← Back to Patent Explorer
US4233046A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of making glass fibers having a reduced tendency to give gumming deposits

Assignee: PPG Industries Inc
•
Filing: 1979-06-22
•
Granted: 1980-11-11
•
Expires: 1999-06-22
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A method and composition are provided for producing an improved sized glass fiber strand that has a reduced tendency to form gummy deposits on fabrication machinery under high relative humidity conditions. The glass fiber strand is treated with a starch based forming size comprising about 50 to about 65 weight percent of the non-aqueous components of the composition being a starch containing cross-links that has been partially cooked along with a hydrogenated vegetable oil, or fatty triglyceride, cationic wetting agent, emulsifying agent, and water. The forming size composition can also contain a salt of a polyamino functional polyamide resin and a carboxylic acid and a wax and a coupling agent.

Inventors

  • 👤 Douglas M. Walser

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 15:01
CPC Classifications
C; C03; C03C; C03C25/00; C03C25/10; C03C25/24; C03C25/26; C03C25/32; C03C25/321; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2913; Y10T428/2933; Y10T428/2938

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 226 words
In a method of forming a sized glass fiber strand comprising drawing glass streams through orifices in a bushing to form individual glass fibers, moving the fibers away from the bushing at a high rate of speed and forming them into a strand, and applying to the fibers while they are moving at this speed and before they are formed into a strand a starch-based sizing solution; 4 percent to 52 percent by weight of the salt of a polyamino functional polyamide resin, said polyamino functional polyamide resin salt being formed from the condensation reaction product of a carboxylic acid and a polyamine, said polyamine having greater than 2 amine groups per molecule, and a carboxylic acid having 1 to 5 carbon atoms; 5 to 25 percent by weight of a wax from the group consisting of animal waxes, vegetable waxes, mineral waxes and synthetic waxes; and 9 percent to 77 percent by weight of a fatty triglyceride; and collecting the glass strands so produced; the improvement comprising: using in the size solution about 50 to about 65 weight percent based on the non-aqueous components in the solution of a starch containing cross-links that has been partially cooked to within about 50 percent of complete cooking so that the sized glass strands produced have a reduced tendency to form gummy deposits under high relative humidity conditions.
Claim 2
Dependent Claim 226 words
In a method of forming a sized glass fiber strand comprising drawing glass streams through orifices in a bushing to form individual glass fibers, moving the fibers away from the bushing at a high rate of speed and forming them into a strand, and applying to the fibers while they are moving at this speed and before they are formed into a strand a starch-based sizing solution; 4 percent to 52 percent by weight of the salt of a polyamino functional polyamide resin, said polyamino functional polyamide resin salt being formed from the condensation reaction product of a carboxylic acid and a polyamine, said polyamine having greater than 2 amine groups per molecule, and a carboxylic acid having 1 to 5 carbon atoms; 5 to 25 percent by weight of a wax from the group consisting of animal waxes, vegetable waxes, mineral waxes and synthetic waxes; and 9 percent to 77 percent by weight of a fatty triglyceride; and collecting the glass strands so produced; the improvement comprising: using in the size solution about 50 to about 65 weight percent based on the non-aqueous components in the solution of a starch containing cross-links that has been partially cooked to within about 50 percent of complete cooking so that the sized glass strands produced have a reduced tendency to form gummy deposits under high relative humidity conditions.
Claim 3
Dependent Claim 55 words
Method according to claim 1 wherein the cross-linked starch was partially cooked by heating the starch to a temperature in the range of about 220° F. to about 250° F. in a jet cooker at a pressure in the range of 90 to about 110 psi and cooling the starch to below around 190° F.
Claim 4
Dependent Claim 13 words
Method according to claim 1 wherein the fatty triglyceride is hydrogenated soybean oil.
Claim 5
Dependent Claim 10 words
Method according to claim 1 wherein the wax is paraffin.
Claim 6
Dependent Claim 19 words
Method according to claim 1 wherein the size contains 10 to 45 percent by weight of an alkyl imidazoline.
Claim 7
Dependent Claim 12 words
Method according to claim 1 wherein the carboxylic acid is acetic acid.
Claim 8
Dependent Claim 27 words
Method according to claim 1 wherein the starch is a cross-linked cornstarch having an amylose content of from 25 to 27 percent by weight of the starch.

References Cited (Backward Citations)

US3227192A Cited
US3615311A Cited
US3664855A Cited
US3928666A Cited
US3869308A Cited
US4066106A Cited
US4147833A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-11-11 1984-05-12 1984-11-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-11-11 1988-05-12 1988-11-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-11-11 1992-05-12 1992-11-11 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag