US4238401A
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Alkoxysilicon materials and method for making
Assignee: General Electric Co
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Filing: 1978-07-24
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Granted: 1980-12-09
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Expires: 1998-07-24
Abstract
Abstract Alkoxysilyl ethers of 1,3-dicarbonyl cyclic compounds, such as methoxy tris-5,5-dimethyl-cyclohexen-2-one-3-yloxy silane can be made by effecting reaction in the presence of an acid acceptor between an alkanol, a halosilane and a 1,3-dicarbonyl cyclic organic compound, for example, 5,5-dimethyl-1,3-cyclohexane dione. The alkoxysilyl ethers are useful as vulcanizing agents for silanol terminated polydiorganosiloxanes.
Inventors
- 👤 James A. Cella
- 👤 Tyrone D. Mitchell
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 03:17
CPC Classifications
C; C07; C07F; C07F7/00; C07F7/02; C07F7/04; C07F7/08; C07F7/18; C07F7/1804; C07F7/06
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
3 words
The compound ##STR10##
Claim 2
Dependent Claim
3 words
The compound ##STR10##
Claim 3
Dependent Claim
3 words
The compound ##STR11##
Claim 4
Dependent Claim
3 words
The compound ##STR11##
Claim 5
Dependent Claim
3 words
The compound ##STR12##
Claim 6
Dependent Claim
3 words
The compound ##STR12##
Claim 7
Dependent Claim
3 words
The compound ##STR13##
Claim 8
Dependent Claim
3 words
The compound ##STR13##
Claim 9
Independent Claim
132 words
A method for making an alkoxy-substituted 1,3-dicarbonylsilyl ether which comprises (1) effecting reaction between an aliphatic alcohol, an organohalosilane of the formula, (R).sub.a SiQ.sub.4-a and a 1,3-dione of the formula, ##STR14## in the presence of an acid acceptor and (2) recovering the resulting alkoxy-substituted 1,3-dicarbonylsilyl ether from step (1), where R is a C.sub.(1-13) monovalent organic radical, R 1 is selected from hydrogen, halogen and R, X and Y are divalent radicals selected from --O--, --S--, and ##STR15## Z is a divalent C.sub.(1-13) organic radical selected from alkylene, cycloalkylene, arylene and a fused ring structure, a is a whole number having a value of from 0 to 2 inclusive, b and c are equal to 0 or 1, R 3 is selected from hydrogen and R radicals, Q is a halogen radical.
Claim 10
Independent Claim
132 words
A method for making an alkoxy-substituted 1,3-dicarbonylsilyl ether which comprises (1) effecting reaction between an aliphatic alcohol, an organohalosilane of the formula, (R).sub.a SiQ.sub.4-a and a 1,3-dione of the formula, ##STR14## in the presence of an acid acceptor and (2) recovering the resulting alkoxy-substituted 1,3-dicarbonylsilyl ether from step (1), where R is a C.sub.(1-13) monovalent organic radical, R 1 is selected from hydrogen, halogen and R, X and Y are divalent radicals selected from --O--, --S--, and ##STR15## Z is a divalent C.sub.(1-13) organic radical selected from alkylene, cycloalkylene, arylene and a fused ring structure, a is a whole number having a value of from 0 to 2 inclusive, b and c are equal to 0 or 1, R 3 is selected from hydrogen and R radicals, Q is a halogen radical.
Claim 11
Dependent Claim
119 words
1,3-silyl carbonyl ethers of the formula, ##STR16## where R is a C.sub.(1-13) monovalent organic radical, R 1 is selected from hydrogen, halogen and R, R 2 is a C.sub.(1-8) alkyl radical, X and Y are divalent radicals selected from --O--, --S-- and ##STR17## Z is a divalent C.sub.(1-13) organic radical selected from alkylene, cycloalkylene, arylene and a fused ring structure, b and c are equal to 0 or 1, R 3 is selected from hydrogen and R, d is a whole number having a value of from 0 to 2 inclusive, e is a whole number having a value of from 1 to 3 inclusive and the sum of d+e has a value of from 1 to 3 inclusive.
Claim 12
Dependent Claim
119 words
1,3-silyl carbonyl ethers of the formula, ##STR16## where R is a C.sub.(1-13) monovalent organic radical, R 1 is selected from hydrogen, halogen and R, R 2 is a C.sub.(1-8) alkyl radical, X and Y are divalent radicals selected from --O--, --S-- and ##STR17## Z is a divalent C.sub.(1-13) organic radical selected from alkylene, cycloalkylene, arylene and a fused ring structure, b and c are equal to 0 or 1, R 3 is selected from hydrogen and R, d is a whole number having a value of from 0 to 2 inclusive, e is a whole number having a value of from 1 to 3 inclusive and the sum of d+e has a value of from 1 to 3 inclusive.
References Cited (Backward Citations)
No citation records indexed.
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