US4231799A
Expired / Lapsed
US
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Electrophotographic recording material
Assignee: Hoechst AG
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Filing: 1975-05-15
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Granted: 1980-11-04
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Expires: 1995-05-15
Abstract
Abstract This invention relates to an electrophotographic recording material consisting of an electroconductive support material and a photoconductive double layer of organic materials which consists of a homogeneous, opaque, charge carrier producing dyestuff layer and of a transparent top layer of insulating materials with at least one charge transporting compound.
Inventors
- 👤 Jurgen Rochlitz
- 👤 Gunter Schon
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 01:49
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/02; G03G5/04; G03G5/06; G03G5/14
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
217 words
An electrophotographic recording material comprising an electroconductive support material with a photoconductive double layer of organic materials composed of a tightly packed, homogeneous, uniform, opaque, charge carrier producing dyestuff layer prepared by vacuum evaporation of the dyestuff and a transparent top layer of insulating materials with at least one charge transporting compound, in which the organic dyestuff layer is composed of the general formula ##STR2## in which R is a hydroxyl or amino group, R 1 is phenyl, naphthyl or quinolyl which are optionally substituted by hydroxy, C 1 -C 4 alkyl, C 1 -C 4 alkoxy, nitro groups, halogen or by carbamoyl or sulfonamido groups which are optionally substituted at the nitrogen by C 1 -C 4 alkyl, C 1 -C 4 alkenyl, phenyl or cyclohexyl groups, R 2 is hydrogen, amino or carbamoyl, which may be N-substituted by phenyl, naphthyl or benzimidazolonyl and in which the transparent top layer is composed of a mixture of a charge transporting monomeric heterocyclic compound with at least one substituted amino group and having an extended π-electron system, which is selected from the group of oxazoles, oxdiazoles, triazoles, imidazoles and pyrazoles, and a binder in a ratio by weight of about 1:1, which recording material is useful in an electrophotographic copying process with negative charging of the top layer.
Claim 2
Dependent Claim
217 words
An electrophotographic recording material comprising an electroconductive support material with a photoconductive double layer of organic materials composed of a tightly packed, homogeneous, uniform, opaque, charge carrier producing dyestuff layer prepared by vacuum evaporation of the dyestuff and a transparent top layer of insulating materials with at least one charge transporting compound, in which the organic dyestuff layer is composed of the general formula ##STR2## in which R is a hydroxyl or amino group, R 1 is phenyl, naphthyl or quinolyl which are optionally substituted by hydroxy, C 1 -C 4 alkyl, C 1 -C 4 alkoxy, nitro groups, halogen or by carbamoyl or sulfonamido groups which are optionally substituted at the nitrogen by C 1 -C 4 alkyl, C 1 -C 4 alkenyl, phenyl or cyclohexyl groups, R 2 is hydrogen, amino or carbamoyl, which may be N-substituted by phenyl, naphthyl or benzimidazolonyl and in which the transparent top layer is composed of a mixture of a charge transporting monomeric heterocyclic compound with at least one substituted amino group and having an extended π-electron system, which is selected from the group of oxazoles, oxdiazoles, triazoles, imidazoles and pyrazoles, and a binder in a ratio by weight of about 1:1, which recording material is useful in an electrophotographic copying process with negative charging of the top layer.
Claim 3
Dependent Claim
21 words
A recording material according to claim 1 in which the charge transporting heterocyclic compound having an extended π-electron system is 2,5-bis-(4'-diethylaminophenyl)-oxdiazole-1,3,4.
Claim 4
Dependent Claim
14 words
A material according to claim 1, in which the heterocyclic compound is an oxadiazole.
Claim 5
Dependent Claim
32 words
A material according to claim 1, in which the binder is selected from the group of polyesters, copolyesters, silicone resins, of copolymers or styrene with maleic acid anhydride, and of polycarbonate resins.
Claim 6
Dependent Claim
19 words
A material according to claim 1, in which the binder is a copolymer from styrene and maleic acid anhydride.
Claim 7
Dependent Claim
22 words
A material according to claim 1, in which the photoconductive double layer is above an insulating intermediate layer on the support material.
Claim 8
Dependent Claim
29 words
A material according to claim 1, in which the electroconductive support material used are metal foils of aluminum or lead or plastics vapor deposited or laminated with these metals.
Claim 9
Dependent Claim
29 words
A material according to claim 1 in which the transport top layer additionally contains a sensitizer, and has a thickness in the range of about 5 to 20 μm.
Claim 10
Dependent Claim
134 words
An electrophotographic recording material comprising an electroconductive support material with a photoconductive double layer of organic materials composed of a tightly packed, homogeneous, uniform, opaque, charge carrier producing dyestuff layer prepared by vacuum evaporation of the dyestuff and a transparent top layer of insulating materials with at least one charge transporting compound, in which the organic dyestuff layer consists of 1-(2-chloro-5-n-propylcarbamoyl-phenyl-azo)-2-hydroxy-3(N-benzimidazolon-(3)-yl-(5)-carbamoyl))-naphthalene and in which the transparent top layer is composed of a mixture of a charge transporting monomeric heterocyclic compound with at least one substituted amino group and having an extended π-electron system, which is selected from the group of oxazoles, oxdiazoles, triazoles, imidazoles and pyrazoles, and a binder in a ratio by weight of about 1:1, which recording material is useful in an electrophotographic copying process with negative charging of the top layer.
