Well stimulation method using foamed acid

Claim 2

In a method of treating a subterranean formation penetrated by a wellbore, wherein a foamed acid in which at least a portion of the formation is soluble is injected into the formation so that at least a portion of the formation is dissolved, the improvement which comprises: prior to injecting said foamed acid, injecting a gelled, substantially unfoamed fluid as a pad fluid for said subsequent stage of foamed acid.

Claim 3

The method of claim 1 wherein at least the foamed acid stage is injected at a rate and pressure sufficient to initiate or extend a fracture in said formation.

Claim 4

The method of claim 2 wherein the injection sequence of gelled pad fluid followed by foamed acid is repeated at least once.

Claim 5

The method of claim 3 wherein the gelling agent for the pad fluid is selected from the group consisting of guar gum and hydroxypropyl guar.

Claim 6

The method of claim 2 wherein at least one of the gelled pad fluid or the foamed acid contains a propping agent, said proppant containing stage being injected at a sufficient rate and pressure to initiate or extend a fracture in the formation.

Claim 7

The method of claim 1 or 2 wherein the gelling agent for the pad fluid is guar gum or hydroxypropyl guar gum.

Claim 8

The method of claim 1, 2, or 4 wherein each of the pad fluid and the foamed acid contains a foaming agent.

Claim 9

The method of claim 7 wherein the foaming agent in each of the pad fluid and the foamed acid comprises a blend of (A) at least one alkyltrimethylammonium chloride, wherein the alkyl chain length is from 8 to 18 carbon atoms and the mode alkyl chain length is 12 or 14 carbon atoms, and (B) an amine oxide selected from the group consisting of bis (2-hydroxyethyl) cocoamine oxide, dimethylhexadecylamine oxide, and dimethyl-hydrogenated tallowamine oxide, wherein Component (A) and Component (B) are in weight ratio to one another of (i) from about 45:55 to about 85:15 when Component (A) is cocotrimethyl ammonium chloride and Component (B) is bis (2-hydroxyethyl) cocoamine oxide, and (ii) from about 40:60 to about 95:5 when said Components (A) and (B) are selected so as to provide a combination other than cocotrimethyl ammonium chloride and bis (2-hydroxyethyl) cocoamine oxide.

Claim 10

The method of claim 8 wherein said foaming agent additionally includes: (C) an adduct of trimethyl-1-heptanol plus seven moles of ethylene oxide; and (D) a perfluorinated surfactant of the formula ##STR2## wherein A - is CI - , F - , I - , or Br - , wherein Components (C) and (D) are in a weight ratio to one another of from about 1:1 to about 40:1, and wherein each of the pad fluid and the foam (by weight of liquid phase) contains Components (A) and (B) in a combined concentration of from about 0.035 to about 0.5 weight percent and Components (C) and (D) in a combined concentration of from about 0.03 to about 0.1 weight percent.

Claim 11

The method of claim 9 wherein at least one of the pad fluid or the foam contains a propping agent, said proppant containing stage being injected at a sufficient rate and pressure to initiate or extend a fracture in the formation.

Claim 12

The method of claim 9 comprising as an initial step, injecting an aqueous, substantially foam-free and gelling agent-free acid into the formation; injecting said gelled pad fluid containing said foaming agent at a rate and pressure sufficient to initiate said fracture; injecting said foamed acid at a rate and pressure sufficient to extend said fracture; and injecting at least one additional cycle of said gelled pad fluid followed by foamed acid at a rate and pressure sufficient to further extend said fracture.

Claim 13

The method of claim 11 wherein the final stage of foamed acid is displaced with foamed brine.

Claim 14

The method of claim 1 wherein said pad fluid is a gelled brine.

Claim 15

The method of claim 13 wherein said pad fluid is a sodium chloride saturated gelled brine.

Claim 16

The method of claim 11 wherein said pad fluid is a gelled brine.

Claim 17

The method of claim 15 wherein said pad fluid is a sodium chloride saturated gelled brine.