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US4234643A Expired / Lapsed US ⏱️ 0.0 years remaining

Tennis ball marking decalcomania

Assignee: GGA Corp A CORP OF DE
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Filing: 1978-05-30
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Granted: 1980-11-18
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Expires: 1998-05-30
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Abstract

Abstract A heat release type decalcomania for marking a tennis ball cover comprising a carrier sheet having on one surface thereof a clear film of thermosetting elastomer formed of a siliconized polyester composition and a blocked isocyanate composition which crosslink when heated at a temperature effecting release of the clear film from the carrier sheet and having on the clear film a composite design formed of a first color layer of a polyamide resin having a softening point of about 100° F. (38° C.) and a second color layer of a polyamide resin having a softening point of about 230° F. (110° C.) with both said layers having a low viscosity adapted to penetrate the tennis ball cover when the design is heated to a temperature at which said clear film is released from said carrier strip.

Inventors

  • 👤 Alan C. Grotefend
  • 👤 Stephen F. Thon

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 12:56
CPC Classifications
B; B32; B32B; B32B27/00; B32B27/06; B32B27/10; A; A63; A63B; A63B45/00; A63B45/02; B32B27/36; B32B27/40; B32B7/00; B32B7/04; B32B7/06; B44; B44C; B44C1/00; B44C1/16; B44C1/165; B44C1/17; B44C1/1712; D; D06; D06Q; D06Q1/00; D06Q1/12; B32B2262/00; B32B2262/02; B32B2262/0261; B32B2307/00; B32B2307/70; B32B2307/748; B32B2317/00; B32B2317/12; B32B2317/122; B32B2367/00; B32B2375/00; B32B2451/00; Y; Y10; Y10S; Y10S428/00; Y10S428/913; Y10S428/914; Y10T; Y10T428/00; Y10T428/24; Y10T428/24802; Y10T428/24843; Y10T428/24851; Y10T428/2486; Y10T428/24868; Y10T428/24876; Y10T428/24893; Y10T428/24901; Y10T428/24934; Y10T428/24942; Y10T428/31504; Y10T428/31725; Y10T428/31728; Y10T428/31736; Y10T428/31779; Y10T428/31783

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 264 words
A heat release type decalcomania for application to a section of textile material formed of felted polyamide-containing textile material which is thereafter adapted for vulcanizing to a rubber surface in a mold comprising; (a) a paper-like wax-free flexible temporary carrier strip; (b) a clear film on one surface of said carrier strip formed of a mixture containing a blocked isocyanate stable at room temperature in a mixture containing a polyester, and a silicone modified polyester which when heated to heat release temperature for application of said decalcomania are adapted to react to form a thermoset elastomeric film and effect the release of said clear film from said carrier strip, and said thermoset elastomeric film also having high temperature mold release properties when heated in said mold; and (c) a pigmented thermoplastic elastomeric design fixedly supported by said clear film formed of a first pigmented layer of thermoplastic elastomer which is comprised of a blend of polyamide resins having a softening point of about 100° F. (38° C.) and a second pigmented layer of thermoplastic elastomer superimposed on said first pigmented layer comprised of a blend of polyamide resins having a softening point of about 230° F. (110° C.), said first and second pigmented layers when heated above said softening points during the heating to effect release of said clear film from said carrier strip and during said vulcanizing having a viscosity which enables said layers penetrating deeply into said felted polyamide-containing textile material, and said second layer being non-tacky and resistant to offsetting when placed in contact with said carrier strip at room temperature.
Claim 2
Dependent Claim 264 words
A heat release type decalcomania for application to a section of textile material formed of felted polyamide-containing textile material which is thereafter adapted for vulcanizing to a rubber surface in a mold comprising; (a) a paper-like wax-free flexible temporary carrier strip; (b) a clear film on one surface of said carrier strip formed of a mixture containing a blocked isocyanate stable at room temperature in a mixture containing a polyester, and a silicone modified polyester which when heated to heat release temperature for application of said decalcomania are adapted to react to form a thermoset elastomeric film and effect the release of said clear film from said carrier strip, and said thermoset elastomeric film also having high temperature mold release properties when heated in said mold; and (c) a pigmented thermoplastic elastomeric design fixedly supported by said clear film formed of a first pigmented layer of thermoplastic elastomer which is comprised of a blend of polyamide resins having a softening point of about 100° F. (38° C.) and a second pigmented layer of thermoplastic elastomer superimposed on said first pigmented layer comprised of a blend of polyamide resins having a softening point of about 230° F. (110° C.), said first and second pigmented layers when heated above said softening points during the heating to effect release of said clear film from said carrier strip and during said vulcanizing having a viscosity which enables said layers penetrating deeply into said felted polyamide-containing textile material, and said second layer being non-tacky and resistant to offsetting when placed in contact with said carrier strip at room temperature.
Claim 3
Dependent Claim 43 words
A decalcomania as in claim 1, wherein said thermosetting elastomer contains a cellulose acetate butyrate resin having a high butyral content to facilitate forming a non-tacky air dry film prior to heating to effect release of said clear film from said carrier strip.
Claim 4
Dependent Claim 39 words
A decalcomania as in claim 1, wherein said blocked isocyanate when heated to a temperature of about 425° F. (218° C.) crosslinks with said siliconized polyester to form a thermosetting elastomeric film having said high temperature mold release properties.
Claim 5
Dependent Claim 29 words
A decalcomania as in claim 1, wherein each said polyamide resin mixture has a Brookfield viscosity less than 8 when heated to temperature of about 420° F. (216° C.).
Claim 6
Dependent Claim 31 words
A decalcomania as in claim 1, wherein said temporary carrier strip is a strip of unlimited length formed of thoroughly seasoned densified Kraft paper polished on both surfaces in roll form.

References Cited (Backward Citations)

GB928347A Cited
US3616176A Cited
US3539424A Cited
US3914484A Cited
US3922435A Cited
JPS4856014A Cited
CA979747A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-11-18 1984-05-19 1984-11-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-11-18 1988-05-19 1988-11-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-11-18 1992-05-19 1992-11-18 $7700.00 Window Closed / Lapsed

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