US4232086A
Expired / Lapsed
US
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Polyolefin-metal bonded structures and process for preparing same
Assignee: Toyo Seikan Group Holdings Ltd
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Filing: 1978-11-15
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Granted: 1980-11-04
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Expires: 1998-11-15
Abstract
Abstract When a polyolefin layer is bonded to a metal substrate through a primer layer, if a polar group-containing ethylenically unsaturated monomer-modified olefin resin (A) having a specific polar group concentration and a specific degree of crystallinity and a coating film-forming base resin (B) are incorporated at a specific ratio into a specific mixed solvent to form a paint and the primer layer is formed by using this paint, there is obtained a novel multi-layer distribution structure comprising the base resin distributed predominantly in the portion of the primer layer contiguous to the surface of the metal substrate and the modified olefin resin distributed predominantly in the portion of the primer layer contiguous to the polyolefin layer and having a concentration gradient of the two components (A) and (B) in the thickness direction. By virtue of the presence of this primer layer, the bonding strength between the metal substrate and the polyolefin and the corrosion resistance of the metal substrate as well as the processability of the polyolefin-metal bonded structure are substantially improved.
Inventors
- 👤 Fumio Mori
- 👤 Isao Ichinose
- 👤 Go Kunimoto
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 07:23
CPC Classifications
B; B32; B32B; B32B15/00; B32B15/04; B32B15/08; B32B15/085; B32B27/00; B32B27/32; B32B7/00; B32B7/04; B32B7/12; C; C09; C09J; C09J5/00; C09J5/06; B32B2250/00; B32B2250/02; B32B2307/00; B32B2307/70; B32B2307/714; B32B2307/726; B32B2307/7265; B32B2311/00; B32B2323/00; B32B2435/00; B32B2435/02; B32B2581/00; Y; Y10; Y10T; Y10T428/00; Y10T428/27; Y10T428/273; Y10T428/31504; Y10T428/31511; Y10T428/31515; Y10T428/31522; Y10T428/31678; Y10T428/31692
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
270 words
A polyolefin-metal bonded structure comprising a metal substrate and a polyolefin resin layer bonded to the metal substrate through a primer layer, said primer layer comprising: (a) a polar group-containing ethylenically unsaturated monomer-modified olefin resin (A) containing said polar groups at a concentration of between about 0.01 and 200 milliequivalents per 100 g of the olefin resin and having a degree of crystallinity of at least about 50%; and (b) a coating film-forming base resin (B) at an (A)/(B) weight ratio of between about 0.2/99.8 and 40/60, said primer layer having a multi-layer distribution structure with concentration gradients of components (A) and (B) in the thickness direction such that the base resin (B) is distributed predominantly in the portion of the primer layer contiguous to the surface of the metal substrate and the modified olefin resin (A) is distributed predominantly in the portion of the primer layer contiguous to the polyolefin layer, wherein when said primer layer is divided into three sub-layers with respect to the thickness direction, the distribution ratio, Dx, defined by the following formula: D.sub.x =10000 W.sub.X /(W)(C.sub.A) wherein W is the weight of the primer layer per unit surface area (mg/dm 2 ), C A is the average % by weight of the modified olefin resin in the primer layer, and W X is the weight per unit area (mg/dm 2 ) of the modified olefin resin in each sub-layer, being at least about 50% in the sub-layer, L S , contiguous to the polyolefin layer and not higher than about 10% in the sub-layer, L B , contiguous to the surface of the metal substrate.
Claim 2
Dependent Claim
270 words
A polyolefin-metal bonded structure comprising a metal substrate and a polyolefin resin layer bonded to the metal substrate through a primer layer, said primer layer comprising: (a) a polar group-containing ethylenically unsaturated monomer-modified olefin resin (A) containing said polar groups at a concentration of between about 0.01 and 200 milliequivalents per 100 g of the olefin resin and having a degree of crystallinity of at least about 50%; and (b) a coating film-forming base resin (B) at an (A)/(B) weight ratio of between about 0.2/99.8 and 40/60, said primer layer having a multi-layer distribution structure with concentration gradients of components (A) and (B) in the thickness direction such that the base resin (B) is distributed predominantly in the portion of the primer layer contiguous to the surface of the metal substrate and the modified olefin resin (A) is distributed predominantly in the portion of the primer layer contiguous to the polyolefin layer, wherein when said primer layer is divided into three sub-layers with respect to the thickness direction, the distribution ratio, Dx, defined by the following formula: D.sub.x =10000 W.sub.X /(W)(C.sub.A) wherein W is the weight of the primer layer per unit surface area (mg/dm 2 ), C A is the average % by weight of the modified olefin resin in the primer layer, and W X is the weight per unit area (mg/dm 2 ) of the modified olefin resin in each sub-layer, being at least about 50% in the sub-layer, L S , contiguous to the polyolefin layer and not higher than about 10% in the sub-layer, L B , contiguous to the surface of the metal substrate.
Claim 3
Dependent Claim
28 words
A bonded structure according to claim 1 wherein the modified olefin resin is an olefin resin grafted with an ethylenically unsaturated carboxylic acid or ethylenically unsaturated carboxylic anhydride.
