Method of controlling fluid loss in acidizing treatment of a subterranean formation

Claim 2

In a method of treating a heterogenous permeable subterranean formation penetrated by a wellbore, wherein an acidizing fluid in which at least a portion of the formation is soluble is injected into the formation so that at least a portion of the formation is dissolved, the improvement which comprises: prior to injecting said acid, injecting an aqueous gelled fluid into the formation, said fluid containing dissolved therein, an inorganic water soluble metal halide or sulfate salt which does not precipitate in acid, in an amount effective to reduce the loss of the acidizing fluid to the more permeable portions of said formation, but not in excess of the amount necessary to saturate said gelled fluid.

Claim 3

The method of claim 1 wherein said salt is selected from those alkali metal and alkaline earth metal halides and sulfates which are soluble in said gelled fluid at least sufficiently so that said effective amount can be dissolved in said fluid.

Claim 4

The method of claim 2 wherein said salt is sodium chloride, calcium chloride, sodium sulfate, or potassium chloride, or a mixture thereof which does not react to form a precipitate.

Claim 5

The method of claim 3 wherein the salt is sodium chloride, potassium chloride, calcium chloride, or a mixture thereof.

Claim 6

The method of claim 4 wherein the salt is NaCl.

Claim 7

The method of claim 1 wherein the acid is an aqueous acid solution or a foamed aqueous acid solution.

Claim 8

The method of claim 6 wherein the acid is foamed.

Claim 9

The method of claim 6 wherein the acid is an aqueous hydrochloric acid solution containing a foaming agent and saturated with CO 2 .

Claim 10

The method of claim 6 wherein at least the following quantities of salt, calculated on an anhydrous basis, are employed in the gelled fluid, per gallon of gelled fluid: ______________________________________ Initial core permeability, md Minimum salt concentration ______________________________________ less than 1.8 md 1.5 lb/gal 1.8 md- 4 md 2 lb/gal greater than 4 md 3 lb/gal ______________________________________

Claim 11

The method of claim 9 wherein said salt is selected from those alkali metal and alkaline earth metal halides and sulfates which are soluble in said gelled fluid at least sufficiently so that said amount can be dissolved in said fluid.

Claim 12

The method of claim 10 wherein said salt is sodium chloride, potassium chloride, calcium chloride, sodium sulfate, or mixtures thereof which do not react to form a precipitate.

Claim 13

The method of claim 11 wherein sufficient salt is employed to substantially saturate the gelled fluid.

Claim 14

The method of claim 11 wherein at least one of the gelled fluid or the acid is injected at a rate and pressure sufficient to fracture said formation.

Claim 15

The method of claim 13 wherein the salt is NaCl, KCl, calcium chloride, or a mixture thereof.

Claim 16

The method of claim 14 wherein the salt is NaCl.

Claim 17

The method of claim 15 wherein sufficient salt is employed to substantially saturate the gelled fluid.

Claim 18

The method of claim 16 wherein at least one of the gelled fluid or the acid is injected at a rate and pressure sufficient to fracture said formation.

Claim 19

The method of claim 1 wherein the injection sequence of gelled pad fluid followed by an acidizing fluid is repeated at least once.

Claim 20

The method of claim 1 wherein the gelled pad fluid is substantially free of solids having a particle size of less than about 70 mesh, U.S. Sieve Series.

Claim 21

The method of claim 1 wherein the gelled pad fluid contains a propping agent, substantially all of said propping agent being retained on a 70 mesh screen, U.S. Sieve Series.

Claim 22

The method of claim 19 wherein the gelled pad fluid and the acidizing fluid are each substantially free of particulate solids.

Claim 23

The method of claim 1 wherein sufficient salt is employed to substantially saturate the gelled fluid.

Claim 24

The method of claim 1 wherein the acidizing fluid is an acid-in-oil emulsion and wherein the initial formation permeability is not in excess of about 1.5 millidarcies.