US4229604A
Expired / Lapsed
US
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Process for producing unsaturated hydrocarbons
Assignee: Individual
•
Filing: 1979-02-05
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Granted: 1980-10-21
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Expires: 1999-02-05
Abstract
Abstract A process for producing unsaturated hydrocarbons which comprises contacting a paraffin, monoolefin and/or alkylaromatic compounds with a catalyst at a temperature within the range of from 400° to 700° C. in the presence of an inert gas and/or steam. The catalyst comprises a carrier having deposited thereonto an oxide of molybdenum in an amount of from 5 to 35% by weight of the catalyst. As the carrier, use is made of a granulated porous crystalline silica modified with magnesia in an amount of from 1 to 20% by weight of the carrier; a granulated magnesium-titanium carrier consisting of 50 to 95% by weight of MgO and 50 to 5% by weight of TiO 2 , or a granulated magnesium-aluminum carrier consisting of 70 to 95% by weight of MgO and 5 to 30% by weight of Al 2 O 3 . Through the spent catalyst an oxygen-containing gas is passed at a temperature within the range of from 400° to 700° until catalytic activity is restored to the catalyst. The process, according to the present invention, ensures a high selectivity; substantially simplifies temperature control in the reaction zone; avoids the possibility of forming of a hazardous mixture of hydrocarbons with oxygen; and simplifies purification of waste waters.
Inventors
- 👤 Dzantemir N. Tmenov
- 👤 Nikolai I. Svintsov
- 👤 Lidia P. Shapovalova
- 👤 Albert V. Tabakov
- 👤 Mikhail L. Dvoretsky
- 👤 Gavril I. Vasiliev
- 👤 Gennady P. Zhestovsky
- 👤 Valentina D. Kandalova
- 👤 Boris S. Korotkevich
- 👤 Anatoly I. Lukashov
- 👤 Valery P. Lukyanenko
- 👤 Roman I. Polataiko
- 👤 Evgeny A. Malov
- 👤 Jury A. Shmuk
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 05:05
CPC Classifications
B; B01; B01J; B01J23/00; B01J23/70; B01J23/76; B01J23/84; B01J23/85; B01J23/88; B01J23/887; B01J23/8872; B01J23/16; B01J23/32; B01J23/34; B01J23/90; B01J37/00; B01J37/12; B01J37/14; C; C07; C07C; C07C5/00; C07C5/32; C07C5/321; C07C5/322; C07C5/327; C07C5/333; C07C5/3332; Y; Y02; Y02P; Y02P20/00; Y02P20/50; Y02P20/582; Y02P20/584
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
231 words
A process for producing unsaturated hydrocarbons comprising contacting compounds selected from the group consisting of paraffin, monoolefin and alkylaromatic hydrocarbons at a temperature within the range of from 400° to 700° C. in the presence of an inert component selected from the group consisting of an inert gas and steam, and in the presence of oxygen in an amount up to 0.1 mole per mole of the hydrocarbon feed, with a catalyst consisting essentially of oxides selected from the group consisting of cobalt, nickel, iron and manganese deposited on a carrier in an amount of from 3.7 to 15% by weight of the catalyst; said catalyst also including an oxide of molybdenum in an amount of from 5 to 35% by weight of the catalyst, also deposited on the carrier; said carrier being selected from the group consisting of granulated porous crystalline silica modified with magnesia in an amount of 1 to 20% by weight of the carrier, granulated magnesium-titanium oxides consisting of 50 to 95% by weight of MgO and 50 to 5% by weight of TiO 2 and granulated magnesium-aluminum oxides consisting of 70 to 95% by weight of MgO and 5 to 30% by weight of Al 2 O 3 ; passing an oxygen-containing gas through the spent catalyst at a temperature within the range of from 400° to 700° C. to restore catalytic activity of the catalyst.
Claim 2
Dependent Claim
231 words
A process for producing unsaturated hydrocarbons comprising contacting compounds selected from the group consisting of paraffin, monoolefin and alkylaromatic hydrocarbons at a temperature within the range of from 400° to 700° C. in the presence of an inert component selected from the group consisting of an inert gas and steam, and in the presence of oxygen in an amount up to 0.1 mole per mole of the hydrocarbon feed, with a catalyst consisting essentially of oxides selected from the group consisting of cobalt, nickel, iron and manganese deposited on a carrier in an amount of from 3.7 to 15% by weight of the catalyst; said catalyst also including an oxide of molybdenum in an amount of from 5 to 35% by weight of the catalyst, also deposited on the carrier; said carrier being selected from the group consisting of granulated porous crystalline silica modified with magnesia in an amount of 1 to 20% by weight of the carrier, granulated magnesium-titanium oxides consisting of 50 to 95% by weight of MgO and 50 to 5% by weight of TiO 2 and granulated magnesium-aluminum oxides consisting of 70 to 95% by weight of MgO and 5 to 30% by weight of Al 2 O 3 ; passing an oxygen-containing gas through the spent catalyst at a temperature within the range of from 400° to 700° C. to restore catalytic activity of the catalyst.
Claim 3
Dependent Claim
225 words
A process for preparing a catalyst consisting essentially of oxides selected from the group consisting of cobalt, nickel, iron and manganese deposited on a carrier in an amount of from 3.7 to 15% by weight of the catalyst; said catalyst also including an oxide of molybdenum in an amount from 5 to 35% by weight of the catalyst, also deposited on the carrier; said carrier being selected from the group consisting of granulated porous crystalline silica modified with magnesia in an amount of 1 to 20% by weight of the carrier, granulated magnesium-titanium oxides consisting of 50 to 95% by weight of MgO and 50 to 5% by weight of TiO 2 , and granulated magnesium-aluminum oxides consisting of 70 to 95% by weight of MgO and 5 to 30% by weight of Al 2 O 3 ; said catalyst being prepared by first impregnating the carrier with an aqueous solution of ammonium molybdate to obtain a suspension, wherefrom water is removed by evaporation, and the carrier is subjected to a second impregnation with an aqueous solution of a metal nitrate selected from the group consisting of cobalt, nickel, iron and manganese, and calcining the resulting mass at a temperature within the range of from 350° to 700° C. in a medium selected from the group consisting of an inert medium and an oxidizing medium.
Claim 4
Dependent Claim
225 words
A process for preparing a catalyst consisting essentially of oxides selected from the group consisting of cobalt, nickel, iron and manganese deposited on a carrier in an amount of from 3.7 to 15% by weight of the catalyst; said catalyst also including an oxide of molybdenum in an amount from 5 to 35% by weight of the catalyst, also deposited on the carrier; said carrier being selected from the group consisting of granulated porous crystalline silica modified with magnesia in an amount of 1 to 20% by weight of the carrier, granulated magnesium-titanium oxides consisting of 50 to 95% by weight of MgO and 50 to 5% by weight of TiO 2 , and granulated magnesium-aluminum oxides consisting of 70 to 95% by weight of MgO and 5 to 30% by weight of Al 2 O 3 ; said catalyst being prepared by first impregnating the carrier with an aqueous solution of ammonium molybdate to obtain a suspension, wherefrom water is removed by evaporation, and the carrier is subjected to a second impregnation with an aqueous solution of a metal nitrate selected from the group consisting of cobalt, nickel, iron and manganese, and calcining the resulting mass at a temperature within the range of from 350° to 700° C. in a medium selected from the group consisting of an inert medium and an oxidizing medium.
Claim 5
Dependent Claim
9 words
The catalyst formed by the process of claim 2.
Claim 6
Dependent Claim
28 words
A process as claimed in claim 2, wherein said impregnation with aqueous solutions of salts and removal of water by evaporation is repeated for 3 to 12 times.
Claim 7
Dependent Claim
21 words
A process as claimed in claim 2, wherein the removal of water from the suspension by evaporation is effected under vacuum.
Claim 8
Dependent Claim
19 words
A process as claimed in claim 2, wherein calcination of the resulting mass is effected in a fluidized bed.
Claim 9
Dependent Claim
56 words
A process as claimed in claim 2, wherein the resulting carrier mass, impregnated with aqueous solutions of ammonium molybdate and a nitric salt and dried, is treated, prior to calcination, with an aqueous solution of a nitrogen-containing compound selected from the group consisting of ammonia, amines and aminoalcohols, followed by the removal of water by evaporation.
Claim 10
Dependent Claim
22 words
A process as claimed in claim 7, wherein the aqueous amine solutions are selected from the group consisting of methylamine and triethylamine.
Claim 11
Dependent Claim
22 words
A process as claimed in claim 7, wherein the aqueous aminoalcohol solutions are selected from the group consisting of monoethanolamine and triethanolamine.
References Cited (Backward Citations)
US2376549A
Cited
US2547380A
Cited
US3488402A
Cited
US3577477A
Cited
US3862256A
Cited
US3969428A
Cited
US4140626A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-10-21 | 1984-04-21 | 1984-10-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-10-21 | 1988-04-21 | 1988-10-21 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-10-21 | 1992-04-21 | 1992-10-21 | $7700.00 | Window Closed / Lapsed |