Claim 4
Dependent Claim
38 words
A bonded structure according to claim 1 wherein the distribution ratio in the sub-layer, L S , is at least about 70% and the distribution ratio in the sub-layer, L B , is not higher than about 5%.
Claim 5
Dependent Claim
47 words
A bonded structure according to claim 1 wherein the base resin has a density 10 percent greater than the density of the modified olefin resin and contains hydroxyl functional groups and carboxyl functional groups at a concentration of at least 1 milliequivalent per gram of base resin.
Claim 6
Dependent Claim
36 words
A bonded structure according to claim 1 wherein the base resin is selected from the group consisting of phenolic resin-epoxy resin paints, urea resin-epoxy resin paints, melamine resin-epoxy resin paints and phenolic resin-epoxy resin-vinyl resin paints.
Claim 7
Dependent Claim
53 words
A bonded structure according to claim 1 wherein the modified olefin resin is applied to the metal substrate in an amount coated of between about 0.1 and 10 mg/dm 2 and the base resin is applied to the metal substrate in an amount coated of between about 10 and 100 mg/dm 2 .
Claim 8
Dependent Claim
47 words
A bonded structure according to claim 1 wherein wherein a modified polyethylene-free undercoat layer composed of a resin selected from the group consisting of phenol-epoxy-vinyl resins is formed in an amount of between about 10 and 200 mg/dm 2 between said primer layer and said metal substrate.
Claim 9
Dependent Claim
18 words
A bonded structure according to claim 1 wherein said structure is in the form of a vessel closure.
Claim 10
Dependent Claim
36 words
A bonded structure according to claim 1 wherein the metal substrate is a crown shell or cap shell, the polyolefin layer is a packing and the entire structure is in the form of a vessel closure.
Claim 11
Dependent Claim
149 words
A process for preparing a polyolefin-metal bonded structure, comprising applying an undercoat paint onto a metal substrate and fusion-bonding a polyolefin layer to the metal substrate through a layer of the undercoat paint, wherein said undercoat paint comprises: (a) a polar group-containing ethylenically unsaturated monomer-modified olefin resin (A) containing said polar groups at a concentration of between about 0.01 and 200 milliequivalents per 100 g of the olefin resin and having a degree of crystallinity of at least about 50%; and (b) a coating film-forming base resin (B) at an (A)/(B) weight ratio of between about 0.2/99.8 and 40/60 in a mixed solvent containing at least 70% by weight of a solvent component having a solubility parameter of between about 8.5 and 9.5, said mixed solvent being further characterized in that the difference between the boiling point of the highest boiling solvent component is at least about 20° C.
Claim 12
Dependent Claim
149 words
A process for preparing a polyolefin-metal bonded structure, comprising applying an undercoat paint onto a metal substrate and fusion-bonding a polyolefin layer to the metal substrate through a layer of the undercoat paint, wherein said undercoat paint comprises: (a) a polar group-containing ethylenically unsaturated monomer-modified olefin resin (A) containing said polar groups at a concentration of between about 0.01 and 200 milliequivalents per 100 g of the olefin resin and having a degree of crystallinity of at least about 50%; and (b) a coating film-forming base resin (B) at an (A)/(B) weight ratio of between about 0.2/99.8 and 40/60 in a mixed solvent containing at least 70% by weight of a solvent component having a solubility parameter of between about 8.5 and 9.5, said mixed solvent being further characterized in that the difference between the boiling point of the highest boiling solvent component is at least about 20° C.
Claim 13
Dependent Claim
27 words
A process according to claim 10 wherein the modified olefin resin is an olefin resin grafted with an ethylenically unsaturated carboxylic acid or ethylenically unsaturated carboxylic anhydride.
Claim 14
Dependent Claim
50 words
A process according to claim 10 wherein the base resin has a density 10 percent greater than the density of the modified olefin resin and contains hydroxyl functional groups and carboxyl functional groups at a concentration of at least 1 milliequivalent of said functional groups per gram of base resin.
Claim 15
Dependent Claim
35 words
A process according to claim 10 wherein the base resin is selected from the group consisting of phenolic resin-epoxy resin paints, urea resin-epoxy resin paints, melamine resin-epoxy resin paints and phenolic resin-epoxy resin-vinyl resin paints.
Claim 16
Dependent Claim
52 words
A process according to claim 10 wherein the modified olefin resin is applied to the metal substrate in an amounted coated of between about 0.1 and 10 mg/dm 2 and the base resin is applied to the metal substrate in an amount coated of between about 10 and 100 mg/dm 2 .
Claim 17
Dependent Claim
46 words
A process according to claim 10 wherein wherein a modified polyethylene-free undercoat layer composed of a resin selected from the group consisting of phenol-epoxy-vinyl resins is coated in an amount of between about 10 and 200 mg/dm 2 between said primer layer and said metal substrate.
Claim 18
Dependent Claim
17 words
A process according to claim 10 wherein said structure is in the form of a vessel closure.
Claim 19
Dependent Claim
35 words
A process according to claim 10 wherein the metal substrate is a crown shell or cap shell, the polyolefin layer is a packing and the entire structure is in the form of a vessel closure.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-11-04 | 1984-05-05 | 1984-11-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-11-04 | 1988-05-05 | 1988-11-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-11-04 | 1992-05-05 | 1992-11-04 | $7700.00 | Window Closed / Lapsed |