from the leach solution and is treated with an aqueous alkaline eluant to extract the uranium and to regenerate the base anion exchange material. The stripped leach solution is adjusted by adding ammonium bicarbonate, peroxide, and ferric ammonium EDTA, and its pH corrected if necessary, and the leach solution is recycled through the ore deposit. The uranium bearing eluant is then acidified and treated with ammonia to precipitate relatively pure ammonium diuranate (ADU).
Inventors
- 👤 John F. Jackovitz
- 👤 Armand J. Panson
- 👤 Earl A. Pantier
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 08:29
CPC Classifications
C; C22; C22B; C22B60/00; C22B60/02; C22B60/0204; C22B60/0217; C22B60/0252; C22B60/0265; C01; C01G; C01G43/00; C22B3/00; C22B3/04; C22B3/16; C22B3/1608; C22B3/1616; C22B3/165; E; E21; E21B; E21B43/00; E21B43/28; Y; Y02; Y02P; Y02P10/00; Y02P10/20
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
142 words
In the process of leaching and recovering of uranium from ore in which the uranium is the present in the tetravalent state, the steps comprising: (a) applying to the ore an aqueous leach solution comprising essentially from about 0.3 to 5 grams per liter of ammonium bicarbonate, from about 0.1 to 3 grams per liter of H 2 O 2 and ferric ammonium EDTA wherein the EDTA:Fe ratio is at least about 1.25:1, the ferric ammonium EDTA providing from 3 to 100 ppm of iron in the solution, the pH of the solution being about 7.4 to 9.5, the leach solution converting tetravalent uranium with which it comes in contact to the hexavalent state which then readily dissolves in the solution, (b) withdrawing from the ore leach solution enriched in uranium, and (c) stripping the uranium from the withdrawn uranium enriched solution.
Claim 2
Dependent Claim
142 words
In the process of leaching and recovering of uranium from ore in which the uranium is the present in the tetravalent state, the steps comprising: (a) applying to the ore an aqueous leach solution comprising essentially from about 0.3 to 5 grams per liter of ammonium bicarbonate, from about 0.1 to 3 grams per liter of H 2 O 2 and ferric ammonium EDTA wherein the EDTA:Fe ratio is at least about 1.25:1, the ferric ammonium EDTA providing from 3 to 100 ppm of iron in the solution, the pH of the solution being about 7.4 to 9.5, the leach solution converting tetravalent uranium with which it comes in contact to the hexavalent state which then readily dissolves in the solution, (b) withdrawing from the ore leach solution enriched in uranium, and (c) stripping the uranium from the withdrawn uranium enriched solution.
Claim 3
Dependent Claim
32 words
The process of claim 1, wherein the leach solution comprises from about 10 to 20 ppm of iron present as ferric ammonium EDTA with the EDTA:Fe ratio being about 1.5:1 to 2:1.
Claim 4
Dependent Claim
24 words
The process of claim 1, wherein the ammonium bicarbonate is introduced into the leach solution as a mixture of ammonium bicarbonate and ammonium carbamate.
Claim 5
Dependent Claim
146 words
In the process of leaching uranium from an ore deposit in which the uranium is in the tetravalent state, the steps comprising: (a) passing through the ore deposit an aqueous leach solution comprising from about 0.3 to 5 grams per liter of ammonium bicarbonate, sufficient ferric ammonium EDTA to provide from about 3 to 100 ppm of iron, the EDTA:Fe ratio being at least about 1.25:1, and oxygen being present in the leach solution, the pH of the leach solution being between 7.4 and 9.5, the oxygen being equivalent to that provided by from 0.1 to 3 grams per liter of H 2 O 2 , the oxygenous leach solution converting tetravalent uranium it contacts into the hexavalent state which dissolves in the leach solution, (b) withdrawing from the ore deposit uranium enriched leach solution, and (c) stripping the uranium from the withdrawn enriched leach solution.
Claim 6
Dependent Claim
146 words
In the process of leaching uranium from an ore deposit in which the uranium is in the tetravalent state, the steps comprising: (a) passing through the ore deposit an aqueous leach solution comprising from about 0.3 to 5 grams per liter of ammonium bicarbonate, sufficient ferric ammonium EDTA to provide from about 3 to 100 ppm of iron, the EDTA:Fe ratio being at least about 1.25:1, and oxygen being present in the leach solution, the pH of the leach solution being between 7.4 and 9.5, the oxygen being equivalent to that provided by from 0.1 to 3 grams per liter of H 2 O 2 , the oxygenous leach solution converting tetravalent uranium it contacts into the hexavalent state which dissolves in the leach solution, (b) withdrawing from the ore deposit uranium enriched leach solution, and (c) stripping the uranium from the withdrawn enriched leach solution.
Claim 7
Dependent Claim
20 words
The process of claim 4, wherein the oxygen in the leach solution is provided by a gas containing free oxygen.
