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US4236980A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for alkali metal chloride electrolysis

Assignee: Hoechst AG
•
Filing: 1979-10-18
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Granted: 1980-12-02
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Expires: 1999-10-18
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Abstract

Abstract For the electrolysis of an aqueous alkali metal chloride solution in a membrane cell with a perfluorinated cation exchange membrane it is important that there is only a minimum amount of cations of polyvalent metals, such as calcium. Otherwise, deposits within the membrane will occur, among other effects. It has been found that the disturbances caused by the above-mentioned cations can be considerably reduced, if an aliphatic polybasic phosphonic acid or the alkali metal salt thereof is added to the alkali metal chloride solution.

Inventors

  • 👤 Nikolaj Medic
  • 👤 Theodor Auel
  • 👤 Dieter Bergner
  • 👤 Jurgen Russow

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 19:50
CPC Classifications
C; C25; C25B; C25B1/00; C25B1/01; C25B1/34; C25B1/46

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 56 words
Process for the electrolysis of an aqueous alkali metal chloride solution which is contaminated by cations of polyvalent metals, in an electrolysis cell whose anode and cathode compartments are separated by a perfluorinated cation exchange membrane, which comprises adding to the alkali metal chloride solution an aliphatic polybasic phosphonic acid or the alkali metal salt thereof.
Claim 2
Dependent Claim 56 words
Process for the electrolysis of an aqueous alkali metal chloride solution which is contaminated by cations of polyvalent metals, in an electrolysis cell whose anode and cathode compartments are separated by a perfluorinated cation exchange membrane, which comprises adding to the alkali metal chloride solution an aliphatic polybasic phosphonic acid or the alkali metal salt thereof.
Claim 3
Dependent Claim 15 words
A process as claimed in claim 1, wherein the phosphonic acid is free of nitrogen.
Claim 4
Dependent Claim 25 words
A process as claimed in claim 1, wherein the phosphonic acid contains at least 2 PO 3 H 2 or COOH groups in the molecule.
Claim 5
Dependent Claim 24 words
A process as claimed in claim 1, which comprises interrupting the electrolysis current for a short time once to 10 times per 24 hours.

References Cited (Backward Citations)

US3849266A Cited
US3793163A Cited
US3988223A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-12-02 1984-06-02 1984-12-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-12-02 1988-06-02 1988-12-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-12-02 1992-06-02 1992-12-02 $7700.00 Window Closed / Lapsed

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