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US4230781A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for making etch-resistant stencil with dichromate-sensitized alkali-caseinate coating

Assignee: RCA Licensing Corp
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Filing: 1976-02-19
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Granted: 1980-10-28
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Expires: 1996-02-19
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Abstract

Abstract Method comprises applying to a surface to be etched a coating of a liquid composition having a pH of about 5.8 to 7.0 and comprising an alkali caseinate, an alkali dichromate photosensitizer, sodium borate and water. The layer is dried, photoexposed, developed and baked to produce an etch-resistant stencil.

Inventors

  • 👤 Joseph J. Piascinski
  • 👤 Ernest E. Doerschuk, III

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 22:13
CPC Classifications
G; G03; G03F; G03F1/00; G03F1/20; G03F7/00; G03F7/004; G03F7/04; H; H05; H05K; H05K3/00; H05K3/0073; H05K3/0076

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 99 words
A method for producing an etch-resistant stencil upon a surface comprising applying to said surface a coating of a liquid composition having a pH of about 5.8 to 7.0 and comprising (i) an alkali caseinate, (ii) an alkali dichromate photosensitizer for said caseinate (iii) hydrated sodium borate, the weight of said hydrated sodium borate comprising 0.10 to 0.35 of the weight of said alkali caseinate, and (iv) water, drying said coating, photoexposing said coating to a light image, developing said exposed coating to produce said stencil, and then baking said stencil in air to render said pattern etch resistant.
Claim 2
Independent Claim 99 words
A method for producing an etch-resistant stencil upon a surface comprising applying to said surface a coating of a liquid composition having a pH of about 5.8 to 7.0 and comprising (i) an alkali caseinate, (ii) an alkali dichromate photosensitizer for said caseinate (iii) hydrated sodium borate, the weight of said hydrated sodium borate comprising 0.10 to 0.35 of the weight of said alkali caseinate, and (iv) water, drying said coating, photoexposing said coating to a light image, developing said exposed coating to produce said stencil, and then baking said stencil in air to render said pattern etch resistant.
Claim 3
Dependent Claim 24 words
The method defined in claim 1 wherein the weight of said sodium borate comprises 0.18 to 0.30 of the weight of said alkali caseinate.
Claim 4
Dependent Claim 19 words
The method defined in claim 1 wherein said composition has a pH in the range of 6.5 to 6.9.
Claim 5
Dependent Claim 19 words
The method defined in claim 1 wherein said dry coating before baking is about 40 to 100 microinches thick.
Claim 6
Dependent Claim 20 words
The method defined in claim 1 wherein said alkali caseinate is sodium caseinate and said alkali dichromate is ammonium dichromate.
Claim 7
Dependent Claim 143 words
In a method for producing an apertured mask for a cathode-ray tube, the steps comprising (a) applying to each major surface of a metal sheet a coating of a liquid, water-based coating composition having a pH of about 5.8 to 7.0 and consisting essentially of (i) alkali caseinate, (ii) an alkali dichromate photosensitizer for said caseinate, (iii) hydrated sodium borate, the weight of said hydrated sodium borate comprising 0.10 to 0.35 of the weight of said alkali caseinate, and (iv) water, (b) drying said coatings, (c) exposing said dry coatings to light images, (d) developing said exposed coatings to produce stencils on each of said major surfaces, (e) baking said stencils in air to render said stencils etch resistant, (f) and then applying an etchant for said metal sheet to both of said major surfaces until said sheet is etched a desired amount.
Claim 8
Dependent Claim 143 words
In a method for producing an apertured mask for a cathode-ray tube, the steps comprising (a) applying to each major surface of a metal sheet a coating of a liquid, water-based coating composition having a pH of about 5.8 to 7.0 and consisting essentially of (i) alkali caseinate, (ii) an alkali dichromate photosensitizer for said caseinate, (iii) hydrated sodium borate, the weight of said hydrated sodium borate comprising 0.10 to 0.35 of the weight of said alkali caseinate, and (iv) water, (b) drying said coatings, (c) exposing said dry coatings to light images, (d) developing said exposed coatings to produce stencils on each of said major surfaces, (e) baking said stencils in air to render said stencils etch resistant, (f) and then applying an etchant for said metal sheet to both of said major surfaces until said sheet is etched a desired amount.
Claim 9
Dependent Claim 21 words
The method defined in claim 6 wherein the specific gravity of said coating composition is in the range 1.028 to 1.036.
Claim 10
Dependent Claim 17 words
The method defined in claim 6 wherein said pH is in the range of 6.5 to 6.9.
Claim 11
Dependent Claim 19 words
The method defined in claim 8 wherein said pattern is baked in air at about 260° to 325° C.
Claim 12
Dependent Claim 19 words
The method defined in claim 8 wherein said sheet is of cold-rolled steel and said etchant includes ferric chloride.

References Cited (Backward Citations)

US2387056A Cited
US2624672A Cited
US2677611A Cited
US2716061A Cited
US3745011A Cited
US3751250A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-10-28 1984-04-28 1984-10-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-10-28 1988-04-28 1988-10-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-10-28 1992-04-28 1992-10-28 $7700.00 Window Closed / Lapsed

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