Claim 8
Dependent Claim
24 words
The process of claim 4, wherein the ammonium bicarbonate is introduced into the leach solution as a mixture of ammonium bicarbonate and ammonium carbamate.
Claim 9
Dependent Claim
39 words
The process of claim 4, wherein the ferric ammonium EDTA is applied in the amount of from about 0.05 to 0.5 pound per ton of uraniferous ore containing about 0.2 to 0.02% of U 3 O 8 by weight.
Claim 10
Dependent Claim
280 words
In the process of in situ leaching and recovery of uranium from an ore deposit containing uranium associated with proportions of one or more undesirable metals and elements such as molybdenum, vanadium, selenium, arsenic and copper, the steps comprising: (a) passing through the ore deposit an aqueous leach solution comprising essentially from about 0.3 to 5 grams per liter of ammonium bicarbonate, sufficient ferric ammonium EDTA to provide from about 3 to 100 ppm of iron, with an EDTA:Fe ratio of at least 1.25:1, and from about 0.1 to 3 grams per liter of H 2 O 2 , the leach solution having a pH of between 7.4 and 9.5, the leach solution converting any tetravalent uranium it contacts to the hexavalent state which readily dissolves in the leach solution, (b) withdrawing from the ore deposit the uranium enriched leach solution, (c) contacting the withdrawn uranium enriched leach solution with a base anion exchange material to cause the uranium to be extracted from the leach solution and to be retained in the ion exchange material, (d) separating the ion exchange material loaded with extracted uranium from the stripped leach solution, (e) applying an aqueous alkaline eluant solution to separated uranium loaded ion exchange material to extract and dissolve the uranium therefrom, and to regenerate the ion exchange material for reuse to extract more uranium from leach solutions, and (f) acidifying the uranium containing eluate solution and then introducing ammonia to precipitate relatively pure ammonium diuranate therefrom, the several leaching, ion exchange extraction and eluant treatment steps each resulting in a lower proportion of said other metals and elements to the uranium being present than in the original ore deposit proportions.
Claim 11
Dependent Claim
280 words
In the process of in situ leaching and recovery of uranium from an ore deposit containing uranium associated with proportions of one or more undesirable metals and elements such as molybdenum, vanadium, selenium, arsenic and copper, the steps comprising: (a) passing through the ore deposit an aqueous leach solution comprising essentially from about 0.3 to 5 grams per liter of ammonium bicarbonate, sufficient ferric ammonium EDTA to provide from about 3 to 100 ppm of iron, with an EDTA:Fe ratio of at least 1.25:1, and from about 0.1 to 3 grams per liter of H 2 O 2 , the leach solution having a pH of between 7.4 and 9.5, the leach solution converting any tetravalent uranium it contacts to the hexavalent state which readily dissolves in the leach solution, (b) withdrawing from the ore deposit the uranium enriched leach solution, (c) contacting the withdrawn uranium enriched leach solution with a base anion exchange material to cause the uranium to be extracted from the leach solution and to be retained in the ion exchange material, (d) separating the ion exchange material loaded with extracted uranium from the stripped leach solution, (e) applying an aqueous alkaline eluant solution to separated uranium loaded ion exchange material to extract and dissolve the uranium therefrom, and to regenerate the ion exchange material for reuse to extract more uranium from leach solutions, and (f) acidifying the uranium containing eluate solution and then introducing ammonia to precipitate relatively pure ammonium diuranate therefrom, the several leaching, ion exchange extraction and eluant treatment steps each resulting in a lower proportion of said other metals and elements to the uranium being present than in the original ore deposit proportions.
Claim 12
Dependent Claim
54 words
The process of claim 8, wherein the stripped leach solution as separated in step (d), is adjusted by adding more ammonium bicarbonate, H 2 O 2 , and ferric ammonium EDTA and ammonia to bring the leach solution to full leach strength as in step (a), and is then recirculated through the ore deposit.
Claim 13
Dependent Claim
22 words
The process of claim 8, wherein the ammonium bicarbonate in the leach solution comprises a mixture of ammonium bicarbonate and ammonium carbamate.
Claim 14
Dependent Claim
45 words
The process of claim 8, wherein after the uranium has been leached out of the ore deposit, there is passed a reducing aqueous solution to cause any residues of uranium and the other metals and elements to be rendered insoluble in water and to precipitate.
Claim 15
Dependent Claim
34 words
The process of claim 8, wherein the aqueous leach solution comprises from about 10 to 20 ppm of iron present as ferric ammonium EDTA with the EDTA:Fe ratio being from about 1.5:1 to 2:1.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-01-06 | 1984-07-07 | 1985-01-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-01-06 | 1988-07-07 | 1989-01-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-01-06 | 1992-07-07 | 1993-01-06 | $7700.00 | Window Closed / Lapsed |