Articulated para-ordered aromatic heterocyclic polymers containing diphenoxybenzene structures

Claim 2

A para-ordered aromatic heterocyclic polymer consisting essentially of repeating units having a structure as represented by one of the following formulas: ##STR41## wherein X in each formula is O, S or NH; Ar is ##STR42## where R is a monovalent aromatic radical and R' and R" are individually selected from the group consisting of hydrogen, a monovalent aromatic radical, a monovalent aliphatic radical, a monovalent cycloaliphatic radical, and a monovalent heterocyclic radical; Ar' is ##STR43## a ranges from about 0.75 to 0.97, b ranges from about 0.03 to 0.25, and the sum of a and b equals 1; and n is an integer equal to the number of repeating units.

Claim 3

The para-ordered aromatic heterocyclic polymer according to claim 1 in which R is ##STR44## R' and R" are hydrogen, a monovalent aromatic radical as listed above, --CH 2 CH 3 , --CH 2 CH 2 CH 3 , --CH 2 CH 2 CH 2 --CH 3 , ##STR45## and n has a value such that the polymer has an inherent viscosity of 2 to 12 dl/g as determined in methanesulfonic acid at 25° C.

Claim 4

The para-ordered aromatic heterocyclic polymer according to claim 2 that consists essentially of repeating units having a structure as represented by formula I.

Claim 5

The para-ordered aromatic heterocyclic polymer according to claim 2 that consists essentially of repeating units having a structure as represented by formula II.

Claim 6

The para-ordered aromatic heterocyclic polymer according to claim 3 in which X is O, Ar is ##STR46## and Ar' is ##STR47##

Claim 7

The para-ordered aromatic heterocyclic polymer according to claim 3 in which X is O, Ar is ##STR48## and Ar' is ##STR49##

Claim 8

The para-ordered aromatic heterocyclic polymer according to claim 3 in which X is O, Ar is ##STR50## and Ar' is ##STR51##

Claim 9

The para-ordered aromatic heterocyclic polymer according to claim 3 in which X is O, Ar is ##STR52## and Ar" is ##STR53##

Claim 10

The para-ordered aromatic heterocyclic polymer according to claim 3 in which X is O, Ar is ##STR54## and Ar is ##STR55##

Claim 11

As an article of manufacture, a strong, flexible film consisting essentially of a para-ordered aromatic heterocyclic polymer according to claim 1.

Claim 12

A process for preparing a para-ordered aromatic heterocyclic polymer which comprises the following steps: (a) mixing an amino compound and a dicarboxylic acid with polyphosphoric acid, the amino compound being selected from the group of compounds having the following formulas: ##STR56## in which X is O, S or NH, and the dicarboxylic acid having the following formula: HO.sub.2 C--Ar--CO.sub.2 H, in which Ar is ##STR57## wherein R is a monovalent aromatic radical and R' and R" are individually selected from the group consisting of hydrogen, a monovalent aromatic radical, a monovalent aliphatic radical, a monovalent cycloaliphatic radical and a monovalent heterocyclic radical; (b) heating the mixture of step (a) in an inert gas atmosphere at a temperature ranging from about 100° to 150° C. for a period of about 12 to 24 hours; (c) at the end of the heating period of step (b), adding to the mixture a difunctional diphenoxybenzene having the following formula: Y--Ar'--Y, in which Y is CO 2 H, CO 2 CH 3 , COCl, CN or CONH 2 and Ar' is ##STR58## (d) heating the mixture of step (c), in an inert gas atmosphere at a temperature ranging from about 150° to 225° C. for a period of about 36 to 96 hours; and (e) recovering a para-ordered aromatic heterocyclic polymer.

Claim 13

A process for preparing a para-ordered aromatic heterocyclic polymer which comprises the following steps: (a) mixing an amino compound and a dicarboxylic acid with polyphosphoric acid, the amino compound being selected from the group of compounds having the following formulas: ##STR56## in which X is O, S or NH, and the dicarboxylic acid having the following formula: HO.sub.2 C--Ar--CO.sub.2 H, in which Ar is ##STR57## wherein R is a monovalent aromatic radical and R' and R" are individually selected from the group consisting of hydrogen, a monovalent aromatic radical, a monovalent aliphatic radical, a monovalent cycloaliphatic radical and a monovalent heterocyclic radical; (b) heating the mixture of step (a) in an inert gas atmosphere at a temperature ranging from about 100° to 150° C. for a period of about 12 to 24 hours; (c) at the end of the heating period of step (b), adding to the mixture a difunctional diphenoxybenzene having the following formula: Y--Ar'--Y, in which Y is CO 2 H, CO 2 CH 3 , COCl, CN or CONH 2 and Ar' is ##STR58## (d) heating the mixture of step (c), in an inert gas atmosphere at a temperature ranging from about 150° to 225° C. for a period of about 36 to 96 hours; and (e) recovering a para-ordered aromatic heterocyclic polymer.

Claim 14

The process according to claim 11 in which there is used an equimolar amount of the amino compound as compared to the combined amount of the dicarboxylic acid and diphenoxybenzene.

Claim 15

The process of claim 12 in which there are used about 0.75 to 0.97 mole of dicarboxylic acid per mole of amino compound and about 0.03 to 0.25 mole of diphenoxybenzene per mole of amino compound.