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US4238388A Expired / Lapsed US ⏱️ 0.0 years remaining

Derivatives of 1,3,5-triazacycloheptane-2,4-dione and their use as polymer stabilizers

Assignee: Ciba Geigy SpA
•
Filing: 1979-06-20
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Granted: 1980-12-09
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Expires: 1999-06-20
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Abstract

Abstract New compounds are disclosed comprised in the formula <IMAGE> where R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12 are as defined in the specification and which have been found highly useful as stabilizers for polymers. Also the process for the preparation of the above new compounds is described.

Inventors

  • 👤 Giuseppe Cantatore
  • 👤 Paolo Cassandrini

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 02:52
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3467

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 308 words
A compound of formula ##STR16## in which: R 1 , R 12 , which can be the same or different, represent --O, --CN, a hydrogen liner or branched alkyl containing 1 to 20 carbon atoms, an alkynl or alkinyl containing 2 to 20 carbon atoms, benzyl, benzyl substituted by 1 to 3 alkyls containing 1 to 4 carbon atoms, hydroxybenzyl, hydroxybenzyl substituted by 1 to 3 alkyls containing 1 to 4 carbon atoms; a --COR 15 , --COOR 15 or --CONR 15 R 16 radical in which R 15 , R 16 , which can be equal or different, represent a linear or branched alkyl containing 1 to 20 carbon atoms, an alkynl containing 2 to 20 carbon atoms, a cycloalkyl containing 5 to 12 carbon atoms anaralkyl containing, 7 to 12 carbon atoms an aryl containing 7 to 12 carbon atoms, or when bonded to N they can be hydrogen, or together with the N to which they are bonded can form a nitrogenous heterocyclic ring of 5 to 8 terms; or a ##STR17## radical in which R 13 is hydrogen, methyl or phenyl, and R 14 is --OH, --CN, ##STR18## --OR 15 , --COOR 15 , --COR 15 , --OCOR 15 , --CONR 15 R 16 , --OCONR 15 R 16 , --NR 15 R 16 in which R 15 and R 16 are as heretofore defined; R 2 , R 3 , R 6 , R 7 , which can be equal or different, represent an alkyl containing 1 to 6 carbon atoms; R 4 , R 5 , which can be equal or different, represent hydrogen or an alkyl containing 1 to 6 carbon atoms; R 8 , R 9 , R 10 , R 11 , which can be equal or different, represent hydrogen or an alkyl containing 1 to 6 carbon atoms.
Claim 2
Dependent Claim 308 words
A compound of formula ##STR16## in which: R 1 , R 12 , which can be the same or different, represent --O, --CN, a hydrogen liner or branched alkyl containing 1 to 20 carbon atoms, an alkynl or alkinyl containing 2 to 20 carbon atoms, benzyl, benzyl substituted by 1 to 3 alkyls containing 1 to 4 carbon atoms, hydroxybenzyl, hydroxybenzyl substituted by 1 to 3 alkyls containing 1 to 4 carbon atoms; a --COR 15 , --COOR 15 or --CONR 15 R 16 radical in which R 15 , R 16 , which can be equal or different, represent a linear or branched alkyl containing 1 to 20 carbon atoms, an alkynl containing 2 to 20 carbon atoms, a cycloalkyl containing 5 to 12 carbon atoms anaralkyl containing, 7 to 12 carbon atoms an aryl containing 7 to 12 carbon atoms, or when bonded to N they can be hydrogen, or together with the N to which they are bonded can form a nitrogenous heterocyclic ring of 5 to 8 terms; or a ##STR17## radical in which R 13 is hydrogen, methyl or phenyl, and R 14 is --OH, --CN, ##STR18## --OR 15 , --COOR 15 , --COR 15 , --OCOR 15 , --CONR 15 R 16 , --OCONR 15 R 16 , --NR 15 R 16 in which R 15 and R 16 are as heretofore defined; R 2 , R 3 , R 6 , R 7 , which can be equal or different, represent an alkyl containing 1 to 6 carbon atoms; R 4 , R 5 , which can be equal or different, represent hydrogen or an alkyl containing 1 to 6 carbon atoms; R 8 , R 9 , R 10 , R 11 , which can be equal or different, represent hydrogen or an alkyl containing 1 to 6 carbon atoms.
Claim 3
Dependent Claim 94 words
A compound as claimed in claim 1 in which R 1 , R 12 , which can be equal or different, are hydrogen or a linear or branched C 1 -C 6 alkyl; R 2 , R 3 , R 6 , R 7 , which can be equal or different, are methyl or ethyl; R 4 , R 5 , which can be equal or different, are hydrogen or methyl; and R 8 , R 9 , R 10 , R 11 , which can be equal or different, are hydrogen or methyl.
Claim 4
Dependent Claim 10 words
A compound as claimed in claim 1 of formula ##STR19##
Claim 5
Dependent Claim 10 words
A compound as claimed in claim 1 of formula ##STR20##
Claim 6
Dependent Claim 10 words
A compound as claimed in claim 1 of formula ##STR21##
Claim 7
Dependent Claim 10 words
A compound as claimed in claim 1 of formula ##STR22##
Claim 8
Dependent Claim 10 words
A compound as claimed in claim 1 of formula ##STR23##
Claim 9
Dependent Claim 10 words
A compound as claimed in claim 1 of formula ##STR24##
Claim 10
Dependent Claim 48 words
A compound according to claim 1 of the formula (I), wherein R 2 and R 6 are methyl, R 4 is hydrogen or methyl, R 5 denotes hydrogen and R 3 and R 7 represent a group --CH 2 --R 4 wherein R 4 is as defined above.
Claim 11
Dependent Claim 29 words
A compound according to claim 9 of the formula (I), wherein R 2 , R 3 , R 6 , R 7 are methyl and R 4 is hydrogen.
Claim 12
Dependent Claim 47 words
Polymer compositions stabilised against light, heat and oxidation, comprising a synthetic polymer and a stabilising compound of formula I as claimed in claim 1, in a quantity of 0.01 to 5%, and preferably 0.1 to 1%, by weight with respect to the weight of the synthetic polymer.
Claim 13
Dependent Claim 21 words
Polymer compositions as claimed in claim 11, which in addition to the stabilisers also comprise other normal additives for synthetic polymers.
Claim 14
Dependent Claim 18 words
Polymer compositions as claimed in claim 11, wherein the synthetic polymer is high density or low density polyethylene.
Claim 15
Dependent Claim 13 words
Polymer compositions as claimed in claim 11, wherein the synthetic polymer is polypropylene.

References Cited (Backward Citations)

US3878199A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-12-09 1984-06-09 1984-12-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-12-09 1988-06-09 1988-12-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-12-09 1992-06-09 1992-12-09 $7700.00 Window Closed / Lapsed

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