Claim 11
Dependent Claim
134 words
An electrophotographic recording material comprising an electroconductive support material with a photoconductive double layer of organic materials composed of a tightly packed, homogeneous, uniform, opaque, charge carrier producing dyestuff layer prepared by vacuum evaporation of the dyestuff and a transparent top layer of insulating materials with at least one charge transporting compound, in which the organic dyestuff layer consists of 1-(2-chloro-5-n-propylcarbamoyl-phenyl-azo)-2-hydroxy-3(N-benzimidazolon-(3)-yl-(5)-carbamoyl))-naphthalene and in which the transparent top layer is composed of a mixture of a charge transporting monomeric heterocyclic compound with at least one substituted amino group and having an extended π-electron system, which is selected from the group of oxazoles, oxdiazoles, triazoles, imidazoles and pyrazoles, and a binder in a ratio by weight of about 1:1, which recording material is useful in an electrophotographic copying process with negative charging of the top layer.
Claim 12
Dependent Claim
134 words
An electrophotographic recording material comprising an electroconductive support material with a photoconductive double layer of organic materials composed of a tightly packed, homogeneous, uniform, opaque, charge carrier producing dyestuff layer prepared by vacuum evaporation of the dyestuff and a transparent top layer of insulating materials with at least one charge transporting compound, in which the organic dyestuff layer consists of 1-(2-chloro-5-propene(1)-yl-carbamoyl-phenyl-azo)-2-hydroxy-3(N-(benzimidazolon-(3)-yl-(5)-carbamoyl)-naphthalene, and in which the transparent top layer is composed of a mixture of a charge transporting monomeric heterocyclic compound with at least one substituted amino group and having an extended π-electron system, which is selected from the group of oxazoles, oxdiazoles, triazoles, imidazoles and pyrazoles, and a binder in a ratio by weight of about 1:1, which recording material is useful in an electrophotographic copying process with negative charging of the top layer.
Claim 13
Dependent Claim
134 words
An electrophotographic recording material comprising an electroconductive support material with a photoconductive double layer of organic materials composed of a tightly packed, homogeneous, uniform, opaque, charge carrier producing dyestuff layer prepared by vacuum evaporation of the dyestuff and a transparent top layer of insulating materials with at least one charge transporting compound, in which the organic dyestuff layer consists of 1-(2-chloro-5-propene(1)-yl-carbamoyl-phenyl-azo)-2-hydroxy-3(N-(benzimidazolon-(3)-yl-(5)-carbamoyl)-naphthalene, and in which the transparent top layer is composed of a mixture of a charge transporting monomeric heterocyclic compound with at least one substituted amino group and having an extended π-electron system, which is selected from the group of oxazoles, oxdiazoles, triazoles, imidazoles and pyrazoles, and a binder in a ratio by weight of about 1:1, which recording material is useful in an electrophotographic copying process with negative charging of the top layer.
Claim 14
Dependent Claim
138 words
An electrophotographic recording material comprising an electroconductive support material with a photoconductive double layer of organic materials composed of a tightly packed, homogeneous, uniform, opaque, charge carrier producing dyestuff layer prepared by vacuum evaporation of the dyestuff and a transparent top layer of insulating materials with at least one charge transporting compound, in which the organic dyestuff layer consists of Permanent Bordeaux FRR, (C.I. 12,385), and in which the transparent top layer is composed of a mixture of a charge transporting monomeric heterocyclic compound with at least one substituted amino group and having an extended π-electron system, which is selected from the group of oxazoles, oxdiazoles, triazoles, imidazoles and pyrazoles, and a binder in a ratio by weight of about 1:1, which recording material is useful in an electrophotographic copying process with negative charging of the top layer.
Claim 15
Dependent Claim
138 words
An electrophotographic recording material comprising an electroconductive support material with a photoconductive double layer of organic materials composed of a tightly packed, homogeneous, uniform, opaque, charge carrier producing dyestuff layer prepared by vacuum evaporation of the dyestuff and a transparent top layer of insulating materials with at least one charge transporting compound, in which the organic dyestuff layer consists of Permanent Bordeaux FRR, (C.I. 12,385), and in which the transparent top layer is composed of a mixture of a charge transporting monomeric heterocyclic compound with at least one substituted amino group and having an extended π-electron system, which is selected from the group of oxazoles, oxdiazoles, triazoles, imidazoles and pyrazoles, and a binder in a ratio by weight of about 1:1, which recording material is useful in an electrophotographic copying process with negative charging of the top layer.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-11-04 | 1984-05-05 | 1984-11-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-11-04 | 1988-05-05 | 1988-11-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-11-04 | 1992-05-05 | 1992-11-04 | $7700.00 | Window Closed / Lapsed |