US4233046A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method of making glass fibers having a reduced tendency to give gumming deposits
Assignee: PPG Industries Inc
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Filing: 1979-06-22
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Granted: 1980-11-11
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Expires: 1999-06-22
Abstract
Abstract A method and composition are provided for producing an improved sized glass fiber strand that has a reduced tendency to form gummy deposits on fabrication machinery under high relative humidity conditions. The glass fiber strand is treated with a starch based forming size comprising about 50 to about 65 weight percent of the non-aqueous components of the composition being a starch containing cross-links that has been partially cooked along with a hydrogenated vegetable oil, or fatty triglyceride, cationic wetting agent, emulsifying agent, and water. The forming size composition can also contain a salt of a polyamino functional polyamide resin and a carboxylic acid and a wax and a coupling agent.
Inventors
- 👤 Douglas M. Walser
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 15:01
CPC Classifications
C; C03; C03C; C03C25/00; C03C25/10; C03C25/24; C03C25/26; C03C25/32; C03C25/321; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2913; Y10T428/2933; Y10T428/2938
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
226 words
In a method of forming a sized glass fiber strand comprising drawing glass streams through orifices in a bushing to form individual glass fibers, moving the fibers away from the bushing at a high rate of speed and forming them into a strand, and applying to the fibers while they are moving at this speed and before they are formed into a strand a starch-based sizing solution; 4 percent to 52 percent by weight of the salt of a polyamino functional polyamide resin, said polyamino functional polyamide resin salt being formed from the condensation reaction product of a carboxylic acid and a polyamine, said polyamine having greater than 2 amine groups per molecule, and a carboxylic acid having 1 to 5 carbon atoms; 5 to 25 percent by weight of a wax from the group consisting of animal waxes, vegetable waxes, mineral waxes and synthetic waxes; and 9 percent to 77 percent by weight of a fatty triglyceride; and collecting the glass strands so produced; the improvement comprising: using in the size solution about 50 to about 65 weight percent based on the non-aqueous components in the solution of a starch containing cross-links that has been partially cooked to within about 50 percent of complete cooking so that the sized glass strands produced have a reduced tendency to form gummy deposits under high relative humidity conditions.
Claim 2
Dependent Claim
226 words
In a method of forming a sized glass fiber strand comprising drawing glass streams through orifices in a bushing to form individual glass fibers, moving the fibers away from the bushing at a high rate of speed and forming them into a strand, and applying to the fibers while they are moving at this speed and before they are formed into a strand a starch-based sizing solution; 4 percent to 52 percent by weight of the salt of a polyamino functional polyamide resin, said polyamino functional polyamide resin salt being formed from the condensation reaction product of a carboxylic acid and a polyamine, said polyamine having greater than 2 amine groups per molecule, and a carboxylic acid having 1 to 5 carbon atoms; 5 to 25 percent by weight of a wax from the group consisting of animal waxes, vegetable waxes, mineral waxes and synthetic waxes; and 9 percent to 77 percent by weight of a fatty triglyceride; and collecting the glass strands so produced; the improvement comprising: using in the size solution about 50 to about 65 weight percent based on the non-aqueous components in the solution of a starch containing cross-links that has been partially cooked to within about 50 percent of complete cooking so that the sized glass strands produced have a reduced tendency to form gummy deposits under high relative humidity conditions.
Claim 3
Dependent Claim
55 words
Method according to claim 1 wherein the cross-linked starch was partially cooked by heating the starch to a temperature in the range of about 220° F. to about 250° F. in a jet cooker at a pressure in the range of 90 to about 110 psi and cooling the starch to below around 190° F.
Claim 4
Dependent Claim
13 words
Method according to claim 1 wherein the fatty triglyceride is hydrogenated soybean oil.
Claim 5
Dependent Claim
10 words
Method according to claim 1 wherein the wax is paraffin.
Claim 6
Dependent Claim
19 words
Method according to claim 1 wherein the size contains 10 to 45 percent by weight of an alkyl imidazoline.
Claim 7
Dependent Claim
12 words
Method according to claim 1 wherein the carboxylic acid is acetic acid.
Claim 8
Dependent Claim
27 words
Method according to claim 1 wherein the starch is a cross-linked cornstarch having an amylose content of from 25 to 27 percent by weight of the starch.
References Cited (Backward Citations)
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-11-11 | 1984-05-12 | 1984-11-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-11-11 | 1988-05-12 | 1988-11-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-11-11 | 1992-05-12 | 1992-11-11 | $7700.00 | Window Closed / Lapsed |